Mesoporous mixed metal oxides derived from P123-templated Mg-Al layered double hydroxides

Journal Article · Sun Nov 14 23:00:00 EST 2010 · Journal of Solid State Chemistry

DOI:https://doi.org/10.1016/j.jssc.2010.08.027· OSTI ID:21491785

Jideng, Zhou; Zhanshuang, Li; Yang, He; Shuangshuang, Lin; Qi, Liu ^[1]; Milin, Zhang ^[1]; Zhaohua, Jiang ^[2]

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1. College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China)
2. College of Chemical Engineering, Harbin Institute of Technology, Harbin 150001 (China)

We report the preparation of mesoporous mixed metal oxides (MMOs) through a soft template method. Different amounts of P123 were used as structure directing agent to synthesize P123-templated Mg-Al layered double hydroxides (LDHs). After calcination of as-synthesized LDHs at 500 {sup o}C, the ordered mesopores were obtained by removal of P123. The mesoporous Mg-Al MMOs fabricated by using 2 wt% P123 exhibited a high specific surface area of 108.1 m{sup 2}/g, and wide distribution of pore size (2-18 nm). An investigation of the 'memory effect' of the mesoporous MMOs revealed that they were successfully reconstructed to ibuprofen intercalated LDHs having different gallery heights, which indicated different intercalation capacities. Due to their mesoporosity these unique MMOs have particular potential as drug or catalyst carriers. - Graphical abstract: Ordered mesoporous Mg-Al MMOs can be obtained through the calcination of P123-templated Mg-Al-CO{sub 3} LDHs. The pore diameter is 2.2 nm. At the presence of ibuprofen, the Mg-Al MMOs can recover to Mg-Al-IBU LDHs, based on its 'remember effect'. Display Omitted

• OSTI ID: 21491785
• Journal Information: Journal of Solid State Chemistry, Journal Name: Journal of Solid State Chemistry Journal Issue: 11 Vol. 183; ISSN 0022-4596; ISSN JSSCBI
• Country of Publication: United States
• Language: English

Related Subjects

77 NANOSCIENCE AND NANOTECHNOLOGY
ALKALINE EARTH METAL COMPOUNDS
ALUMINIUM COMPOUNDS
ALUMINIUM HYDROXIDES
ALUMINIUM OXIDES
CALCINATION
CARBON COMPOUNDS
CARBONATES
CATALYSTS
CHALCOGENIDES
CHEMICAL REACTIONS
CLATHRATES
DECOMPOSITION
DRUGS
HYDROGEN COMPOUNDS
HYDROXIDES
MAGNESIUM CARBONATES
MAGNESIUM COMPOUNDS
MAGNESIUM HYDROXIDES
MAGNESIUM OXIDES
NANOSTRUCTURES
OXIDES
OXYGEN COMPOUNDS
PHYSICAL PROPERTIES
PYROLYSIS
SPECIFIC SURFACE AREA
THERMOCHEMICAL PROCESSES