On the Arrhenius-like behavior of conductivity during flash sintering of 3 mol% yttria stabilized zirconia ceramics

Campos, João V.; Lavagnini, Isabela R.; Avila, Viviana; Yoon, Bola; Ghose, Sanjit; Raj, Rishi; Pallone, Eliria M.J.A.; Jesus, Lilian M.

doi:10.1016/j.scriptamat.2021.114093

On the Arrhenius-like behavior of conductivity during flash sintering of 3 mol% yttria stabilized zirconia ceramics

Journal Article · Wed Jun 30 00:00:00 EDT 2021 · Scripta Materialia

DOI:https://doi.org/10.1016/j.scriptamat.2021.114093· OSTI ID:1817201

^[1]; ^[1]; Avila, Viviana ^[2]; ^[2]; Ghose, Sanjit ^[3]; Raj, Rishi ^[2]; Pallone, Eliria M.J.A. ^[4]; Jesus, Lilian M. ^[5]

Univ. of Sao Paulo (Brazil); Univ. of Colorado, Boulder, CO (United States)
Univ. of Colorado, Boulder, CO (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Univ. of Sao Paulo (Brazil)
Univ. of Colorado, Boulder, CO (United States); Univ. Federal de Sao Carlos (UFSCAR) (Brazil)

Here, we discuss the Arrhenius behavior of electrical conductivity σ during flash sintering of 3 mol% yttria stabilized zirconia (3YSZ). In situ x-ray diffraction is used to determine sample temperature. Sintering contribution to σ is excluded by investigating the flash event on a dense ceramic. We show that total conductivity follows an Arrhenius-like equation in both dense and green samples, even during Stage II of flash. The non-linearity often verified during flash sintering of 3YSZ is therefore related to the furnace temperature instead of the sample temperature when building the ln(σ) vs. 1/T plots. Furthermore, we verified a change in the activation energy for conduction prior to the ignition of the flash event and discussed the possible mechanisms. For instance, the decrease in activation energy from Stage I to II in the dense sample is attributed to a contribution from electronic carriers.

View Accepted Manuscript (DOE)

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); Sao Paulo Research Foundation (FAPESP); National Council for Scientific and Technological Development (CNPq); US Army Research Office (ARO); US Department of the Navy, Office of Naval Research (ONR)

Grant/Contract Number:: SC0012704

OSTI ID:: 1817201

Alternate ID(s):: OSTI ID: 1804581
OSTI ID: 23199644

Report Number(s):: BNL--222041-2021-JAAM

Journal Information:: Scripta Materialia, Journal Name: Scripta Materialia Vol. 203; ISSN 1359-6462

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (46)

