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Title: Catalytic Zirconium/Hafnium-Based Metal–Organic Frameworks

Journal Article · · ACS Catalysis
ORCiD logo [1];  [1];  [1];  [1];  [1]; ORCiD logo [1];  [1]; ORCiD logo [2]
  1. Northwestern Univ., Evanston, IL (United States)
  2. Northwestern Univ., Evanston, IL (United States); King Abdulaziz Univ., Jeddah (Saudi Arabia)
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Metal–organic frameworks (MOFs) are highly versatile materials that find applications in several fields. Highly stable zirconium/hafnium-based MOFs were recently introduced and nowadays represent a rapidly growing family. Their unique and intriguing properties make them privileged materials and outstanding candidates in heterogeneous catalysis, finding use either as catalysts or catalyst supports. Various techniques have been developed to incorporate active species into Zr-MOFs, giving rise to catalysts that often demonstrate higher performances or unusual activity when compared with their homogeneous analogues. Catalytic functions are commonly incorporated at the zirconium-oxide node, at the linker, or encapsulated in the pores. Representative examples are discussed, and advantages in adopting Zr- and Hf-MOFs in catalytic applications are highlighted.

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research Center for Inorganometallic Catalyst Design (ICDC); Northwestern Univ., Evanston, IL (United States); Energy Frontier Research Centers (EFRC) (United States). Argonne-Northwestern Solar Energy Research Center (ANSER)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES); US Defense Threat Reduction Agency; US Army Research Office (ARO); Swiss Science Foundation
Grant/Contract Number:
FG02-03ER15457; SC0012702; SC0001059; HDTRA10-1-0023; W911NF-13-1-0229; FG02-08ER15967
OSTI ID:
1871000
Journal Information:
ACS Catalysis, Vol. 7, Issue 2; ISSN 2155-5435
Publisher:
American Chemical Society (ACS)Copyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 276 works
Citation information provided by
Web of Science

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  • Journal of the American Chemical Society, Vol. 136, Issue 45, p. 15861-15864 https://doi.org/10.1021/ja508626n
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  • Journal of the American Chemical Society, Vol. 135, Issue 28, p. 10294-10297 https://doi.org/10.1021/ja4050828
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Mixed-linker approach in designing porous zirconium-based metal–organic frameworks with high hydrogen storage capacity journal January 2016
Textile/Metal-Organic-Framework Composites as Self-Detoxifying Filters for Chemical-Warfare Agents journal May 2015
Research Update: A hafnium-based metal-organic framework as a catalyst for regioselective ring-opening of epoxides with a mild hydride source journal December 2014
Nanoscale metal−organic frameworks for combined photodynamic & radiation therapy in cancer treatment journal August 2016
Tackling poison and leach: catalysis by dangling thiol–palladium functions within a porous metal–organic solid journal January 2015
Robust, Chiral, and Porous BINAP-Based Metal–Organic Frameworks for Highly Enantioselective Cyclization Reactions journal September 2015
Sintering-Resistant Single-Site Nickel Catalyst Supported by Metal–Organic Framework journal February 2016
The use of a rigid tritopic phosphonic ligand for the synthesis of a robust honeycomb-like layered zirconium phosphonate framework journal January 2014
Structural Transitions of the Metal-Oxide Nodes within Metal–Organic Frameworks: On the Local Structures of NU-1000 and UiO-66 journal March 2016
Electronic structure of porphyrin-based metal–organic frameworks and their suitability for solar fuel production photocatalysis journal January 2015
Zr-Fumarate MOF a Novel CO2-Adsorbing Material: Synthesis and Characterization journal January 2014
Highly selective and sensitive metal-organic framework fluorescent probe for Cu2+ through rational design of binding sites journal April 2016
A visually detectable pH responsive zirconium metal–organic framework journal January 2016
Metal–Organic Framework Nodes as Nearly Ideal Supports for Molecular Catalysts: NU-1000- and UiO-66-Supported Iridium Complexes journal June 2015
