Selective Electrochemical Capture and Release of Uranyl in Solution (Final Report)
- Univ. of California, Santa Barbara, CA (United States)
The goal of this project is to investigate the selective, electrochemical capture and release of uranyl ((UO2)2+) from biphasic or heterogeneous mixtures using a class of cluster molecules, ortho-carboranes (Cb), containing selective binding groups. Possible applications in PUREX, seawater uranyl extraction, or in actinide/lanthanide (An/Ln) or Ln/Ln separations are envisioned. With this funding, we sought to achieve these goals by harnessing the redox-switchable chelating properties of the “closo” Cb to the reduced “nido” Cb enabling the electrochemical control of the ligand bite angle. Using this premise, specific goals include: 1) integrating new selective coordinating groups (L) onto the carbon positions of Cb for the selective capture and release of uranyl, and; 2) anchoring these selective carboranes onto electrode and/or heterogeneous surfaces for the selective, heterogeneous capture and release of uranyl from aqueous solutions under flow conditions. Overall, this work focuses on advancing our understanding and controlling the properties of this new platform for metal capture and release chemistry which, we believe, has the potential for broader applicability in the separation sciences.
- Research Organization:
- Univ. of California, Santa Barbara, CA (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- DOE Contract Number:
- SC0021649
- OSTI ID:
- 1972704
- Report Number(s):
- DOE-UCSB-SC0021649; TRN: US2406115
- Country of Publication:
- United States
- Language:
- English
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