In-situ synchrotron X-ray diffraction of hydroxyapatite-zirconia composite during conventional and flash sintering

Lavagnini, Isabela R.; Campos, João V.; Jesus, Lílian M.; Lobo, Anderson O.; Ghose, Sanjit K.; Raj, Rishi; Pallone, Eliria M.J.A.

doi:10.1016/j.jeurceramsoc.2024.01.070

In-situ synchrotron X-ray diffraction of hydroxyapatite-zirconia composite during conventional and flash sintering

Journal Article · Tue Jan 23 23:00:00 EST 2024 · Journal of the European Ceramic Society

DOI:https://doi.org/10.1016/j.jeurceramsoc.2024.01.070· OSTI ID:2284077

Lavagnini, Isabela R. ^[1]; Campos, João V. ^[2]; Jesus, Lílian M. ^[2]; Lobo, Anderson O. ^[3]; Ghose, Sanjit K. ^[4]; Raj, Rishi ^[5]; Pallone, Eliria M.J.A. ^[6]

Univ. of Sao Paulo (Brazil); Univ. of Colorado, Boulder, CO (United States)
Univ. of Colorado, Boulder, CO (United States); Federal Univ. of Sao Carlos, Sao Paulo (Brazil)
Federal University of Piauí (Brazil)
Brookhaven National Laboratory (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)
Univ. of Colorado, Boulder, CO (United States)
Univ. of Sao Paulo (Brazil)

Here, we conducted in-situ X-ray diffraction to study the crystalline phase evolution in hydroxyapatite-zirconia composites during both conventional and flash sintering processes. Additionally, we examined the thermal history and microstructure of the composite under these sintering conditions. Despite both sintering methods reaching similar average temperatures, they yielded distinct results in terms of crystalline phase composition and microstructure. In the flash sintered samples, we observed a complete transformation of hydroxyapatite into α- tricalcium phosphate and a complete tetragonal to cubic phase transition in zirconia. Conversely, the conventionally sintered samples remained practically stable. Notably, the flash sintered samples exhibited needle-like microstructures, which were absent in their conventionally sintered counterparts. This divergence suggests that the application of an electric field plays a role in generating athermal effects during the sintering of hydroxyapatite-zirconia composites.

View Accepted Manuscript (DOE)

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704; AC02-98CH10886

OSTI ID:: 2284077

Alternate ID(s):: OSTI ID: 2311913

Report Number(s):: BNL--225279-2024-JAAM

Journal Information:: Journal of the European Ceramic Society, Journal Name: Journal of the European Ceramic Society Journal Issue: 7 Vol. 44; ISSN 0955-2219

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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