Enhanced visible-light photocatalytic performance of BiOBr/UiO-66(Zr) composite for dye degradation with the assistance of UiO-66 journal January 2015
Pilot-scale synthesis of a zirconium-benzenedicarboxylate UiO-66 for CO2 adsorption and catalysis journal May 2015
AIE-active tetraphenylethene functionalized metal–organic framework for selective detection of nitroaromatic explosives and organic photocatalysis journal January 2016
Amino-functionalized Zr-MOF nanoparticles for adsorption of CO 2 and CH 4 journal March 2013
Adding to the Arsenal of Zirconium-Based Metal-Organic Frameworks: the Topology as a Platform for Solvent-Assisted Metal Incorporation : Adding to the Arsenal of Zirconium-Based Metal-Organic Frameworks: the Topology as a Platform for Solvent-Assisted Metal Incorporation journal July 2016
Prediction of hydrogen storage properties of Zr-based MOFs journal April 2016
A molecular Pd( ii ) complex incorporated into a MOF as a highly active single-site heterogeneous catalyst for C–Cl bond activation journal January 2014
An Exceptionally Stable, Porphyrinic Zr Metal–Organic Framework Exhibiting pH-Dependent Fluorescence journal September 2013
Porphyrin-Metalation-Mediated Tuning of Photoredox Catalytic Properties in Metal–Organic Frameworks journal August 2015
Rigidifying Fluorescent Linkers by Metal–Organic Framework Formation for Fluorescence Blue Shift and Quantum Yield Enhancement journal May 2014
Friedel–Crafts Acylation of p-Xylene over Sulfonated Zirconium Terephthalates journal March 2014
Understanding the Thermodynamic and Kinetic Behavior of the CO 2 /CH 4 Gas Mixture within the Porous Zirconium Terephthalate UiO-66(Zr): A Joint Experimental and Modeling Approach journal June 2011
Selective oxidation of benzyl alcohol under solvent-free condition with gold nanoparticles encapsulated in metal-organic framework journal May 2014
Studies on Photocatalytic CO 2 Reduction over NH 2 -Uio-66(Zr) and Its Derivatives: Towards a Better Understanding of Photocatalysis on Metal-Organic Frameworks journal September 2013
Beyond post-synthesis modification: evolution of metal–organic frameworks via building block replacement journal January 2014
Porphyrinic Metal–Organic Framework Catalyzed Heck-Reaction: Fluorescence “Turn-On” Sensing of Cu(II) Ion journal September 2016
Oxygen sensing via phosphorescence quenching of doped metal–organic frameworks journal January 2012
Introduction of a mediator for enhancing photocatalytic performance via post-synthetic metal exchange in metal–organic frameworks (MOFs) journal January 2015
Instantaneous Hydrolysis of Nerve-Agent Simulants with a Six-Connected Zirconium-Based Metal-Organic Framework journal May 2015
Induced Chirality in a Metal-Organic Framework by Postsynthetic Modification for Highly Selective Asymmetric Aldol Reactions journal July 2014
Defects in Metal–Organic Frameworks: Challenge or Opportunity? journal August 2015
Highly dispersed Au nanoparticles immobilized on Zr-based metal–organic frameworks as heterostructured catalyst for CO oxidation journal January 2013
De Novo Tailoring Pore Morphologies and Sizes for Different Substrates in a Urea-Containing MOFs Catalytic Platform journal March 2016
Encapsulation of a Nerve Agent Detoxifying Enzyme by a Mesoporous Zirconium Metal–Organic Framework Engenders Thermal and Long-Term Stability journal June 2016
A Highly Stable Porphyrinic Zirconium Metal–Organic Framework with shp-a Topology journal December 2014
Perfluoroalkane Functionalization of NU-1000 via Solvent-Assisted Ligand Incorporation: Synthesis and CO2 Adsorption Studies
  • Deria, Pravas; Mondloch, Joseph E.; Tylianakis, Emmanuel
  • Journal of the American Chemical Society, Vol. 135, Issue 45, p. 16801-16804 https://doi.org/10.1021/ja408959g
journal October 2013
UiO-66-polyether block amide mixed matrix membranes for CO2 separation journal September 2016
BODIPY-containing nanoscale metal–organic frameworks for photodynamic therapy journal January 2016
Water-medium C–H activation over a hydrophobic perfluoroalkane-decorated metal-organic framework platform journal January 2016
Effective Adsorption and Enhanced Removal of Organophosphorus Pesticides from Aqueous Solution by Zr-Based MOFs of UiO-67 journal December 2014
