On the Arrhenius-like behavior of conductivity during flash sintering of 3 mol% yttria stabilized zirconia ceramics

Campos, João V.; Lavagnini, Isabela R.; Avila, Viviana; Yoon, Bola; Ghose, Sanjit; Raj, Rishi; Pallone, Eliria M.J.A.; Jesus, Lilian M.

doi:10.1016/j.scriptamat.2021.114093

Title: On the Arrhenius-like behavior of conductivity during flash sintering of 3 mol% yttria stabilized zirconia ceramics

Journal Article · Wed Jun 30 00:00:00 EDT 2021 · Scripta Materialia

DOI:https://doi.org/10.1016/j.scriptamat.2021.114093· OSTI ID:1817201

^[1];

^[1]; Avila, Viviana ^[2];

^[2]; Ghose, Sanjit ^[3]; Raj, Rishi ^[2]; Pallone, Eliria M.J.A. ^[4]; Jesus, Lilian M. ^[5]

Univ. of Sao Paulo (Brazil); Univ. of Colorado, Boulder, CO (United States)
Univ. of Colorado, Boulder, CO (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Univ. of Sao Paulo (Brazil)
Univ. of Colorado, Boulder, CO (United States); Univ. Federal de Sao Carlos (UFSCAR) (Brazil)

Here, we discuss the Arrhenius behavior of electrical conductivity σ during flash sintering of 3 mol% yttria stabilized zirconia (3YSZ). In situ x-ray diffraction is used to determine sample temperature. Sintering contribution to σ is excluded by investigating the flash event on a dense ceramic. We show that total conductivity follows an Arrhenius-like equation in both dense and green samples, even during Stage II of flash. The non-linearity often verified during flash sintering of 3YSZ is therefore related to the furnace temperature instead of the sample temperature when building the ln(σ) vs. 1/T plots. Furthermore, we verified a change in the activation energy for conduction prior to the ignition of the flash event and discussed the possible mechanisms. For instance, the decrease in activation energy from Stage I to II in the dense sample is attributed to a contribution from electronic carriers.

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Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); Sao Paulo Research Foundation (FAPESP); National Council for Scientific and Technological Development (CNPq); US Army Research Office (ARO); US Department of the Navy, Office of Naval Research (ONR)

Grant/Contract Number:: SC0012704; 2018/04331-5; 2018/19730-6; 2019/03786-1; 2019/14677-9; 200573/2018-7; W911NF-16-1-0200; N00014-18-1-2270

OSTI ID:: 1817201

Alternate ID(s):: OSTI ID: 1804581

Report Number(s):: BNL-222041-2021-JAAM

Journal Information:: Scripta Materialia, Vol. 203; ISSN 1359-6462

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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