Blackening in yttria stabilized zirconia due to cathodic processes at solid platinum electrodes Casselton, R. E. W. Journal of Applied Electrochemistry, Vol. 4, Issue 1 https://doi.org/10.1007/BF00615903	journal	February 1974
Electrical conductivity of polycrystalline tetragonal zirconia ZrO2-M2O3 (M=Sc, Y, Yb) Yamamoto, O.; Takeda, Y.; Kanno, R. Journal of Materials Science Letters, Vol. 8, Issue 2 https://doi.org/10.1007/BF00730724	journal	February 1989
Electrochemical blackening of yttria-stabilized zirconia â€“ morphological instability of the moving reaction front Janek, J. Solid State Ionics, Vol. 116, Issue 3-4 https://doi.org/10.1016/S0167-2738(98)00415-9	journal	January 1999
Reduction in sintering temperature for flash-sintering of yttria by nickel cation-doping Yoshida, Hidehiro; Morita, Koji; Kim, Byung-Nam Acta Materialia, Vol. 106 https://doi.org/10.1016/j.actamat.2016.01.037	journal	March 2016
Oxygen potential transition in mixed conducting oxide electrolyte Dong, Yanhao; Chen, I-Wei Acta Materialia, Vol. 156 https://doi.org/10.1016/j.actamat.2018.06.014	journal	September 2018
Incubation time for flash sintering as caused by internal reactions, exemplified for yttria stabilized zirconia Kirchheim, Reiner Acta Materialia, Vol. 175 https://doi.org/10.1016/j.actamat.2019.06.030	journal	August 2019
Laser sintering and radioluminescence emission of pure and doped Y 2 O 3 ceramics Oliveira, Tiago Cordeiro de; Silva, Marcelo Souza da; Jesus, Lilian Menezes de Ceramics International, Vol. 40, Issue 10 https://doi.org/10.1016/j.ceramint.2014.07.056	journal	December 2014
Translucent and persistent luminescent SrAl2O4:Eu2+Dy3+ ceramics Sampaio, D. V.; Souza, N. R. S.; Santos, J. C. A. Ceramics International, Vol. 42, Issue 3 https://doi.org/10.1016/j.ceramint.2015.11.108	journal	February 2016
Polymeric synthesis and conventional versus laser sintering of CaCu3Ti4O12 electroceramics: (micro)structures, phase development and dielectric properties Jesus, L. M.; Santos, J. C. A.; Sampaio, D. V. Journal of Alloys and Compounds, Vol. 654 https://doi.org/10.1016/j.jallcom.2015.09.027	journal	January 2016
Effect of conventional and laser sintering on the (micro)structural and dielectric properties of Bi2/3Cu3Ti4O12 synthesized through a polymeric precursor route Jesus, L. M.; Barbosa, L. B.; Ardila, D. R. Journal of Alloys and Compounds, Vol. 735 https://doi.org/10.1016/j.jallcom.2017.10.140	journal	February 2018
Joule heating during flash-sintering Raj, Rishi Journal of the European Ceramic Society, Vol. 32, Issue 10 https://doi.org/10.1016/j.jeurceramsoc.2012.02.030	journal	August 2012
Densification behaviour and microstructural development in undoped yttria prepared by flash-sintering Yoshida, Hidehiro; Sakka, Yoshio; Yamamoto, Takahisa Journal of the European Ceramic Society, Vol. 34, Issue 4 https://doi.org/10.1016/j.jeurceramsoc.2013.10.031	journal	April 2014
Flash-sintering of MnCo2O4 and its relation to phase stability Gaur, Anshu; Sglavo, Vincenzo M. Journal of the European Ceramic Society, Vol. 34, Issue 10 https://doi.org/10.1016/j.jeurceramsoc.2014.02.012	journal	September 2014
Electrical characteristics of flash sintering: thermal runaway of Joule heating Todd, R. I.; Zapata-Solvas, E.; Bonilla, R. S. Journal of the European Ceramic Society, Vol. 35, Issue 6 https://doi.org/10.1016/j.jeurceramsoc.2014.12.022	journal	June 2015
Flash sintering incubation in Al2O3/TZP composites Bichaud, E.; Chaix, J. M.; Carry, C. Journal of the European Ceramic Society, Vol. 35, Issue 9 https://doi.org/10.1016/j.jeurceramsoc.2015.02.033	journal	September 2015
Electroluminescence and the measurement of temperature during Stage III of flash sintering experiments Terauds, Kalvis; Lebrun, Jean-Marie; Lee, Hyun-Hwi Journal of the European Ceramic Society, Vol. 35, Issue 11 https://doi.org/10.1016/j.jeurceramsoc.2015.03.040	journal	October 2015