A metal–organic framework immobilised iridium pincer complex journal January 2016
An amine-functionalized metal–organic framework as a sensing platform for DNA detection journal January 2014
High Efficiency Adsorption and Removal of Selenate and Selenite from Water Using Metal–Organic Frameworks journal June 2015
SERS-Active Metal–Organic Frameworks Embedding Gold Nanorods journal July 2011
Bias-Switchable Permselectivity and Redox Catalytic Activity of a Ferrocene-Functionalized, Thin-Film Metal–Organic Framework Compound journal February 2015
Nanoscale Metal–Organic Frameworks for Real-Time Intracellular pH Sensing in Live Cells journal August 2014
Photochemical Reduction of Low Concentrations of CO 2 in a Porous Coordination Polymer with a Ruthenium(II)-CO Complex journal January 2016
Tuning the optical properties of the zirconium–UiO-66 metal–organic framework for photocatalytic degradation of methyl orange journal February 2015
Noble-metal-free MoS2 co-catalyst decorated UiO-66/CdS hybrids for efficient photocatalytic H2 production journal May 2015
Enhancing CO 2 Separation Ability of a Metal-Organic Framework by Post-Synthetic Ligand Exchange with Flexible Aliphatic Carboxylates journal December 2013
Efficient extraction of sulfate from water using a Zr-metal–organic framework journal January 2016
Metal–Organic Framework Nodes Support Single-Site Magnesium–Alkyl Catalysts for Hydroboration and Hydroamination Reactions journal June 2016
A visible-light responsive zirconium metal–organic framework for living photopolymerization of methacrylates journal January 2016
Bifunctional iridium-(2-aminoterephthalate)–Zr-MOF chemoselective catalyst for the synthesis of secondary amines by one-pot three-step cascade reaction journal March 2013
Construction of Pt complex within Zr-based MOF and its application for hydrogen production under visible-light irradiation journal September 2016
Selective detection and controlled release of Aspirin over fluorescent amino-functionalized metal–organic framework in aqueous solution journal July 2016
Water-Stable Zirconium-Based Metal-Organic Framework Material with High-Surface Area and Gas-Storage Capacities journal August 2014
Merging metal–organic framework catalysis with organocatalysis: A thiourea functionalized heterogeneous catalyst at the nanoscale journal January 2014
A luminescent Zr-based metal–organic framework for sensing/capture of nitrobenzene and high-pressure separation of CH 4 /C 2 H 6 journal January 2015
Transparent Metal–Organic Framework/Polymer Mixed Matrix Membranes as Water Vapor Barriers journal April 2016
Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts journal August 2012
Application of metal and metal oxide nanoparticles@MOFs journal January 2016
Phosphotungstic acid encapsulated in metal-organic framework UiO-66: An effective catalyst for the selective oxidation of cyclopentene to glutaraldehyde journal July 2015
Metal–organic frameworks as heterogeneous catalysts for oxidation reactions journal January 2011
Recent advances in carbon dioxide capture with metal-organic frameworks journal August 2012
Carbonized Nanoscale Metal–Organic Frameworks as High Performance Electrocatalyst for Oxygen Reduction Reaction journal November 2014
Doping Metal–Organic Frameworks for Water Oxidation, Carbon Dioxide Reduction, and Organic Photocatalysis journal August 2011
Au@UiO-66: a base free oxidation catalyst journal January 2015
A porous proton-relaying metal-organic framework material that accelerates electrochemical hydrogen evolution journal September 2015
An Evaluation of UiO-66 for Gas-Based Applications journal September 2011
Hybrid Crystals Comprising Metal-Organic Frameworks and Functional Particles: Synthesis and Applications journal July 2014
Computational Design of Metal–Organic Frameworks Based on Stable Zirconium Building Units for Storage and Delivery of Methane journal September 2014
Metal–Organic Framework Thin Films as Platforms for Atomic Layer Deposition of Cobalt Ions To Enable Electrocatalytic Water Oxidation journal December 2015
Ligand Dynamics of Drug-Loaded Microporous Zirconium Terephthalates-Based Metal–Organic Frameworks: Impact of the Nature and Concentration of the Guest journal January 2014
