Selective electrochemical capture and release of uranyl from aqueous alkali, lanthanide, and actinide mixtures using redox-switchable carboranes

Keener, Megan; Mattejat, Maxwell; Zheng, Shao-Liang; Wu, Guang; Hayton, Trevor W.; Ménard, Gabriel

doi:10.1039/D1SC07070C

Selective electrochemical capture and release of uranyl from aqueous alkali, lanthanide, and actinide mixtures using redox-switchable carboranes

Journal Article · Thu Mar 24 00:00:00 EDT 2022 · Chemical Science

DOI:https://doi.org/10.1039/D1SC07070C· OSTI ID:1846487

^[1]; Mattejat, Maxwell ^[1]; ^[2]; Wu, Guang ^[1]; ^[1]; ^[1]

Department of Chemistry and Biochemistry, University of California, Santa Barbara, California 93106, USA
Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, USA

Redox-switchable carboranes electrochemically capture and release UO ₂ ²⁺ selectively from mixed metal aqueous solutions, mimicking in part spent nuclear fuel.

View Journal Article

Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0001861; SC0021649

OSTI ID:: 1846487

Alternate ID(s):: OSTI ID: 1972697

Journal Information:: Chemical Science, Journal Name: Chemical Science Journal Issue: 12 Vol. 13; ISSN 2041-6520; ISSN CSHCBM

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

References (26)

