Cathode pre-lithiation/sodiation for next-generation batteries

Dose, Wesley M.; Johnson, Christopher S.

doi:10.1016/j.coelec.2021.100827

Cathode pre-lithiation/sodiation for next-generation batteries

Journal Article · Tue Aug 10 00:00:00 EDT 2021 · Current Opinion in Electrochemistry

DOI:https://doi.org/10.1016/j.coelec.2021.100827· OSTI ID:1923244

^[1]; ^[2]

Univ. of Cambridge (United Kingdom)
Argonne National Lab. (ANL), Argonne, IL (United States)

Electrochemical energy storage is playing a pivotal role in the global pursuit of a clean and sustainable energy future. Lithium-ion batteries (LIBs) are the state-of-the-art technology, but future energy requirements demand higher energy densities and a more diverse battery landscape to meet a wide variety of applications. Unfortunately, many next-generation LIB chemistries and beyond-LIB technologies suffer from large first-cycle irreversible capacity caused by active ion loss. The field of pre-lithiation/sodiation has recently emerged as researchers attempt to mitigate active ion loss and boost the energy density of next-generation LIBs and sodium-ion batteries. Herein, we highlight recent advances in cathode pre-lithiation/sodiation using sacrificial additives and pre-lithiation/sodiation of cathode active materials.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: Engineering and Physical Sciences Research Council (EPSRC); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1923244

Journal Information:: Current Opinion in Electrochemistry, Journal Name: Current Opinion in Electrochemistry Vol. 31; ISSN 2451-9103

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (58)