Effect of amine modification on the properties of zirconium–carboxylic acid based materials and their applications as NO2 adsorbents at ambient conditions journal April 2014
MOF catalysis in relation to their homogeneous counterparts and conventional solid catalysts journal January 2014
Designing Heterogeneous Catalysts by Incorporating Enzyme-Like Functionalities into MOFs journal May 2010
Comparative study of titanium-functionalized UiO-66: support effect on the oxidation of cyclohexene using hydrogen peroxide journal January 2015
Evaluation of MOFs for air purification and air quality control applications: Ammonia removal from air journal March 2015
Utilizing mixed-linker zirconium based metal-organic frameworks to enhance the visible light photocatalytic oxidation of alcohol journal March 2015
Adsorptive separation of xenon/krypton mixtures using a zirconium-based metal-organic framework with high hydrothermal and radioactive stabilities journal December 2016
Surfactant-Mediated Conformal Overgrowth of Core-Shell Metal-Organic Framework Materials with Mismatched Topologies journal September 2015
Metal Nanocrystals Embedded in Single Nanocrystals of MOFs Give Unusual Selectivity as Heterogeneous Catalysts journal September 2014
Platinum nanoparticles encapsulated metal–organic frameworks for the electrochemical detection of telomerase activity journal January 2016
Amorphous metal–organic frameworks for drug delivery journal January 2015
A Hafnium-Based Metal–Organic Framework as a Nature-Inspired Tandem Reaction Catalyst journal October 2015
Modulated Hydrothermal Synthesis of UiO-66(Hf)-Type Metal–Organic Frameworks for Optimal Carbon Dioxide Separation journal January 2016
A Metal-Organic Framework/DNA Hybrid System as a Novel Fluorescent Biosensor for Mercury(II) Ion Detection journal December 2015
The dual capture of As V and As III by UiO-66 and analogues journal January 2016
Investigation of metal organic frameworks for the adsorptive removal of hydrochloride from dilute aqueous solution journal September 2016
Adsorption of fluoride to UiO-66-NH 2 in water: Stability, kinetic, isotherm and thermodynamic studies journal January 2016
Biomimetic Catalysis of a Porous Iron-Based Metal–Metalloporphyrin Framework journal November 2012
Recent advances in visible-light-responsive photocatalysts for hydrogen production and solar energy conversion – from semiconducting TiO2 to MOF/PCP photocatalysts journal January 2013
A Nitro-Functionalized Metal-Organic Framework as a Reaction-Based Fluorescence Turn-On Probe for Rapid and Selective H 2 S Detection journal June 2015
Elucidating Molecular Iridium Water Oxidation Catalysts Using Metal–Organic Frameworks: A Comprehensive Structural, Catalytic, Spectroscopic, and Kinetic Study journal November 2012
Water Stable Zr-Benzenedicarboxylate Metal-Organic Frameworks as Photocatalysts for Hydrogen Generation journal August 2010
Cooperative Cluster Metalation and Ligand Migration in Zirconium Metal-Organic Frameworks journal October 2015
Synthesis of nanocrystals of Zr-based metal–organic frameworks with csq-net: significant enhancement in the degradation of a nerve agent simulant journal January 2015
Defect-Engineered Metal-Organic Frameworks journal June 2015
Topotactic Transformations of Metal–Organic Frameworks to Highly Porous and Stable Inorganic Sorbents for Efficient Radionuclide Sequestration journal September 2014
Proline-functionalized metal–organic frameworks and their use in asymmetric catalysis: pitfalls in the MOFs rush journal January 2015
A fluorescent metal–organic framework for highly selective detection of nitro explosives in the aqueous phase journal January 2014
Seed-mediated growth of MOF-encapsulated Pd@Ag core–shell nanoparticles: toward advanced room temperature nanocatalysts journal January 2016
Improving the mechanical stability of zirconium-based metal–organic frameworks by incorporation of acidic modulators journal January 2015
Size-Controlled Synthesis of Porphyrinic Metal–Organic Framework and Functionalization for Targeted Photodynamic Therapy journal March 2016
Metals@MOFs - Loading MOFs with Metal Nanoparticles for Hybrid Functions journal July 2010
Mechanism for the Hydrolysis of Organophosphates by the Bacterial Phosphotriesterase † journal May 2004
