Strategies for design and synthesis of porous liquids toward carbon capture and separation

Mokhtarinori, Narges; Yang, Zhenzhen; Dai, Sheng

doi:10.1016/j.cogsc.2022.100705

Strategies for design and synthesis of porous liquids toward carbon capture and separation

Journal Article · Wed Sep 21 00:00:00 EDT 2022 · Current Opinion in Green and Sustainable Chemistry

DOI:https://doi.org/10.1016/j.cogsc.2022.100705· OSTI ID:1905369

Mokhtarinori, Narges ^[1]; Yang, Zhenzhen ^[2]; Dai, Sheng ^[3]

Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Porous liquids (PLs) represent a promising category of sorbents in carbon capture and separation capable of integrating the advantages of flowing liquid and porous solid systems. Well-defined pores were engineered into liquid sorbents via liquifying molecules with stiff interior voids, dissolving rigid porous hosts in flowing liquids, or dispersing porous frameworks in high steric hindrance solvents, producing type I, II, or III PLs, respectively. Unique features of PLs have triggered broad interest in exploring their applications in carbon capture and separation, in which diverse design strategies, synthesis approaches, and enhanced performance have been reported. Here, in this minireview, recent progress in the design, synthesis, and structural engineering of PLs and efforts towards the optimization of their carbon capture and separation behavior will be summarized, including the comparison between PLs with varied types. Porosity engineering into liquid sorbents provides opportunities to resolve challenging issues in conventional sorption and separation systems.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1905369

Alternate ID(s):: OSTI ID: 1962214

Journal Information:: Current Opinion in Green and Sustainable Chemistry, Journal Name: Current Opinion in Green and Sustainable Chemistry Vol. 38; ISSN 2452-2236

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (60)