High‐Efficiency Cathode Sodium Compensation for Sodium‐Ion Batteries Niu, Yu‐Bin; Guo, Yu‐Jie; Yin, Ya‐Xia Advanced Materials, Vol. 32, Issue 33 https://doi.org/10.1002/adma.202001419	journal	July 2020
Pre‐Lithiation Strategies for Next‐Generation Practical Lithium‐Ion Batteries Jin, Liming; Shen, Chao; Wu, Qiang Advanced Science, Vol. 8, Issue 12 https://doi.org/10.1002/advs.202005031	journal	March 2021
Lithium Sulfide/Metal Nanocomposite as a High-Capacity Cathode Prelithiation Material Sun, Yongming; Lee, Hyun-Wook; Seh, Zhi Wei Advanced Energy Materials, Vol. 6, Issue 12 https://doi.org/10.1002/aenm.201600154	journal	May 2016
Challenges and Recent Progress in the Development of Si Anodes for Lithium-Ion Battery Jin, Yan; Zhu, Bin; Lu, Zhenda Advanced Energy Materials, Vol. 7, Issue 23 https://doi.org/10.1002/aenm.201700715	journal	September 2017
Li ₂ O:Li–Mn–O Disordered Rock‐Salt Nanocomposites as Cathode Prelithiation Additives for High‐Energy Density Li‐Ion Batteries Diaz‐Lopez, Maria; Chater, Philip A.; Bordet, Pierre Advanced Energy Materials, Vol. 10, Issue 7 https://doi.org/10.1002/aenm.201902788	journal	January 2020
Integration of Graphite and Silicon Anodes for the Commercialization of High‐Energy Lithium‐Ion Batteries Chae, Sujong; Choi, Seong‐Hyeon; Kim, Namhyung Angewandte Chemie International Edition, Vol. 59, Issue 1 https://doi.org/10.1002/anie.201902085	journal	January 2020
Highly Efficient, Cost Effective, and Safe Sodiation Agent for High-Performance Sodium-Ion Batteries Shanmukaraj, Devaraj; Kretschmer, Katja; Sahu, Tuhin ChemSusChem, Vol. 11, Issue 18 https://doi.org/10.1002/cssc.201801099	journal	August 2018
Synthesis and host properties of tetragonal Li2Mn2O4 and Li2Co0.4Mn1.6O4 West, K.; Vitins, G.; Koksbang, R. Electrochimica Acta, Vol. 45, Issue 19 https://doi.org/10.1016/S0013-4686(00)00395-9	journal	June 2000
Li2CuO2 as an additive for capacity enhancement of lithium ion cells Vitins, G.; Raekelboom, E. A.; Weller, M. T. Journal of Power Sources, Vol. 119-121 https://doi.org/10.1016/S0378-7753(03)00236-2	journal	June 2003
Sacrificial salts: Compensating the initial charge irreversibility in lithium batteries Shanmukaraj, Devaraj; Grugeon, Sylvie; Laruelle, Stéphane Electrochemistry Communications, Vol. 12, Issue 10 https://doi.org/10.1016/j.elecom.2010.07.016	journal	October 2010
A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries Verma, Pallavi; Maire, Pascal; Novák, Petr Electrochimica Acta, Vol. 55, Issue 22, p. 6332-6341 https://doi.org/10.1016/j.electacta.2010.05.072	journal	September 2010
Li2NiO2 as a sacrificing positive additive for lithium-ion batteries Park, Hosang; Yoon, Taeho; Kim, Young-Ugk Electrochimica Acta, Vol. 108 https://doi.org/10.1016/j.electacta.2013.06.117	journal	October 2013
Stabilized Li3N for efficient battery cathode prelithiation Sun, Yongming; Li, Yanbin; Sun, Jie Energy Storage Materials, Vol. 6 https://doi.org/10.1016/j.ensm.2016.10.004	journal	January 2017
Understanding and improving the initial Coulombic efficiency of high-capacity anode materials for practical sodium ion batteries He, Hanna; Sun, Dan; Tang, Yougen Energy Storage Materials, Vol. 23 https://doi.org/10.1016/j.ensm.2019.05.008	journal	December 2019
A new pre-sodiation additive for sodium-ion batteries Jo, Jae Hyeon; Choi, Ji Ung; Park, Yun Ji Energy Storage Materials, Vol. 32 https://doi.org/10.1016/j.ensm.2020.07.002	journal	November 2020
Electrocatalytic-driven compensation for sodium ion pouch cell with high energy density and long lifespan Zhang, Qi; Gao, Xuan-Wen; Shi, Ying Energy Storage Materials, Vol. 39 https://doi.org/10.1016/j.ensm.2021.04.011	journal	August 2021
Manipulating irreversible phase transition of NaCrO2 towards an effective sodium compensation additive for superior sodium-ion full cells Shen, Bolei; Zhan, Renming; Dai, Chunlong Journal of Colloid and Interface Science, Vol. 553 https://doi.org/10.1016/j.jcis.2019.06.056	journal	October 2019