Incorporation of iron hydrogenase active sites into a highly stable metal–organic framework for photocatalytic hydrogen generation journal January 2014
Porphyrinic metal-organic framework as electrochemical probe for DNA sensing via triple-helix molecular switch journal September 2015
Metal-Organic Framework-Based Nanomaterials for Electrocatalysis journal May 2016
A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
  • Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni
  • Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851 https://doi.org/10.1021/ja8057953
journal October 2008
Self-Supporting Metal-Organic Layers as Single-Site Solid Catalysts journal March 2016
Nano metal–organic framework (NMOF)-based strategies for multiplexed microRNA detection in solution and living cancer cells journal January 2015
Synthesis and Stability of Tagged UiO-66 Zr-MOFs journal December 2010
Dual-Function Metal–Organic Framework as a Versatile Catalyst for Detoxifying Chemical Warfare Agent Simulants journal October 2015
Ag2CO3/UiO-66(Zr) composite with enhanced visible-light promoted photocatalytic activity for dye degradation journal December 2015
Phosphorous-Nitrogen-Codoped Carbon Materials Derived from Metal-Organic Frameworks as Efficient Electrocatalysts for Oxygen Reduction Reactions: Phosphorous-Nitrogen-Codoped Carbon Materials journal November 2015
CH4 storage and CO2 capture in highly porous zirconium oxide based metal–organic frameworks journal January 2012
Immobilization of laccase via adsorption onto bimodal mesoporous Zr-MOF journal February 2016
Molybdenum Polysulfide Anchored on Porous Zr-Metal Organic Framework To Enhance the Performance of Hydrogen Evolution Reaction journal June 2016
Visible-Light Photoreduction of CO 2 in a Metal–Organic Framework: Boosting Electron–Hole Separation via Electron Trap States journal October 2015
Mechanochemical and solvent-free assembly of zirconium-based metal–organic frameworks journal January 2016
Synergetic catalysis of palladium nanoparticles encaged within amine-functionalized UiO-66 in the hydrodeoxygenation of vanillin in water journal January 2016
Handbook of Heterogeneous Catalysis book March 2008
Rational Tuning of Water Vapor and CO 2 Adsorption in Highly Stable Zr-Based MOFs journal October 2012
Effect of the functionalisation route on a Zr-MOF with an Ir–NHC complex for catalysis journal January 2015
Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks journal June 2012
Zr- and Hf-based nanoscale metal–organic frameworks as contrast agents for computed tomography journal January 2012
Structural determination of a highly stable metal-organic framework with possible application to interim radioactive waste scavenging: Hf-UiO-66 journal September 2012
The first example of a zirconium-oxide based metal–organic framework constructed from monocarboxylate ligands journal January 2015
Towards acid MOFs – catalytic performance of sulfonic acid functionalized architectures journal January 2013
How Impurities Affect CO 2 Capture in Metal–Organic Frameworks Modified with Different Functional Groups journal November 2014
Toward Inexpensive Photocatalytic Hydrogen Evolution: A Nickel Sulfide Catalyst Supported on a High-Stability Metal–Organic Framework journal August 2016
Metal–organic framework materials as catalysts journal January 2009
Production of ultra-deep sulfur-free diesels using a sustainable catalytic system based on UiO-66(Zr) journal January 2015
Adsorptive removal of diclofenac sodium from water with Zr-based metal–organic frameworks journal January 2016
Construction of Ultrastable Porphyrin Zr Metal–Organic Frameworks through Linker Elimination journal October 2013
Controllable Encapsulation of “Clean” Metal Clusters within MOFs through Kinetic Modulation: Towards Advanced Heterogeneous Nanocatalysts journal March 2016
Pd@UiO-66-Type MOFs Prepared by Chemical Vapor Infiltration as Shape-Selective Hydrogenation Catalysts: MOFs as Shape-Selective Hydrogenation Catalysts journal July 2015
Eu(III) functionalized Zr-based metal-organic framework as excellent fluorescent probe for Cd2+ detection in aqueous environment journal January 2016
Enhanced stability and CO2 affinity of a UiO-66 type metal–organic framework decorated with dimethyl groups journal January 2012