Estimating Joule heating and ionic conductivity during flash sintering of 8YSZ Du, Yaxi; Stevenson, Adam J.; Vernat, Dorothée Journal of the European Ceramic Society, Vol. 36, Issue 3 https://doi.org/10.1016/j.jeurceramsoc.2015.10.037	journal	February 2016
Multifuncional translucent ferroelectric Ba1−xCaxTiO3 ceramics produced by laser sintering Silva, R. S.; Jesus, L. M.; Oliveira, T. C. Journal of the European Ceramic Society, Vol. 36, Issue 16 https://doi.org/10.1016/j.jeurceramsoc.2016.07.010	journal	December 2016
Ultra-fast firing: Effect of heating rate on sintering of 3YSZ, with and without an electric field Ji, W.; Parker, B.; Falco, S. Journal of the European Ceramic Society, Vol. 37, Issue 6 https://doi.org/10.1016/j.jeurceramsoc.2017.01.033	journal	June 2017
Flash Sintering using Controlled Current Ramp Charalambous, Harry; Jha, Shikhar Krishn; Christian, Kent Harrison Journal of the European Ceramic Society, Vol. 38, Issue 10 https://doi.org/10.1016/j.jeurceramsoc.2018.04.003	journal	August 2018
Development of an instrumented and automated flash sintering setup for enhanced process monitoring and parameter control Campos, João Vitor; Lavagnini, Isabela Reis; Sousa, Rafael Vieira de Journal of the European Ceramic Society, Vol. 39, Issue 2-3 https://doi.org/10.1016/j.jeurceramsoc.2018.09.002	journal	February 2019
Influence of flash sintering on the ionic conductivity of 8 mol% yttria stabilized zirconia Vendrell, Xavier; Yadav, Devinder; Raj, Rishi Journal of the European Ceramic Society, Vol. 39, Issue 4 https://doi.org/10.1016/j.jeurceramsoc.2018.12.048	journal	April 2019
Study of the ionic conductivity of Li0.5La0.5TiO3 laser-sintered ceramics Silva, J. H. L.; Alves, Y. G. S.; Almeida, A. Journal of the European Ceramic Society, Vol. 40, Issue 15 https://doi.org/10.1016/j.jeurceramsoc.2020.06.008	journal	December 2020
Electrical-field induced nonlinear conductive behavior in dense zirconia ceramic Gao, Yan; Liu, Fangzhou; Liu, Dianguang Journal of Materials Science & Technology, Vol. 33, Issue 8 https://doi.org/10.1016/j.jmst.2017.03.005	journal	August 2017
Viscous flow flash sintering of porous silica glass Prado, Miguel Oscar; Biesuz, Mattia; Frasnelli, Matteo Journal of Non-Crystalline Solids, Vol. 476 https://doi.org/10.1016/j.jnoncrysol.2017.09.024	journal	November 2017
The onset of the flash transition in single crystals of cubic zirconia as a function of electric field and temperature Yadav, D.; Raj, R. Scripta Materialia, Vol. 134 https://doi.org/10.1016/j.scriptamat.2017.02.015	journal	June 2017
Flash sintering scaling-up challenges: Influence of the sample size on the microstructure and onset temperature of the flash event Campos, João V.; Lavagnini, Isabela R.; Pereira da Silva, João G. Scripta Materialia, Vol. 186 https://doi.org/10.1016/j.scriptamat.2020.04.022	journal	September 2020
Electronic Conductivity in Yttria-Stabilized Zirconia under a Small dc Bias Masó, Nahum; West, Anthony R. Chemistry of Materials, Vol. 27, Issue 5 https://doi.org/10.1021/cm503957x	journal	February 2015
Machine learning enabled autonomous microstructural characterization in 3D samples Chan, Henry; Cherukara, Mathew; Loeffler, Troy D. npj Computational Materials, Vol. 6, Issue 1 https://doi.org/10.1038/s41524-019-0267-z	journal	January 2020
A Mathematical Model for Flash Sintering Hewitt, I. J.; Lacey, A. A.; Todd, R. I. Mathematical Modelling of Natural Phenomena, Vol. 10, Issue 6 https://doi.org/10.1051/mmnp/201510607	journal	January 2015
Flash Sintering of Nanograin Zirconia in <5 s at 850°C Cologna, Marco; Rashkova, Boriana; Raj, Rishi Journal of the American Ceramic Society, Vol. 93, Issue 11, p. 3556-3559 https://doi.org/10.1111/j.1551-2916.2010.04089.x	journal	September 2010