A new strategy to mitigate the initial capacity loss of lithium ion batteries Su, Xin; Lin, Chikai; Wang, Xiaoping Journal of Power Sources, Vol. 324 https://doi.org/10.1016/j.jpowsour.2016.05.063	journal	August 2016
NaN 3 addition, a strategy to overcome the problem of sodium deficiency in P2-Na 0.67 [Fe 0.5 Mn 0.5 ]O 2 cathode for sodium-ion battery Martinez De Ilarduya, Jaione; Otaegui, Laida; López del Amo, Juan Miguel Journal of Power Sources, Vol. 337 https://doi.org/10.1016/j.jpowsour.2016.10.084	journal	January 2017
A new approach for compensating the irreversible capacity loss of high-energy Si/C\|LiNi 0.5 Mn 1.5 O 4 lithium-ion batteries Gabrielli, Giulio; Marinaro, Mario; Mancini, Marilena Journal of Power Sources, Vol. 351 https://doi.org/10.1016/j.jpowsour.2017.03.051	journal	May 2017
How to overcome Na deficiency in full cell using P2-phase sodium cathode – A proof of concept study of Na-rhodizonate used as sodium reservoir Marelli, Elena; Marino, Cyril; Bolli, Christoph Journal of Power Sources, Vol. 450 https://doi.org/10.1016/j.jpowsour.2019.227617	journal	February 2020
Challenges of today for Na-based batteries of the future: From materials to cell metrics Hasa, Ivana; Mariyappan, Sathiya; Saurel, Damien Journal of Power Sources, Vol. 482 https://doi.org/10.1016/j.jpowsour.2020.228872	journal	January 2021
Electrochemical and Chemical Properties of Na₂NiO₂ as a Cathode Additive for a Rechargeable Sodium Battery Park, Kyusung; Yu, Byeong-Chul; Goodenough, John B. Chemistry of Materials, Vol. 27, Issue 19 https://doi.org/10.1021/acs.chemmater.5b02684	journal	September 2015
Dual Stabilization and Sacrificial Effect of Na ₂ CO ₃ for Increasing Capacities of Na-Ion Cells Based on P2-Na _x MO ₂ Electrodes Sathiya, Mariyappan; Thomas, Joy; Batuk, Dmitry Chemistry of Materials, Vol. 29, Issue 14 https://doi.org/10.1021/acs.chemmater.7b01542	journal	July 2017
Promises and Challenges of Next-Generation “Beyond Li-ion” Batteries for Electric Vehicles and Grid Decarbonization Tian, Yaosen; Zeng, Guobo; Rutt, Ann Chemical Reviews, Vol. 121, Issue 3 https://doi.org/10.1021/acs.chemrev.0c00767	journal	December 2020
Conformal Prelithiation Nanoshell on LiCoO ₂ Enabling High-Energy Lithium-Ion Batteries Liu, Xiaoxiao; Tan, Yuchen; Wang, Wenyu Nano Letters, Vol. 20, Issue 6 https://doi.org/10.1021/acs.nanolett.0c01413	journal	May 2020
In Situ Chemical Synthesis of Lithium Fluoride/Metal Nanocomposite for High Capacity Prelithiation of Cathodes Sun, Yongming; Lee, Hyun-Wook; Zheng, Guangyuan Nano Letters, Vol. 16, Issue 2 https://doi.org/10.1021/acs.nanolett.5b05228	journal	January 2016
Metal/LiF/Li₂O Nanocomposite for Battery Cathode Prelithiation: Trade-off between Capacity and Stability Du, Junmou; Wang, Wenyu; Sheng Eng, Alex Yong Nano Letters, Vol. 20, Issue 1 https://doi.org/10.1021/acs.nanolett.9b04278	journal	November 2019
Dual-Functional Cathodic Prelithiation Reagent of Li₃P in Lithium-Ion Battery for Compensating Initial Capacity Loss and Enhancing Safety Wang, Xiaoyi; Liu, Cheng; Zhang, Shaojie ACS Applied Energy Materials, Vol. 4, Issue 5 https://doi.org/10.1021/acsaem.1c00773	journal	April 2021
Liquid Ammonia Chemical Lithiation: An Approach for High-Energy and High-Voltage Si–Graphite\|Li _{1+ x} Ni _0.5 Mn _1.5 O ₄ Li-Ion Batteries Dose, Wesley M.; Blauwkamp, James; Piernas-Muñoz, María José ACS Applied Energy Materials, Vol. 2, Issue 7 https://doi.org/10.1021/acsaem.9b00695	journal	June 2019
Improved Sodiation Additive and Its Nuances in the Performance Enhancement of Sodium-Ion Batteries Fernández-Ropero, Antonio J.; Zarrabeitia, Maider; Baraldi, Giorgio ACS Applied Materials & Interfaces, Vol. 13, Issue 10 https://doi.org/10.1021/acsami.0c20542	journal	March 2021