Highly dispersed palladium nanoparticles supported on amino functionalized metal-organic frameworks as an efficient and reusable catalyst for Suzuki cross-coupling reaction journal July 2014
Flexible Zirconium Metal-Organic Frameworks as Bioinspired Switchable Catalysts journal June 2016
Efficient molybdenum( vi ) modified Zr-MOF catalysts for epoxidation of olefins journal January 2014
A Highly Stable Zeotype Mesoporous Zirconium Metal-Organic Framework with Ultralarge Pores journal November 2014
Metal–Organic Frameworks Encapsulated in Photocleavable Capsules for UV-Light Triggered Catalysis journal August 2015
Exploring reverse shape selectivity and molecular sieving effect of metal-organic framework UIO-66 coated capillary column for gas chromatographic separation journal September 2012
A responsive MOF nanocomposite for decoding volatile organic compounds journal January 2016
Reverse shape selectivity in the adsorption of hexane and xylene isomers in MOF UiO-66 journal March 2011
Carbonylative Sonogashira coupling of terminal alkynes with aryl iodides under atmospheric pressure of CO using Pd( ii )@MOF as the catalyst journal January 2014
A dye-sensitized Pt@UiO-66(Zr) metal–organic framework for visible-light photocatalytic hydrogen production journal January 2014
A Ag–Pd alloy supported on an amine-functionalized UiO-66 as an efficient synergetic catalyst for the dehydrogenation of formic acid at room temperature journal January 2016
Zirconium-Based Metal–Organic Framework for Removal of Perrhenate from Water journal August 2016
Palladium Nanoparticles Supported on Zirconium Metal Organic Framework as an Efficient Heterogeneous Catalyst for the Suzuki–Miyaura Coupling Reaction journal December 2015
Ca 2+ , pH and thermo triple-responsive mechanized Zr-based MOFs for on-command drug release in bone diseases journal January 2016
Metal–Organic Framework (MOF) Defects under Control: Insights into the Missing Linker Sites and Their Implication in the Reactivity of Zirconium-Based Frameworks journal August 2015
Carbon Dioxide Capture in Metal–Organic Frameworks journal September 2011
Screening Lewis Pair Moieties for Catalytic Hydrogenation of CO 2 in Functionalized UiO-66 journal September 2015
Cooperative effect of temperature and linker functionality on CO2 capture from industrial gas mixtures in metal–organic frameworks: a combined experimental and molecular simulation study journal January 2012
Superior removal of arsenic from water with zirconium metal-organic framework UiO-66 journal November 2015
Ligand-based solid solution approach to stabilisation of sulphonic acid groups in porous coordination polymer Zr6O4(OH)4(BDC)6 (UiO-66) journal January 2012
Pre-concentration and energy transfer enable the efficient luminescence sensing of transition metal ions by metal–organic frameworks journal January 2015
Exploiting parameter space in MOFs: a 20-fold enhancement of phosphate-ester hydrolysis with UiO-66-NH 2 journal January 2015
Chemical, thermal and mechanical stabilities of metal–organic frameworks journal February 2016
Engineering UiO-66-NH 2 for Toxic Gas Removal journal January 2014
Photoresponsive spiropyran-functionalised MOF-808: postsynthetic incorporation and light dependent gas adsorption properties journal January 2016
Ultraporous, Water Stable, and Breathing Zirconium-Based Metal–Organic Frameworks with ftw Topology journal September 2015
Engineering Metal Organic Frameworks for Heterogeneous Catalysis journal August 2010
Modulation by Amino Acids: Toward Superior Control in the Synthesis of Zirconium Metal-Organic Frameworks journal August 2016
Effects of linker substitution on catalytic properties of porous zirconium terephthalate UiO-66 in acetalization of benzaldehyde with methanol journal February 2014
An efficient combination of Zr-MOF and microwave irradiation in catalytic Lewis acid Friedel–Crafts benzoylation journal January 2016
Metal–Organic Framework Materials as Chemical Sensors journal September 2011
Nanoscale UiO-MOF-based luminescent sensors for highly selective detection of cysteine and glutathione and their application in bioimaging journal January 2015
UiO-67-type Metal–Organic Frameworks with Enhanced Water Stability and Methane Adsorption Capacity journal February 2016
