Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Acetate intercalated Mg–Al layered double hydroxides (LDHs) through modified amide hydrolysis: a new route to synthesize novel mixed metal oxides (MMOs) for CO 2 capture

Journal Article · · Dalton Transactions
DOI:https://doi.org/10.1039/D1DT00602A· OSTI ID:1782388

SEM images of MMOs derived from Mg–Al-acetate intercalated LDHs synthesized by acetamide hydrolysis with (a) Mg/Al = 3, (b) Mg/Al = 4 and their high temperature CO 2 capture capacity versus temperature (c) were obtained.

Sponsoring Organization:
USDOE
OSTI ID:
1782388
Journal Information:
Dalton Transactions, Journal Name: Dalton Transactions Journal Issue: 21 Vol. 50; ISSN 1477-9226; ISSN ICHBD9
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

References (60)

New Synthetic Routes to Hydrotalcite-Like Compounds − Characterisation and Properties of the Obtained Materials journal October 1998
Nanosheets of Oxides and Hydroxides: Ultimate 2D Charge-Bearing Functional Crystallites journal October 2010
Valuing Metal-Organic Frameworks for Postcombustion Carbon Capture: A Benchmark Study for Evaluating Physical Adsorbents journal August 2017
DFT-Based Simulation and Experimental Validation of the Topotactic Transformation of MgAl Layered Double Hydroxides journal August 2016
Layered Double Hydroxide (LDH)‐Derived Mixed Metal Oxides (MMOs): A Systematic Crystal‐Chemical Approach to Investigating the Chemical Composition and its Effect on High Temperature CO 2 capture. journal May 2020
Synthesis of the Benzoate Intercalated Layered Double ­Hydroxide of Nickel and Aluminum: Application of Mering's Rule: Benzoate Intercalated Layered Double Hydroxide of Ni and Al journal October 2013
Ageing behaviour of unary hydroxides in trivalent metal salt solutions: Formation of layered double hydroxide (LDH)-like phases journal October 2000
High temperature adsorption of CO2 on various hydrotalcite-like compounds journal February 2008
Topotaxy, nucleation and growth journal November 1990
Hydrotalcite-type anionic clays: Preparation, properties and applications. journal December 1991
Preparation of cadmium hydroxyapatite particles using acetamide journal February 2001
Hydrotalcite-like compounds as adsorbents for carbon dioxide journal September 2002
Solvent-free liquid phase oxidation of benzyl alcohol to benzaldehyde by molecular oxygen using non-noble transition metal containing hydrotalcite-like solid catalysts journal April 2003
High temperature adsorption of CO2 on Mg–Al hydrotalcite: Effect of the charge compensating anions and the synthesis pH journal April 2011
A review on strategies to LDH-based materials to improve adsorption capacity and photoreduction efficiency for CO2 journal May 2019
Elevated temperature CO2 capture on nano-structured MgO–Al2O3 aerogel: Effect of Mg/Al molar ratio journal April 2014
Adsorption of carbon dioxide on hydrotalcite-like compounds of different compositions journal September 2011
Synthesis of elevated temperature CO2 adsorbents from aqueous miscible organic-layered double hydroxides journal January 2019
Results of the 18-month test with MEA at the post-combustion capture pilot plant at Niederaussem – new impetus to solvent management, emissions and dynamic behaviour journal April 2020
Progress in hydrotalcite like compounds and metal-based oxides for CO 2 capture: a review journal September 2015
An in-situ IR study on the adsorption of CO2 and H2O on hydrotalcites journal March 2018
Impact of organic interlayer anions on the CO 2 adsorption performance of Mg-Al layered double hydroxides derived mixed oxides journal May 2017
Reversible hydration and aqueous exfoliation of the acetate-intercalated layered double hydroxide of Ni and Al: Observation of an ordered interstratified phase journal December 2012
CO2 sorption on hydrotalcite and alkali-modified (K and Cs) hydrotalcites at high temperatures journal August 2008
Mapping the Birth and Evolution of Pores upon Thermal Activation of Layered Hydroxides journal March 2017
Adsorption of CO 2 on MgAl-CO 3 LDHs-Derived Sorbents with 3D Nanoflower-like Structure journal January 2018
CO 2 Capture and Utilization Editorial journal April 2020
Stabilization of Layered Double Oxide in Hybrid Matrix of Graphene and Layered Metal Oxide Nanosheets: An Effective Way To Explore Efficient CO 2 Adsorbent journal October 2016