Remarkable Luminescence Properties of Lanthanide Complexes with Asymmetric Dodecahedron Structures Miyata, Kohei; Nakagawa, Tetsuya; Kawakami, Ryuhei Chemistry – A European Journal, Vol. 17, Issue 2 https://doi.org/10.1002/chem.201001993	journal	November 2010
Introducing a Hydrogen-Bond Donor into a Weakly Nucleophilic Brønsted Base: Alkali Metal Hexamethyldisilazides (MHMDS, M=Li, Na, K, Rb and Cs) with Ammonia Neufeld, Roman; Michel, Reent; Herbst-Irmer, Regine Chemistry - A European Journal, Vol. 22, Issue 35 https://doi.org/10.1002/chem.201600833	journal	July 2016
Self-Assembly of Hexanuclear Clusters of 4f and 5f Elements with Cation Specificity Diwu, Juan; Good, Justin J.; DiStefano, Victoria H. European Journal of Inorganic Chemistry, Vol. 2011, Issue 9 https://doi.org/10.1002/ejic.201100066	journal	February 2011
The absorption and fluorescence spectra of uranyl nitrate solutions at room temperature Pant, D. D.; Khandelwal, D. P. Proceedings of the Indian Academy of Sciences - Section A, Vol. 50, Issue 5 https://doi.org/10.1007/BF03048924	journal	November 1959
A novel cesium–carborane cluster: synthesis and structure of [Cs5–(C2B9H12)4Cl]n Oki, Aderemi R.; Sokolova, Olga; Gilbes, Blanca Inorganic Chemistry Communications, Vol. 5, Issue 9 https://doi.org/10.1016/S1387-7003(02)00538-5	journal	September 2002
Nuclear power for sustainable development: Current status and future prospects Adamantiades, A.; Kessides, I. Energy Policy, Vol. 37, Issue 12 https://doi.org/10.1016/j.enpol.2009.07.052	journal	December 2009
A review on UREX processes for nuclear spent fuel reprocessing Kumari, Indu; Kumar, B. V. R.; Khanna, Ashok Nuclear Engineering and Design, Vol. 358 https://doi.org/10.1016/j.nucengdes.2019.110410	journal	March 2020
A comparison of analogous 4f- and 5f-element compounds: syntheses and crystal structures of triphenylphosphine oxide complexes of lanthanide(III) and uranium(III) triflates and iodides [MX2(OPPh3)4][X] (X=OTf and M=Ce or U; X=I and M=Nd, Ce, La, U) Berthet, Jean-Claude; Nierlich, Martine; Ephritikhine, Michel Polyhedron, Vol. 22, Issue 27 https://doi.org/10.1016/j.poly.2003.09.008	journal	December 2003
Binuclear complexes of lanthanides with 1,4-bis(diphenylphosphino)butane dioxide Spichal, Zdenek; Necas, Marek; Pinkas, Jiri Polyhedron, Vol. 25, Issue 3 https://doi.org/10.1016/j.poly.2005.08.007	journal	February 2006
Tuning the Separation of Light Lanthanides Using a Reverse-Size Selective Aqueous Complexant Thiele, Nikki A.; Fiszbein, David J.; Woods, Joshua J. Inorganic Chemistry, Vol. 59, Issue 22 https://doi.org/10.1021/acs.inorgchem.0c02413	journal	October 2020
Involvement of 5f Orbitals in the Covalent Bonding between the Uranyl Ion and Trialkyl Phosphine Oxide: Unraveled by Oxygen K-Edge X-ray Absorption Spectroscopy and Density Functional Theory Zhang, Yusheng; Duan, Wuhua; Yang, Yuning Inorganic Chemistry, Vol. 61, Issue 1 https://doi.org/10.1021/acs.inorgchem.1c02236	journal	November 2021
Structural Studies of Cesium, Lithium/Cesium, and Sodium/Cesium Bis(trimethylsilyl)amide (HMDS) Complexes Ojeda-Amador, Ana I.; Martínez-Martínez, Antonio J.; Kennedy, Alan R. Inorganic Chemistry, Vol. 55, Issue 11 https://doi.org/10.1021/acs.inorgchem.6b00839	journal	May 2016
On the Nature of the Carbonyl versus Phosphoryl Binding in Uranyl Nitrate Complexes Raychaudhuri, Diganta; Gopakumar, Gopinadhanpillai; Nagarajan, Sivaraman The Journal of Physical Chemistry A, Vol. 124, Issue 38 https://doi.org/10.1021/acs.jpca.0c07007	journal	August 2020
Symmetric Phthalocyanine Charge Carrier for Dual Redox Flow Battery/Capacitor Applications Hunt, Camden; Mattejat, Maxwell; Anderson, Cassidy ACS Applied Energy Materials, Vol. 2, Issue 8 https://doi.org/10.1021/acsaem.9b01317	journal	August 2019
Rational Design of Sequestering Agents for Plutonium and Other Actinides Gorden, Anne E. V.; Xu, Jide; Raymond, Kenneth N. Chemical Reviews, Vol. 103, Issue 11 https://doi.org/10.1021/cr990114x	journal	November 2003
Hydrolysis of Uranyl(VI) in Acidic and Basic Aqueous Solutions Using a Noncomplexing Organic Base: A Multivariate Spectroscopic and Statistical Study Quilès, Fabienne; Nguyen-Trung, Chinh; Carteret, Cédric Inorganic Chemistry, Vol. 50, Issue 7 https://doi.org/10.1021/ic101953q	journal	April 2011
Periodic Trends in Actinide Phosphonates: Divergence and Convergence between Thorium, Uranium, Neptunium, and Plutonium Systems Nelson, Anna-Gay D.; Bray, Travis H.; Stanley, Forrest A. Inorganic Chemistry, Vol. 48, Issue 10 https://doi.org/10.1021/ic900484w	journal	May 2009
Cyclometalation and Solvent Deoxygenation during Reduction of a Homoleptic Th(OAr) ₄ Complex: Serendipitous Formation of a Terminally Bonded Th−OH Function Korobkov, Ilia; Arunachalampillai, Athimoolan; Gambarotta, Sandro Organometallics, Vol. 23, Issue 26 https://doi.org/10.1021/om049369d	journal	November 2004
Synthesis and Crystal Structure of the First Polymeric Cesium Compound of a Carborane Ligand System Hosmane, Narayan S.; Demissie, Temesgen; Zhang, Hongming Organometallics, Vol. 17, Issue 3 https://doi.org/10.1021/om970938+	journal	January 1998
Redox-switchable carboranes for uranium capture and release Keener, Megan; Hunt, Camden; Carroll, Timothy G. Nature, Vol. 577, Issue 7792 https://doi.org/10.1038/s41586-019-1926-4	journal	January 2020
Polyethyleneimine methylphosphonate: towards the design of a new class of macromolecular actinide chelating agents in the case of human exposition Lahrouch, Florian; Sofronov, Oleksandr; Creff, Gaëlle Dalton Trans., Vol. 46, Issue 40 https://doi.org/10.1039/C7DT02643A	journal	January 2017
A slowly magnetic relaxing Sm ^III monomer with a D _5h equatorial compressed ligand field Pan, Yong-Ze; Hua, Qiu-Yan; Lin, Li-Shan Inorganic Chemistry Frontiers, Vol. 7, Issue 12 https://doi.org/10.1039/D0QI00326C	journal	January 2020
Simultaneous separation and recovery of Cs(I) and Sr(II) using a hybrid macrocyclic compounds loaded adsorbent. Kinetic, equilibrium and dynamic adsorption studies Wu, Yan; Zhang, XiaoXia; Kim, Seong-Yun Journal of Nuclear Science and Technology, Vol. 53, Issue 12 https://doi.org/10.1080/00223131.2016.1175979	journal	May 2016
Nuclear Eclectic Power Rose, D. J. Science, Vol. 184, Issue 4134 https://doi.org/10.1126/science.184.4134.351	journal	April 1974
The Use of Surrogates in Waste Immobilization Studies: A Case Study of Plutonium Bingham, Paul A.; Hand, Russell J.; Stennett, Martin C. MRS Proceedings, Vol. 1107 https://doi.org/10.1557/PROC-1107-421	journal	January 2008
Purex Process for Plutonium and Uranium Recovery Lanham, W. B.; Runion, T. C. https://doi.org/10.2172/4165457	report	October 1949

Similar Records

Selective Electrochemical Capture and Release of Uranyl in Solution (Final Report)

Technical Report · Mon May 08 00:00:00 EDT 2023 · OSTI ID:1972704

Selective heterogeneous capture and release of actinides using carborane-functionalized electrodes

Journal Article · Thu Jul 20 00:00:00 EDT 2023 · ChemComm · OSTI ID:2421949

Selective electrochemical capture and release of uranyl from aqueous alkali, lanthanide, and actinide mixtures using redox-switchable carboranes

Citation Formats

References (26)

Similar Records

Related Subjects