Nucleophilic addition of amines, alcohols, and thiophenol with epoxide/olefin using highly efficient zirconium metal organic framework heterogeneous catalyst journal January 2015
Deep desulfurization by oxidation using an active ionic liquid-supported Zr metal-organic framework as catalyst: Deep desulfurization using metal-organic framework journal December 2014
Homochiral Metal–Organic Frameworks for Asymmetric Heterogeneous Catalysis journal September 2011
An In Situ One-Pot Synthetic Approach towards Multivariate Zirconium MOFs journal April 2016
Porous metal–organic frameworks as platforms for functional applications journal January 2011
Stereoselective Halogenation of Integral Unsaturated C-C Bonds in Chemically and Mechanically Robust Zr and Hf MOFs journal February 2016
Enhanced Photocatalytic Activity of the AgI/UiO-66(Zr) Composite for Rhodamine B Degradation under Visible-Light Irradiation journal March 2015
Synthesis of well dispersed polymer grafted metal–organic framework nanoparticles journal January 2015
Highly efficient visible-light-driven CO 2 reduction to formate by a new anthracene-based zirconium MOF via dual catalytic routes journal January 2016
A Water Stable Metal-Organic Framework with Optimal Features for CO 2 Capture journal June 2013
Detoxification of Chemical Warfare Agents Using a Zr 6 -Based Metal-Organic Framework/Polymer Mixture journal September 2016
On thermal stability and catalytic reactivity of Zr-based metal–organic framework (UiO-67) encapsulated Pt catalysts journal August 2016
Asymmetric Catalysis with Chiral Porous Metal–Organic Frameworks: Critical Issues journal June 2011
Synthesis of two metal-porphyrin frameworks assembled from porphyrin building motifs, 5, 10, 15, 20-tetrapyridylporphyrin and their base catalyzed property journal November 2015
Nanoscale Metal–Organic Framework for Highly Effective Photodynamic Therapy of Resistant Head and Neck Cancer journal November 2014
A new metal–organic framework with high stability based on zirconium for sensing small molecules journal May 2013
The development of a novel HAuCl 4 @MOF catalyst and its catalytic application in the formation of dihydrochalcones journal January 2014
A Porous Zirconium-Based Metal-Organic Framework with the Potential for the Separation of Butene Isomers journal September 2016
Photocatalytic CO 2 reduction by a mixed metal (Zr/Ti), mixed ligand metal–organic framework under visible light irradiation journal January 2015
Zr IV Coordination Polymers Based on a Naturally Occurring Phenolic Derivative journal November 2014
A Breathing Zirconium Metal-Organic Framework with Reversible Loss of Crystallinity by Correlated Nanodomain Formation journal February 2016
U(VI) capture from aqueous solution by highly porous and stable MOFs: UiO-66 and its amine derivative journal April 2015
Modulator Effects on the Water-Based Synthesis of Zr/Hf Metal–Organic Frameworks: Quantitative Relationship Studies between Modulator, Synthetic Condition, and Performance journal March 2016
Single-Crystal-to-Single-Crystal Metalation of a Metal–Organic Framework: A Route toward Structurally Well-Defined Catalysts journal February 2015
Vanadium-Node-Functionalized UiO-66: A Thermally Stable MOF-Supported Catalyst for the Gas-Phase Oxidative Dehydrogenation of Cyclohexene journal June 2014
Hydrolysis of the RNA model substrate catalyzed by a binuclear Zr IV -substituted Keggin polyoxometalate journal January 2015
Highly Stable Mesoporous Zirconium Porphyrinic Frameworks with Distinct Flexibility journal March 2016
Metal–organic framework composites: from fundamentals to applications journal January 2015
Thermodynamically Guided Synthesis of Mixed-Linker Zr-MOFs with Enhanced Tunability journal May 2016
Preparation and catalytic properties of Pd nanoparticles supported on micro-crystal DUT-67 MOFs journal January 2015
Immobilizing CdS nanoparticles and MoS 2 /RGO on Zr-based metal–organic framework 12-tungstosilicate@UiO-67 toward enhanced photocatalytic H 2 evolution journal January 2016
A mixed dicarboxylate strut approach to enhancing catalytic activity of a de novo urea derivative of metal–organic framework UiO-67 journal January 2013