Modular Type III Porous Liquids Based on Porous Organic Cage Microparticles Kai, Aiting; Egleston, Benjamin D.; Tarzia, Andrew Advanced Functional Materials, Vol. 31, Issue 51 https://doi.org/10.1002/adfm.202106116	journal	September 2021
Engineering Permanent Porosity into Liquids Jie, Kecheng; Zhou, Yujuan; Ryan, Hugh P. Advanced Materials, Vol. 33, Issue 18 https://doi.org/10.1002/adma.202005745	journal	March 2021
Porous Ionic Liquids: Structure, Stability, and Gas Absorption Mechanisms Avila, Jocasta; Červinka, Ctirad; Dugas, Pierre‐Yves Advanced Materials Interfaces, Vol. 8, Issue 9 https://doi.org/10.1002/admi.202001982	journal	March 2021
Carbon Dioxide Capture by Superbase-Derived Protic Ionic Liquids Wang, Congmin; Luo, Huimin; Jiang, De-en Angewandte Chemie, Vol. 122, Issue 34 https://doi.org/10.1002/ange.201002641	journal	July 2010
Tuning the Basicity of Ionic Liquids for Equimolar CO2 Capture Wang, Congmin; Luo, Xiaoyan; Luo, Huimin Angewandte Chemie International Edition, Vol. 50, Issue 21 https://doi.org/10.1002/anie.201008151	journal	March 2011
Porous Liquids: A Promising Class of Media for Gas Separation Zhang, Jinshui; Chai, Song-Hai; Qiao, Zhen-An Angewandte Chemie International Edition, Vol. 54, Issue 3 https://doi.org/10.1002/anie.201409420	journal	November 2014
Electrostatic-Assisted Liquefaction of Porous Carbons Li, Peipei; Schott, Jennifer A.; Zhang, Jinshui Angewandte Chemie International Edition, Vol. 56, Issue 47 https://doi.org/10.1002/anie.201708843	journal	October 2017
Porous Ionic Liquids or Liquid Metal-Organic Frameworks? Costa Gomes, Margarida; Pison, Laure; Červinka, Ctirad Angewandte Chemie International Edition, Vol. 57, Issue 37 https://doi.org/10.1002/anie.201805495	journal	August 2018
Transforming Porous Organic Cages into Porous Ionic Liquids via a Supramolecular Complexation Strategy Jie, Kecheng; Onishi, Nicole; Schott, Jennifer A. Angewandte Chemie International Edition, Vol. 59, Issue 6 https://doi.org/10.1002/anie.201912068	journal	February 2020
High‐Performance Porous Ionic Liquids for Low‐Pressure CO ₂ Capture** Avila, Jocasta; Lepre, L. Fernando; Santini, Catherine C. Angewandte Chemie International Edition, Vol. 60, Issue 23 https://doi.org/10.1002/anie.202100090	journal	May 2021
Porous Metal–Organic Framework Liquids for Enhanced CO ₂ Adsorption and Catalytic Conversion Zou, Yu‐Huang; Huang, Yuan‐Biao; Si, Duan‐Hui Angewandte Chemie International Edition, Vol. 60, Issue 38 https://doi.org/10.1002/anie.202107156	journal	August 2021
Porous Liquids O'Reilly, Niamh; Giri, Nicola; James, Stuart L. Chemistry - A European Journal, Vol. 13, Issue 11 https://doi.org/10.1002/chem.200700090	journal	April 2007
Exploring Opportunities for Platinum Nanoparticles Encapsulated in Porous Liquids as Hydrogenation Catalysts Hemming, Ellen B.; Masters, Anthony F.; Maschmeyer, Thomas Chemistry – A European Journal, Vol. 26, Issue 31 https://doi.org/10.1002/chem.201905288	journal	March 2020
Effect of Pore Size on the Carbon Dioxide Adsorption Behavior of Porous Liquids Based on Hollow Silica Shi, Ting; Zheng, Yaping; Wang, Tianyu ChemPhysChem, Vol. 19, Issue 1 https://doi.org/10.1002/cphc.201700842	journal	December 2017
Adsorbent Materials for Carbon Dioxide Capture from Large Anthropogenic Point Sources Choi, Sunho; Drese, Jeffrey H.; Jones, Christopher W. ChemSusChem, Vol. 2, Issue 9, p. 796-854 https://doi.org/10.1002/cssc.200900036	journal	September 2009
Composite Porous Liquid for Recyclable Sequestration, Storage and In Situ Catalytic Conversion of Carbon Dioxide at Room Temperature Bhattacharjee, Archita; Kumar, Raj; Sharma, Kamendra P. ChemSusChem, Vol. 14, Issue 16 https://doi.org/10.1002/cssc.202100931	journal	July 2021
