Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Time-resolved electron energy distribution functions at the substrate during a HiPIMS discharge with cathode voltage reversal

Journal Article · · Plasma Sources Science and Technology
Abstract

The time-dependent plasma properties of a high-power impulse magnetron sputtering plasma are investigated which include a positive ‘kick’ pulse on the sputtering target 2μs after the main negative pulse, this reversing the voltage on the cathode. At a substrate 15 cm distant from the magnetron, the time-dependent electron energy distribution function (EEDF), plasma potential, potential commute time and plasma diffusion properties are measured using a single Langmuir probe. Results show that the positive pulse on the target expels plasma and raises the plasma potential across the chamber on the order of 1 to 2μs, which is the time scale of the electron diffusion. The EEDF at the substrate fits a Druyvesteyn distribution during the main negative pulse rising slightly in average energy over time. The distribution is still Druyvesteyn and at the very start of the positive pulse, but then loses the higher energy electrons and drops in average electron energy as the positive pulse progresses. A Boltzmann equation solver, BOLSIG+, was used to predict the EEDF at the substrate during the positive pulse and it agrees best with the measurements assuming a value of 0.2 Td for theE/N(electric field/gas number density).

Research Organization:
Starfire Industries, LLC, Champaign, IL (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0020689
OSTI ID:
1979316
Journal Information:
Plasma Sources Science and Technology, Journal Name: Plasma Sources Science and Technology Journal Issue: 6 Vol. 31; ISSN 0963-0252
Publisher:
IOP Publishing
Country of Publication:
United States
Language:
English

References (28)

High power impulse magnetron sputtering discharge
  • Gudmundsson, J. T.; Brenning, N.; Lundin, D.
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 30, Issue 3 https://doi.org/10.1116/1.3691832
journal May 2012
Improved film density for coatings at grazing angle of incidence in high power impulse magnetron sputtering with positive pulse journal July 2020
Anomalous behaviors of plasma parameters in unbalanced direct-current magnetron discharge journal July 2004
Langmuir probe measurement of electron temperature in a Druyvesteyn electron plasma journal June 1973
Spatial and temporal behavior of the plasma parameters in a pulsed magnetron discharge journal December 2002
Time‐ and space‐resolved radio‐frequency plasma electron energy distributions from a displacement‐current‐based electric probe diagnostic journal March 1993
Plasma Expansion into a Vacuum journal May 2003
Linear magnetron HiPIMS high deposition rate magnet pack journal September 2018
Plasma dynamic in chromium and titanium HIPIMS discharges journal December 2007
On the electron energy distribution in the gas discharge positive column: Langmuir paradox journal September 2013
Measurements of time varying plasma potential, temperature, and density in a 13.56 MHz radio‐frequency discharge
  • Wilson, Jeffrey L.; Caughman, J. B. O.; Nguyen, Phi Long
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 7, Issue 3 https://doi.org/10.1116/1.575830
journal May 1989
Evolution of the electron energy distribution and plasma parameters in a pulsed magnetron discharge journal May 2001
Time-resolved Langmuir probe investigation of hybrid high power impulse magnetron sputtering discharges journal April 2013
Time-resolved Langmuir probe diagnostics of a bipolar high power impulse magnetron sputtering discharge journal February 2020
Ion energy measurements at the surface of an ion cyclotron range of frequencies antenna Faraday shield
  • Caughman, J. B. O.; Ruzic, D. N.; Hoffman, D. J.
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 8, Issue 6 https://doi.org/10.1116/1.576437
journal November 1990
Investigating the plasma parameters and discharge asymmetry in dual magnetron reactive high power impulse magnetron sputtering discharge with Al in Ar/O2 mixture journal May 2020
Cu films prepared by bipolar pulsed high power impulse magnetron sputtering journal April 2018
Plasma parameters in positive voltage pulses of bipolar HiPIMS discharge determined by Langmuir probe with a sub-microsecond time resolution journal August 2020
Study of plasma dynamics in a modulated pulsed power magnetron discharge using a time-resolved Langmuir probe journal January 2011
Bipolar HiPIMS for tailoring ion energies in thin film deposition journal February 2019
LXCat: an Open-Access, Web-Based Platform for Data Needed for Modeling Low Temperature Plasmas: LXCat: an Open-Access, Web-Based Platform for… journal September 2016
Electron energy distributions and plasma parameters in high-power pulsed magnetron sputtering discharges journal February 2009
On the electron energy in the high power impulse magnetron sputtering discharge journal June 2009
Solving the Boltzmann equation to obtain electron transport coefficients and rate coefficients for fluid models journal October 2005
Angular dependence of plasma parameters and film properties during high power impulse magnetron sputtering for deposition of Ti and TiO2 layers journal May 2017
Copper thin films deposited using different ion acceleration strategies in HiPIMS journal September 2021
Plasma diagnostics of low pressure high power impulse magnetron sputtering assisted by electron cyclotron wave resonance plasma journal November 2012
Electron energy distribution function in a dc magnetron sputtering discharge journal August 1992

Similar Records

Time-resolved ion energy distribution functions during a HiPIMS discharge with cathode voltage reversal
Journal Article · Mon Dec 05 23:00:00 EST 2022 · Physica Scripta · OSTI ID:2421634

Electron dynamics in radio frequency magnetron sputtering argon discharges with a dielectric target
Journal Article · Sun Feb 28 23:00:00 EST 2021 · Plasma Sources Science and Technology · OSTI ID:1850776

On the electron energy in the high power impulse magnetron sputtering discharge
Journal Article · Mon Jun 15 00:00:00 EDT 2009 · Journal of Applied Physics · OSTI ID:21352245

Related Subjects