Mesoporous mixed metal oxides derived from P123-templated Mg-Al layered double hydroxides
- College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China)
- College of Chemical Engineering, Harbin Institute of Technology, Harbin 150001 (China)
We report the preparation of mesoporous mixed metal oxides (MMOs) through a soft template method. Different amounts of P123 were used as structure directing agent to synthesize P123-templated Mg-Al layered double hydroxides (LDHs). After calcination of as-synthesized LDHs at 500 {sup o}C, the ordered mesopores were obtained by removal of P123. The mesoporous Mg-Al MMOs fabricated by using 2 wt% P123 exhibited a high specific surface area of 108.1 m{sup 2}/g, and wide distribution of pore size (2-18 nm). An investigation of the 'memory effect' of the mesoporous MMOs revealed that they were successfully reconstructed to ibuprofen intercalated LDHs having different gallery heights, which indicated different intercalation capacities. Due to their mesoporosity these unique MMOs have particular potential as drug or catalyst carriers. - Graphical abstract: Ordered mesoporous Mg-Al MMOs can be obtained through the calcination of P123-templated Mg-Al-CO{sub 3} LDHs. The pore diameter is 2.2 nm. At the presence of ibuprofen, the Mg-Al MMOs can recover to Mg-Al-IBU LDHs, based on its 'remember effect'. Display Omitted
- OSTI ID:
- 21491785
- Journal Information:
- Journal of Solid State Chemistry, Vol. 183, Issue 11; Other Information: DOI: 10.1016/j.jssc.2010.08.027; PII: S0022-4596(10)00361-0; Copyright (c) 2010 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; ISSN 0022-4596
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
ALUMINIUM HYDROXIDES
ALUMINIUM OXIDES
CALCINATION
CATALYSTS
CLATHRATES
DRUGS
MAGNESIUM CARBONATES
MAGNESIUM HYDROXIDES
MAGNESIUM OXIDES
NANOSTRUCTURES
SPECIFIC SURFACE AREA
ALKALINE EARTH METAL COMPOUNDS
ALUMINIUM COMPOUNDS
CARBON COMPOUNDS
CARBONATES
CHALCOGENIDES
CHEMICAL REACTIONS
DECOMPOSITION
HYDROGEN COMPOUNDS
HYDROXIDES
MAGNESIUM COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PHYSICAL PROPERTIES
PYROLYSIS
THERMOCHEMICAL PROCESSES