Hollow Silica‐Based Porous Liquids Functionalized Mixed Matrix Membranes for CO ₂ Capture Liu, Shuo; Meng, Long; Fan, Jinwen ChemistrySelect, Vol. 6, Issue 20 https://doi.org/10.1002/slct.202100664	journal	May 2021
An In Situ Coupling Strategy toward Porous Carbon Liquid with Permanent Porosity Li, Peipei; Wang, Dechao; Zhang, Lu Small, Vol. 17, Issue 10 https://doi.org/10.1002/smll.202006687	journal	January 2021
Tuning the CO2 adsorption by the selection of suitable ionic liquids at ZIF-8 confinement: A DFT study Thomas, Anoopa; Prakash, Muthuramalingam Applied Surface Science, Vol. 491 https://doi.org/10.1016/j.apsusc.2019.06.130	journal	October 2019
Porous liquids based on porous cages, metal organic frameworks and metal organic polyhedra Bavykina, Anastasiya; Cadiau, Amandine; Gascon, Jorge Coordination Chemistry Reviews, Vol. 386 https://doi.org/10.1016/j.ccr.2019.01.015	journal	May 2019
Zeolitic imidazolate frameworks-based porous liquids with low viscosity for CO2 and toluene uptakes Li, Xiaoqian; Wang, Dechao; He, Zhongjie Chemical Engineering Journal, Vol. 417 https://doi.org/10.1016/j.cej.2021.129239	journal	August 2021
Porous Liquids: The Next Frontier Fulvio, Pasquale Fernando; Dai, Sheng Chem, Vol. 6, Issue 12 https://doi.org/10.1016/j.chempr.2020.11.005	journal	December 2020
A bifunctional zeolitic porous liquid with incompatible Lewis pairs for antagonistic cascade catalysis Chen, Hao; Yang, Zhenzhen; Peng, Honggen Chem, Vol. 7, Issue 12 https://doi.org/10.1016/j.chempr.2021.08.022	journal	December 2021
Extraction desulphurization of fuels using ZIF-8-based porous liquid Wu, Jimin; Wu, Xumin; Zhao, Pingping Fuel, Vol. 300 https://doi.org/10.1016/j.fuel.2021.121013	journal	September 2021
Enhanced CO2 capture by binary systems of pyridinium-based ionic liquids and porous ZIF-8 particles Wang, Xue; Shang, Dawei; Zeng, Shaojuan The Journal of Chemical Thermodynamics, Vol. 128 https://doi.org/10.1016/j.jct.2018.08.038	journal	January 2019
Performance of nitrile-containing anions in task-specific ionic liquids for improved CO2/N2 separation Mahurin, Shannon M.; Lee, Je Seung; Baker, Gary A. Journal of Membrane Science, Vol. 353, Issue 1-2 https://doi.org/10.1016/j.memsci.2010.02.045	journal	May 2010
Nanoscopic characterization of type II porous liquid and its use for CO2 absorption from molecular simulation Atilhan, Mert; Cincotti, Alberto; Aparicio, Santiago Journal of Molecular Liquids, Vol. 330 https://doi.org/10.1016/j.molliq.2021.115660	journal	May 2021
Molecular dynamics study of dispersion and fluidity of porous liquids with different pore sizes Sheng, Lisha; Chen, Zhenqian Journal of Molecular Liquids, Vol. 333 https://doi.org/10.1016/j.molliq.2021.115890	journal	July 2021
Zeolitic imidazolate frameworks based porous liquids for promising fluid selective gas sorbents Wu, Yiwei; Wang, Dechao; Li, Peipei Journal of Molecular Liquids, Vol. 342 https://doi.org/10.1016/j.molliq.2021.117522	journal	November 2021
An electrostatic repulsion strategy construct ZIFs based liquids with permanent porosity for efficient CO2 capture Li, Xiaoqian; Wang, Dechao; Ning, Hailong Separation and Purification Technology, Vol. 276 https://doi.org/10.1016/j.seppur.2021.119305	journal	December 2021
Thermodynamics and Kinetics of Gas Storage in Porous Liquids Zhang, Fei; Yang, Fengchang; Huang, Jingsong The Journal of Physical Chemistry B, Vol. 120, Issue 29 https://doi.org/10.1021/acs.jpcb.6b04784	journal	July 2016
Investigations of CO₂ Capture from Gas Mixtures Using Porous Liquids Yin, Zhijian; Chen, Houyang; Yang, Li Langmuir, Vol. 37, Issue 3 https://doi.org/10.1021/acs.langmuir.0c03276	journal	January 2021