Direct Synthesis of Hierarchically Porous Metal–Organic Frameworks with High Stability and Strong Brønsted Acidity: The Decisive Role of Hafnium in Efficient and Selective Fructose Dehydration journal April 2016
Synthetic Access to Atomically Dispersed Metals in Metal–Organic Frameworks via a Combined Atomic-Layer-Deposition-in-MOF and Metal-Exchange Approach journal February 2016
Defect creation in metal-organic frameworks for rapid and controllable decontamination of roxarsone from aqueous solution journal January 2016
Zr-based metal–organic frameworks: design, synthesis, structure, and applications journal January 2016
Zirconium metal-organic framework supported highly-dispersed nanosized BiVO 4 for enhanced visible-light photocatalytic applications: UiO-66 supported highly-dispersed nanosized BiVO 4 journal February 2016
One-Pot Multifunctional Catalysis with NNN-Pincer Zr-MOF: Zr Base Catalyzed Condensation with Rh-Catalyzed Hydrogenation journal July 2013
Core–Shell Catalysts of Metal Nanoparticle Core and Metal–Organic Framework Shell journal November 2014
Applications of metal–organic frameworks in heterogeneous supramolecular catalysis journal January 2014
Tetrazine functionalized zirconium MOF as an optical sensor for oxidizing gases journal January 2015
Precise Modulation of the Breathing Behavior and Pore Surface in Zr-MOFs by Reversible Post-Synthetic Variable-Spacer Installation to Fine-Tune the Expansion Magnitude and Sorption Properties journal July 2016
Controlling Catalytic Properties of Pd Nanoclusters through Their Chemical Environment at the Atomic Level Using Isoreticular Metal–Organic Frameworks journal April 2016
Superacidity in Sulfated Metal–Organic Framework-808 journal September 2014
Are Zr 6 -based MOFs water stable? Linker hydrolysis vs. capillary-force-driven channel collapse journal January 2014
Hybrid porous solids past, present, future journal January 2008
Privileged Phosphine-Based Metal–Organic Frameworks for Broad-Scope Asymmetric Catalysis journal February 2014
Water Stability and Adsorption in Metal–Organic Frameworks journal September 2014
Enantiopure Peptide-Functionalized Metal–Organic Frameworks journal July 2015
Real-Time Monitoring of Dissolved Oxygen with Inherent Oxygen-Sensitive Centers in Metal–Organic Frameworks journal April 2016
Tuning Zr 6 Metal–Organic Framework (MOF) Nodes as Catalyst Supports: Site Densities and Electron-Donor Properties Influence Molecular Iridium Complexes as Ethylene Conversion Catalysts journal December 2015
Single-Site Cobalt Catalysts at New Zr 8 (μ 2 -O) 8 (μ 2 -OH) 4 Metal-Organic Framework Nodes for Highly Active Hydrogenation of Alkenes, Imines, Carbonyls, and Heterocycles journal September 2016
Drastic Enhancement of the CO 2 Adsorption Properties in Sulfone-Functionalized Zr- and Hf-UiO-67 MOFs with Hierarchical Mesopores journal December 2013
Pd(0)@UiO-68-AP: chelation-directed bifunctional heterogeneous catalyst for stepwise organic transformations journal January 2016
Chemoselective reduction of α,β-unsaturated carbonyl compounds with UiO-66 materials journal August 2016
Tuning the cavities of zirconium-based MIL-140 frameworks to modulate CO 2 adsorption journal January 2015
Room-temperature acetylene hydration by a Hg( ii )-laced metal–organic framework journal January 2015
Inserting CO 2 into Aryl C−H Bonds of Metal-Organic Frameworks: CO 2 Utilization for Direct Heterogeneous C−H Activation journal April 2016
Functionalized metal organic framework-polyimide mixed matrix membranes for CO2/CH4 separation journal September 2012
Pt Nanoparticles@Photoactive Metal–Organic Frameworks: Efficient Hydrogen Evolution via Synergistic Photoexcitation and Electron Injection journal April 2012
Active site engineering in UiO-66 type metal–organic frameworks by intentional creation of defects: a theoretical rationalization journal January 2015
Functionalized UiO-66 by Single and Binary (OH) 2 and NO 2 Groups for Uptake of CO 2 and CH 4 journal January 2016
Selective Photooxidation of a Mustard-Gas Simulant Catalyzed by a Porphyrinic Metal-Organic Framework journal June 2015
Electrochemistry within metal-organic frameworks book

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
metal-organic framework
zirconium
hafnium
catalysis
node
linker
encapsulation