A bifunctional zeolitic porous liquid with incompatible Lewis pairs for antagonistic cascade catalysis

Chen, Hao; Yang, Zhenzhen; Peng, Honggen; Jie, Kecheng; Li, Peipei; Ding, Shunmin; Guo, Wei; Suo, Xian; Liu, Jixing; Yan, Ran; Liu, Wenming; Do-Thanh, Chi-Linh; Wang, Hongming; Wang, Zhendong; Han, Lu; Yang, Weimin; Dai, Sheng

doi:10.1016/j.chempr.2021.08.022

A bifunctional zeolitic porous liquid with incompatible Lewis pairs for antagonistic cascade catalysis

Journal Article · Wed Sep 22 00:00:00 EDT 2021 · Chem

DOI:https://doi.org/10.1016/j.chempr.2021.08.022· OSTI ID:1830136

Chen, Hao ^[1]; ^[1]; Peng, Honggen ^[2]; Jie, Kecheng ^[3]; Li, Peipei ^[4]; Ding, Shunmin ^[5]; Guo, Wei ^[1]; Suo, Xian ^[3]; Liu, Jixing ^[6]; Yan, Ran ^[5]; Liu, Wenming ^[5]; Do-Thanh, Chi-Linh ^[3]; Wang, Hongming ^[5]; Wang, Zhendong ^[5]; Han, Lu ^[7]; Yang, Weimin ^[8]; ^[4]

Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Nanchang Univ. (China); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Nanchang Univ. (China)
Jiangsu University, Zhenjiang (China)
Tongji Unversity, Shanghai (China)
Sinopec Shanghai Research Institute of Petrochemical Technology, Shanghai (China)

The emergence of porous liquids (PLs) opened opportunities to form unique antagonistic systems capable of fulfilling cascade reactions promoted by incompatible active sites in one pot, which is a long-term challenging subject in catalysis. Herein, unique bifunctional type III PL-based systems were facilely fabricated via assembly of zeolite nanosheets with ionic liquids. Rational structural design afforded PLs that feature high zeolite concentration, stable dispersion after 2 years, abundant cavity distribution, and involvement of antagonistic groups (acid and base sites) in separated and active form via steric hindrance control and electronic repulsion regulation. These unique properties worked cooperatively to fulfill the cascade deacetalization-Knoevenagel/Aldol condensation in one pot with superior catalytic efficiency outperforming the traditional systems. The key to success lies in the formation of bifunctional composites, transformation of zeolite from heterogeneous to homogeneous via surface modification, as well as rapid mass transfer ensured by the rigid porous architecture.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1830136

Alternate ID(s):: OSTI ID: 1869352

Journal Information:: Chem, Journal Name: Chem Journal Issue: 12 Vol. 7; ISSN 2451-9294

Publisher:: Cell Press, ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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A bifunctional zeolitic porous liquid with incompatible Lewis pairs for antagonistic cascade catalysis

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