Insights on Electrochemical Behaviors of Sodium Peroxide as a Sacrificial Cathode Additive for Boosting Energy Density of Na-Ion Battery Guo, Yu-Jie; Niu, Yu-Bin; Wei, Zheng ACS Applied Materials & Interfaces, Vol. 13, Issue 2 https://doi.org/10.1021/acsami.0c20870	journal	January 2021
New Insight into Ethylenediaminetetraacetic Acid Tetrasodium Salt as a Sacrificing Sodium Ion Source for Sodium-Deficient Cathode Materials for Full Cells Jo, Jae Hyeon; Choi, Ji Ung; Park, Yun Ji ACS Applied Materials & Interfaces, Vol. 11, Issue 6 https://doi.org/10.1021/acsami.8b18488	journal	January 2019
Using Mixed Salt Electrolytes to Stabilize Silicon Anodes for Lithium-Ion Batteries via in Situ Formation of Li–M–Si Ternaries (M = Mg, Zn, Al, Ca) Han, Binghong; Liao, Chen; Dogan, Fulya ACS Applied Materials & Interfaces, Vol. 11, Issue 33 https://doi.org/10.1021/acsami.9b07270	journal	July 2019
Presodiation Strategies and Their Effect on Electrode–Electrolyte Interphases for High-Performance Electrodes for Sodium-Ion Batteries Moeez, Iqra; Jung, Hun-Gi; Lim, Hee-Dae ACS Applied Materials & Interfaces, Vol. 11, Issue 44 https://doi.org/10.1021/acsami.9b14381	journal	October 2019
Prelithiated Li-Enriched Gradient Interphase toward Practical High-Energy NMC–Silicon Full Cell Liu, Xiaoxiao; Liu, Tongchao; Wang, Rui ACS Energy Letters, Vol. 6, Issue 2 https://doi.org/10.1021/acsenergylett.0c02487	journal	December 2020
Prelithiation: A Crucial Strategy for Boosting the Practical Application of Next-Generation Lithium Ion Battery Wang, Fei; Wang, Bo; Li, Jingxuan ACS Nano, Vol. 15, Issue 2 https://doi.org/10.1021/acsnano.0c10664	journal	February 2021
LiFeO ₂ -Incorporated Li ₂ MoO ₃ as a Cathode Additive for Lithium-Ion Battery Safety Park, Kyu-Sung; Im, Dongmin; Benayad, Anass Chemistry of Materials, Vol. 24, Issue 14 https://doi.org/10.1021/cm300505y	journal	July 2012
In Situ Mitigation of First-Cycle Anode Irreversibility in a New Spinel/FeSb Lithium-Ion Cell Enabled via a Microwave-Assisted Chemical Lithiation Process Moorhead-Rosenberg, Zachary; Allcorn, Eric; Manthiram, Arumugam Chemistry of Materials, Vol. 26, Issue 20 https://doi.org/10.1021/cm5024426	journal	October 2014
High-capacity battery cathode prelithiation to offset initial lithium loss Sun, Yongming; Lee, Hyun-Wook; Seh, Zhi Wei Nature Energy, Vol. 1, Issue 1 https://doi.org/10.1038/nenergy.2015.8	journal	January 2016
Prospects for lithium-ion batteries and beyond—a 2030 vision Grey, Clare P.; Hall, David S. Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-19991-4	journal	December 2020
LiMn2O4 spinel and substituted cathodes Thackeray, Michael M.; Amine, Khalil Nature Energy, Vol. 6, Issue 5 https://doi.org/10.1038/s41560-021-00815-8	journal	May 2021
Li ₂ O ₂ as a cathode additive for the initial anode irreversibility compensation in lithium-ion batteries Bie, Yitian; Yang, Jun; Wang, Jiulin Chemical Communications, Vol. 53, Issue 59 https://doi.org/10.1039/C7CC04646D	journal	January 2017
Running out of lithium? A route to differentiate between capacity losses and active lithium losses in lithium-ion batteries Holtstiege, Florian; Wilken, Andrea; Winter, Martin Physical Chemistry Chemical Physics, Vol. 19, Issue 38 https://doi.org/10.1039/C7CP05405J	journal	January 2017
Controllable charge capacity using a black additive for high-energy-density sodium-ion batteries Jo, Chang-Heum; Choi, Ji Ung; Yashiro, Hitoshi Journal of Materials Chemistry A, Vol. 7, Issue 8 https://doi.org/10.1039/C8TA09833F	journal	January 2019
Progress and perspectives on pre-lithiation technologies for lithium ion capacitors Jin, Liming; Shen, Chao; Shellikeri, Annadanesh Energy & Environmental Science, Vol. 13, Issue 8 https://doi.org/10.1039/D0EE00807A	journal	January 2020
