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Pt redistribution during Ni(Pt) silicide formation

Journal Article · · Applied Physics Letters
DOI:https://doi.org/10.1063/1.3058719· OSTI ID:21175838
; ;  [1]; ;  [2];  [3];  [4];  [5]
  1. Instituut voor Kern-en Stralingsfysica and INPAC, KULeuven, B-3001 Leuven (Belgium)
  2. Vakgroep Vaste-stofwetenschappen, Universiteit Gent, B-9000 Gent (Belgium)
  3. Department of Physics, University of Cape Town, Rondebosch 7700 (South Africa)
  4. Instituto Tecnologico e Nuclear, Estrada Nacional 10, Apartado 21, 2686-953 Sacavem, Portugal and Centro de Fisica Nuclear da Universidade de Lisboa, Av. Prof. Gama Pinto 2, 1699 Lisboa Codex (Portugal)
  5. Instituto Superior de Engenharia do Porto, R. S. Tome, 4200 Porto (Portugal)

We report on a real-time Rutherford backscattering spectrometry study of the erratic redistribution of Pt during Ni silicide formation in a solid phase reaction. The inhomogeneous Pt redistribution in Ni(Pt)Si films is a consequence of the low solubility of Pt in Ni{sub 2}Si compared to NiSi and the limited mobility of Pt in NiSi. Pt further acts as a diffusion barrier and resides in the Ni{sub 2}Si grain boundaries, significantly slowing down the Ni{sub 2}Si and NiSi growth kinetics. Moreover, the observed incorporation of a large amount of Pt in the NiSi seeds indicates that Pt plays a major role in selecting the crystallographic orientation of these seeds and thus in the texture of the resulting Ni{sub 1-x}Pt{sub x}Si film.

OSTI ID:
21175838
Journal Information:
Applied Physics Letters, Journal Name: Applied Physics Letters Journal Issue: 26 Vol. 93; ISSN APPLAB; ISSN 0003-6951
Country of Publication:
United States
Language:
English

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