Porous Liquid: A Stable ZIF-8 Colloid in Ionic Liquid with Permanent Porosity Liu, Shengjun; Liu, Jiandang; Hou, Xudong Langmuir, Vol. 34, Issue 12 https://doi.org/10.1021/acs.langmuir.7b04212	journal	March 2018
Cyclodextrin Porous Liquid Materials for Efficient Chiral Recognition and Separation of Nucleosides Wang, Yan; Sun, Yawei; Bian, He ACS Applied Materials & Interfaces, Vol. 12, Issue 41 https://doi.org/10.1021/acsami.0c15836	journal	October 2020
Transforming Metal–Organic Frameworks into Porous Liquids via a Covalent Linkage Strategy for CO₂ Capture Wang, Dechao; Xin, Yangyang; Li, Xiaoqian ACS Applied Materials & Interfaces, Vol. 13, Issue 2 https://doi.org/10.1021/acsami.0c18707	journal	January 2021
New Class of Type III Porous Liquids: A Promising Platform for Rational Adjustment of Gas Sorption Behavior Shan, Weida; Fulvio, Pasquale F.; Kong, Liyun ACS Applied Materials & Interfaces, Vol. 10, Issue 1 https://doi.org/10.1021/acsami.7b15873	journal	December 2017
Equimolar CO₂ Absorption by Anion-Functionalized Ionic Liquids Gurkan, Burcu E.; de la Fuente, Juan C.; Mindrup, Elaine M. Journal of the American Chemical Society, Vol. 132, Issue 7, p. 2116-2117 https://doi.org/10.1021/ja909305t	journal	February 2010
General Way To Construct Micro- and Mesoporous Metal–Organic Framework-Based Porous Liquids He, Sanfeng; Chen, Lihan; Cui, Jing Journal of the American Chemical Society, Vol. 141, Issue 50 https://doi.org/10.1021/jacs.9b08458	journal	November 2019
Ionic Liquids for CO ₂ Capture and Emission Reduction Brennecke, Joan F.; Gurkan, Burcu E. The Journal of Physical Chemistry Letters, Vol. 1, Issue 24 https://doi.org/10.1021/jz1014828	journal	December 2010
Cooperative insertion of CO2 in diamine-appended metal-organic frameworks McDonald, Thomas M.; Mason, Jarad A.; Kong, Xueqian Nature, Vol. 519, Issue 7543 https://doi.org/10.1038/nature14327	journal	March 2015
Liquid metal–organic frameworks Gaillac, Romain; Pullumbi, Pluton; Beyer, Kevin A. Nature Materials, Vol. 16, Issue 11 https://doi.org/10.1038/nmat4998	journal	October 2017
Coordination cages as permanently porous ionic liquids Ma, Lillian; Haynes, Cally J. E.; Grommet, Angela B. Nature Chemistry, Vol. 12, Issue 3 https://doi.org/10.1038/s41557-020-0419-2	journal	February 2020
Solution processable metal–organic frameworks for mixed matrix membranes using porous liquids Knebel, Alexander; Bavykina, Anastasiya; Datta, Shuvo Jit Nature Materials, Vol. 19, Issue 12 https://doi.org/10.1038/s41563-020-0764-y	journal	August 2020
The changing state of porous materials Bennett, Thomas D.; Coudert, François-Xavier; James, Stuart L. Nature Materials, Vol. 20, Issue 9 https://doi.org/10.1038/s41563-021-00957-w	journal	April 2021
Understanding gas capacity, guest selectivity, and diffusion in porous liquids Greenaway, Rebecca L.; Holden, Daniel; Eden, Edward G. B. Chemical Science, Vol. 8, Issue 4 https://doi.org/10.1039/C6SC05196K	journal	January 2017
Porous liquid zeolites: hydrogen bonding-stabilized H-ZSM-5 in branched ionic liquids Li, Peipei; Chen, Hao; Schott, Jennifer A. Nanoscale, Vol. 11, Issue 4 https://doi.org/10.1039/C8NR07337F	journal	January 2019
The encapsulation of metal nanoparticles within porous liquids Hemming, Ellen B.; Masters, Anthony F.; Maschmeyer, Thomas Chemical Communications, Vol. 55, Issue 75 https://doi.org/10.1039/C9CC03546J	journal	January 2019
A polyether amine modified metal organic framework enhanced the CO ₂ adsorption capacity of room temperature porous liquids Zhao, Xuemei; Yuan, Yihui; Li, Peipei Chemical Communications, Vol. 55, Issue 87 https://doi.org/10.1039/C9CC07243H	journal	January 2019