High-Temperature CO 2 Sorption on Hydrotalcite Having a High Mg/Al Molar Ratio journal February 2016
Trends in Solid Adsorbent Materials Development for CO 2 Capture journal June 2019
Reduced to Hierarchy: Carbon Filament-Supported Mixed Metal Oxide Nanoparticles journal November 2019
Rapid Exchange between Atmospheric CO 2 and Carbonate Anion Intercalated within Magnesium Rich Layered Double Hydroxide journal October 2014
Amine-Based CO 2 Capture Technology Development from the Beginning of 2013—A Review journal January 2015
Hydrothermal Synthesis of Layered Double Hydroxide−Deoxycholate Intercalation Compounds journal November 2000
Graphene Oxide as Support for Layered Double Hydroxides: Enhancing the CO 2 Adsorption Capacity journal November 2012
Markedly Improved CO 2 Capture Efficiency and Stability of Gallium Substituted Hydrotalcites at Elevated Temperatures journal July 2009
Layered Double Hydroxide Stability. 1. Relative Stabilities of Layered Double Hydroxides and Their Simple Counterparts journal February 1999
High-Performance CO 2 Adsorbent from Interlayer Potassium-Promoted Stearate-Pillared Hydrotalcite Precursors journal August 2013
Adsorption of Carbon Dioxide onto Hydrotalcite-like Compounds (HTlcs) at High Temperatures journal January 2001
Influence of Water on High-Temperature CO 2 Capture Using Layered Double Hydroxide Derivatives journal April 2008
Post-Combustion CO2 Capture Using Solid Sorbents: A Review journal September 2011
Adsorption of CO 2 on Hydrotalcite-Derived Mixed Oxides: Sorption Mechanisms and Consequences for Adsorption Irreversibility journal March 2010
Unique Layered Double Hydroxide Morphologies Using Reverse Microemulsion Synthesis journal November 2005
A Reexamination of Hydrotalcite Crystal Chemistry journal January 1996
Homogeneous Precipitation by Formamide Hydrolysis: Synthesis, Reversible Hydration, and Aqueous Exfoliation of the Layered Double Hydroxide (LDH) of Ni and Al journal October 2010
Water-Swellable MgAl−LDH (Layered Double Hydroxide) Hybrids: Synthesis, Characterization, and Film Preparation journal April 2008
Acceleration of global warming due to carbon-cycle feedbacks in a coupled climate model journal November 2000
Synthesis of Al-rich hydrotalcite-like compounds by using the urea hydrolysis reaction—control of size and morphology journal January 2003
Exfoliation of layered double hydroxides (LDHs): a new route to mineralize atmospheric CO 2 journal January 2014
Ultra-high aspect ratio hybrid materials: the role of organic guest and synthesis method journal January 2018
The effect of the layer-interlayer chemistry of LDHs on developing high temperature carbon capture materials journal January 2020
CCCLXVII.—The hydrolysis of acetamide journal January 1930
Synthesis of organo-layered double hydroxides by an environmentally friendly co-hydration route journal January 2007
Efficient synthesis of ordered organo-layered double hydroxides journal January 2010
Worldwide innovations in the development of carbon capture technologies and the utilization of CO2 journal January 2012
Synthesis of high-temperature CO2 adsorbents from organo-layered double hydroxides with markedly improved CO2 capture capacity journal January 2012
Layered double hydroxides supported on multi-walled carbon nanotubes: preparation and CO2 adsorption characteristics journal January 2012
Comprehensive investigation of CO2 adsorption on Mg–Al–CO3 LDH-derived mixed metal oxides journal January 2013
Formation of Hydroxyapatite Whiskers by Hydrothermal Homogeneous Precipitation Using Acetamide: Formation of Hydroxyapatite Whiskers journal February 2011
Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report) journal October 2015

Similar Records

Reversible hydration and aqueous exfoliation of the acetate-intercalated layered double hydroxide of Ni and Al: Observation of an ordered interstratified phase
Journal Article · Fri Dec 14 23:00:00 EST 2012 · Journal of Solid State Chemistry · OSTI ID:22149954

Mesoporous mixed metal oxides derived from P123-templated Mg-Al layered double hydroxides
Journal Article · Sun Nov 14 23:00:00 EST 2010 · Journal of Solid State Chemistry · OSTI ID:21491785

Solubility and release of fenbufen intercalated in Mg, Al and Mg, Al, Fe layered double hydroxides (LDH): The effect of Eudragit S 100 covering
Journal Article · Tue Dec 14 23:00:00 EST 2010 · Journal of Solid State Chemistry · OSTI ID:21504032

Related Subjects