Optimisation of sodium-based energy storage cells using pre-sodiation: a perspective on the emerging field Dewar, Daniel; Glushenkov, Alexey M. Energy & Environmental Science, Vol. 14, Issue 3 https://doi.org/10.1039/D0EE02782K	journal	January 2021
Sodium citrate as a self-sacrificial sodium compensation additive for sodium-ion batteries Zhang, Rui; Tang, Zheng; Sun, Dan Chemical Communications, Vol. 57, Issue 35 https://doi.org/10.1039/D1CC01292D	journal	January 2021
Dual functionality of over-lithiated NMC for high energy silicon-based lithium-ion batteries Dose, Wesley M.; Kim, Soojeong; Liu, Qian Journal of Materials Chemistry A, Vol. 9, Issue 21 https://doi.org/10.1039/D1TA01290H	journal	January 2021
Layered vanadium and molybdenum oxides: batteries and electrochromics Chernova, Natasha A.; Roppolo, Megan; Dillon, Anne C. Journal of Materials Chemistry, Vol. 19, Issue 17 https://doi.org/10.1039/b819629j	journal	January 2009
Preparation and Electrochemical Characterization of Overlithiated Spinel LiMn2 O 4 Peramunage, D.; Abraham, K. M. Journal of The Electrochemical Society, Vol. 145, Issue 4 https://doi.org/10.1149/1.1838428	journal	April 1998
Li Metal-Free Rechargeable Batteries Based on Li[sub 1+x]Mn[sub 2]O[sub 4] Cathodes (0 ≤ x ≤ 1) and Carbon Anodes Tarascon, J. M. Journal of The Electrochemical Society, Vol. 138, Issue 10 https://doi.org/10.1149/1.2085331	journal	January 1991
Beneficial Effect of Li ₅ FeO ₄ Lithium Source for Li-Ion Batteries with a Layered NMC Cathode and Si Anode Dose, Wesley M.; Villa, Cesar; Hu, Xiaobing Journal of The Electrochemical Society, Vol. 167, Issue 16 https://doi.org/10.1149/1945-7111/abd1ef	journal	December 2020
Lithium Oxalate as Capacity and Cycle-Life Enhancer in LNMO/Graphite and LNMO/SiG Full Cells Solchenbach, Sophie; Wetjen, Morten; Pritzl, Daniel Journal of The Electrochemical Society, Vol. 165, Issue 3 https://doi.org/10.1149/2.0611803jes	journal	January 2018
Role of Li ₆ CoO ₄ Cathode Additive in Li-Ion Cells Containing Low Coulombic Efficiency Anode Material Noh, Mijung; Cho, Jaephil Journal of The Electrochemical Society, Vol. 159, Issue 8 https://doi.org/10.1149/2.085208jes	journal	January 2012
An Approach for Pre-Lithiation of Li _{1+ x} Ni _0.5 Mn _1.5 O ₄ Cathodes Mitigating Active Lithium Loss Betz, Johannes; Nowak, Laura; Winter, Martin Journal of The Electrochemical Society, Vol. 166, Issue 15 https://doi.org/10.1149/2.1221914jes	journal	January 2019
Assessment of Li-Inventory in Cycled Si-Graphite Anodes Using LiFePO ₄ as a Diagnostic Cathode Dose, Wesley M.; Maroni, Victor A.; Piernas-Muñoz, Maria Jose Journal of The Electrochemical Society, Vol. 165, Issue 10 https://doi.org/10.1149/2.1271810jes	journal	January 2018
Pre-Lithiation Strategies for Rechargeable Energy Storage Technologies: Concepts, Promises and Challenges Holtstiege, Florian; Bärmann, Peer; Nölle, Roman Batteries, Vol. 4, Issue 1 https://doi.org/10.3390/batteries4010004	journal	January 2018

Similar Records

Research Progress and Perspectives on Pre‐Sodiation Strategies for Sodium‐Ion Batteries

Journal Article · Sun Aug 11 20:00:00 EDT 2024 · Advanced Functional Materials · OSTI ID:2570355

Progress and Perspectives on Pre-lithiation Technologies for Lithium Ion Capacitors

Journal Article · Sat Aug 01 00:00:00 EDT 2020 · Energy & Environmental Science · OSTI ID:1668806

In Situ, Atomic‐Resolution Observation of Lithiation and Sodiation of WS ₂ Nanoflakes: Implications for Lithium‐Ion and Sodium‐Ion Batteries

Journal Article · Wed May 12 20:00:00 EDT 2021 · Small · OSTI ID:1782891

Related Subjects

25 ENERGY STORAGE
Pre-lithiation
electrochemical energy storage
irreversible capacity
lithium-ion batteries
pre-sodiation
sodium-ion batteries
solid electrolyte interphase

Cathode pre-lithiation/sodiation for next-generation batteries

Citation Formats

References (58)

Similar Records

Related Subjects