Flash-Sinterforging of Nanograin Zirconia Field Assisted Sintering and Superplasticity Francis, John S.C.; Raj, Rishi; Chen, I.-W. Journal of the American Ceramic Society, Vol. 95, Issue 1, p. 138-146 https://doi.org/10.1111/j.1551-2916.2011.04855.x	journal	September 2011
Influence of the Field and the Current Limit on Flash Sintering at Isothermal Furnace Temperatures Francis, John S. C.; Raj, Rishi Journal of the American Ceramic Society, Vol. 96, Issue 9 https://doi.org/10.1111/jace.12472	journal	July 2013
Impedance Spectroscopy and Dielectric Properties of Flash Versus Conventionally Sintered Yttria-Doped Zirconia Electroceramics Viewed at the Microstructural Level M'Peko, J. -C.; Francis, J. S. C.; Raj, Rishi Journal of the American Ceramic Society, Vol. 96, Issue 12 https://doi.org/10.1111/jace.12567	journal	September 2013
Predicting the Onset of Flash Sintering Dong, Yanhao; Chen, I. ‐Wei Journal of the American Ceramic Society, Vol. 98, Issue 8 https://doi.org/10.1111/jace.13679	journal	May 2015
Broadening of Diffraction Peak Widths and Temperature Nonuniformity During Flash Experiments Lebrun, Jean‐Marie; Jha, Shikhar K.; McCormack, Scott J. Journal of the American Ceramic Society, Vol. 99, Issue 10 https://doi.org/10.1111/jace.14326	journal	June 2016
In‐situ measurements of lattice expansion related to defect generation during flash sintering Lebrun, J. ‐M.; Hellberg, C. S.; Jha, S. K. Journal of the American Ceramic Society, Vol. 100, Issue 11 https://doi.org/10.1111/jace.15071	journal	July 2017
Two unique measurements related to flash experiments with yttria-stabilized zirconia Yadav, Devinder; Raj, Rishi Journal of the American Ceramic Society, Vol. 100, Issue 12 https://doi.org/10.1111/jace.15114	journal	August 2017
Electrical and hydrogen reduction enhances kinetics in doped zirconia and ceria: II . Mapping electrode polarization and vacancy condensation in YSZ Dong, Yanhao; Chen, I‐Wei Journal of the American Ceramic Society, Vol. 101, Issue 3 https://doi.org/10.1111/jace.15274	journal	October 2017
α-Alumina and spinel react into single-phase high-alumina spinel in <3 seconds during flash sintering Kok, David; Yadav, Devinder; Sortino, Emanuele Journal of the American Ceramic Society https://doi.org/10.1111/jace.15927	journal	July 2018
On the synchronicity of flash sintering and phase transformation Yoon, Bola; Yadav, Devinder; Ghose, Sanjit Journal of the American Ceramic Society, Vol. 102, Issue 6 https://doi.org/10.1111/jace.16335	journal	February 2019
Induced p‐ type semiconductivity in yttria‐stabilized zirconia Vendrell, Xavier; West, Anthony R. Journal of the American Ceramic Society, Vol. 102, Issue 10 https://doi.org/10.1111/jace.16492	journal	April 2019
DC electrical degradation of YSZ: Voltage‐controlled electrical metallization of a fast ion conducting insulator Alvarez, Ana; Dong, Yanhao; Chen, I‐Wei Journal of the American Ceramic Society, Vol. 103, Issue 5 https://doi.org/10.1111/jace.17004	journal	January 2020
Microstructural evolution of 3YSZ flash‐sintered with current ramp control R. Lavagnini, Isabela; Campos, João V.; Ferreira, Julieta A. Journal of the American Ceramic Society, Vol. 103, Issue 6 https://doi.org/10.1111/jace.17037	journal	February 2020
Measurement and modelling of electrical resistivity by four-terminal method during flash sintering of 3YSZ Yoshida, Michiyuki; Falco, Simone; Todd, Richard I. Journal of the Ceramic Society of Japan, Vol. 126, Issue 7 https://doi.org/10.2109/jcersj2.17256	journal	January 2018
Investigation of Electrochemical, Optical and Thermal Effects during Flash Sintering of 8YSZ Biesuz, Mattia; Pinter, Lorenzo; Saunders, Theo Materials, Vol. 11, Issue 7 https://doi.org/10.3390/ma11071214	journal	July 2018

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