Preparation of SBA-15-Supported Metals by Vapor-Phase Infiltration

Wang, Ching-Yu; Shen, Kai; Gorte, Raymond J.; Vohs, John M.

doi:10.3390/inorganics10110215

Preparation of SBA-15-Supported Metals by Vapor-Phase Infiltration

Journal Article · Sat Nov 19 00:00:00 EST 2022 · Inorganics

DOI:https://doi.org/10.3390/inorganics10110215· OSTI ID:1899218

Wang, Ching-Yu; Shen, Kai; ;

A simple method is presented for incorporating various catalytic metals into the pores of SBA-15 using vapor-phase infiltration. The precursors used in Atomic Layer Deposition (ALD) for Pt, Pd, Rh, Ru, and Ni were exposed to an evacuated SBA-15, resulting in monolayer films of the adsorbed precursors inside the mesopores. The metal particles that formed after removal of the precursor ligands remained in the pores and had particle sizes ranging from 3.8 nm for Pt to 5.2 nm for Ni, as determined by Transmission Electron Microscopy (TEM), XRD, and CO chemisorption. Metal loadings for saturation exposures ranged from 5.1-wt% for Ni to 9.1-wt% for Pt; however, uniform deposition was demonstrated for lower loadings of Pd by decreasing the amount of precursor. To determine the effect of the surface composition of the mesopores, Pd particles were also added to SBA-15 that was coated with a 0.2-nm film of ZrO2.

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Research Organization:: Univ. of Pennsylvania, Philadelphia, PA (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: SC0009440

OSTI ID:: 1899218

Alternate ID(s):: OSTI ID: 1898635

Journal Information:: Inorganics, Journal Name: Inorganics Journal Issue: 11 Vol. 10; ISSN 2304-6740; ISSN INORCW

Publisher:: MDPI AGCopyright Statement

Country of Publication:: Switzerland

Language:: English

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