A solvent-free porous liquid comprising hollow nanorod–polymer surfactant conjugates Kumar, Raj; Dhasaiyan, Prabhu; Naveenkumar, Parinamipura M. Nanoscale Advances, Vol. 1, Issue 10 https://doi.org/10.1039/C9NA00353C	journal	January 2019
Type 3 porous liquids based on non-ionic liquid phases – a broad and tailorable platform of selective, fluid gas sorbents Cahir, John; Tsang, Min Ying; Lai, Beibei Chemical Science, Vol. 11, Issue 8 https://doi.org/10.1039/C9SC05770F	journal	January 2020
Transforming surface-modified metal organic framework powder into room temperature porous liquids via an electrical balance strategy Zhao, Xiaoran; An, Shuhao; Dai, Jialing New Journal of Chemistry, Vol. 44, Issue 29 https://doi.org/10.1039/D0NJ02388D	journal	January 2020
Colloidal three-dimensional covalent organic frameworks and their application as porous liquids Mow, Rachel E.; Lipton, Andrew S.; Shulda, Sarah Journal of Materials Chemistry A, Vol. 8, Issue 44 https://doi.org/10.1039/D0TA06768G	journal	January 2020
Integrated, one-pot carbon capture and utilisation using porous ionic liquids Zhou, Yujiao; Avila, Jocasta; Berthet, Nicolas Chemical Communications, Vol. 57, Issue 64 https://doi.org/10.1039/D1CC02642A	journal	January 2021
ZIF-8-porous ionic liquids for the extraction of 2,2,3,3-tetrafluoro-1-propanol and water mixture Wang, Zenghui; Zhao, Pingping; Wu, Jimin New Journal of Chemistry, Vol. 45, Issue 19 https://doi.org/10.1039/D1NJ01053K	journal	January 2021
Porous liquids – the future is looking emptier Egleston, Benjamin D.; Mroz, Austin; Jelfs, Kim E. Chemical Science, Vol. 13, Issue 18 https://doi.org/10.1039/D2SC00087C	journal	January 2022
Immobilisation of Homogeneous Pd Catalysts within a Type I Porous Liquid Hemming, Ellen B.; Masters, Anthony F.; Maschmeyer, Thomas Australian Journal of Chemistry, Vol. 73, Issue 12 https://doi.org/10.1071/CH20256	journal	January 2020
The use of the cohen–turnbull model for calculation of the self-diffusion coefficients of liquid dichloroalkanes Drozdowski, Henryk Physics and Chemistry of Liquids, Vol. 41, Issue 6 https://doi.org/10.1080/00319100310001623082	journal	December 2003
Ionic liquids for carbon capture Fu, Yuqing; Yang, Zhenzhen; Mahurin, Shannon M. MRS Bulletin, Vol. 47, Issue 4 https://doi.org/10.1557/s43577-022-00315-4	journal	April 2022
Preparation of Porous Liquid Based on Silicalite-1 Liu, Yutong; Bai, Yang; Tian, Tao Materials, Vol. 12, Issue 23 https://doi.org/10.3390/ma12233984	journal	December 2019
Key Parameters to Tailor Hollow Silica Nanospheres for a Type I Porous Liquid Synthesis: Optimized Structure and Accessibility Ben Ghozi-Bouvrande, Justine; Pellet-Rostaing, Stéphane; Dourdain, Sandrine Nanomaterials, Vol. 11, Issue 9 https://doi.org/10.3390/nano11092307	journal	September 2021

Figures / Tables (4)

Similar Records

Tailoring the Gating Effect of Organic Cage via a Porous Liquid Approach

Journal Article · Sun Sep 22 20:00:00 EDT 2024 · Advanced Functional Materials · OSTI ID:2538048

A bifunctional zeolitic porous liquid with incompatible Lewis pairs for antagonistic cascade catalysis

Journal Article · Tue Sep 21 20:00:00 EDT 2021 · Chem · OSTI ID:1830136

Control of Permanent Porosity in Type 3 Porous Liquids via Solvent Clustering

Journal Article · Wed Jan 08 19:00:00 EST 2025 · ACS Applied Materials & Interfaces · OSTI ID:2585672

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Carbon capture
Carbon dioxide
Ionic liquids
Porous liquids
Porous materials

Strategies for design and synthesis of porous liquids toward carbon capture and separation

Citation Formats

References (60)

Figures / Tables (4)

Similar Records

Related Subjects