Cation- and pH-Dependent Hydrogen Evolution and Oxidation Reaction Kinetics

Huang, Botao; Rao, Reshma R.; You, Sifan; Hpone Myint, Kyaw; Song, Yizhi; Wang, Yanming; Ding, Wendu; Giordano, Livia; Zhang, Yirui; Wang, Tao; Muy, Sokseiha; Katayama, Yu; Grossman, Jeffrey C.; Willard, Adam P.; Xu, Kang; Jiang, Ying; Shao-Horn, Yang

doi:10.1021/jacsau.1c00281

Cation- and pH-Dependent Hydrogen Evolution and Oxidation Reaction Kinetics

Journal Article · Thu Aug 26 00:00:00 EDT 2021 · JACS Au

DOI:https://doi.org/10.1021/jacsau.1c00281· OSTI ID:1815183

^[1]; Rao, Reshma R. ^[1]; You, Sifan ^[2]; Hpone Myint, Kyaw ^[3]; Song, Yizhi ^[2]; ^[4]; ^[3]; ^[1]; ^[5]; Wang, Tao ^[1]; Muy, Sokseiha ^[1]; ^[6]; ^[7]; ^[3]; ^[8]; Jiang, Ying ^[2]; ^[9]

Electrochemical Energy Laboratory, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States, Research Laboratory of Electronics, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States
International Center for Quantum Materials, School of Physics, Peking University, Beijing 100871, People’s Republic of China
Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States
Research Laboratory of Electronics, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States
Electrochemical Energy Laboratory, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States, Department of Mechanical Engineering, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States
Electrochemical Energy Laboratory, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States, Department of Applied Chemistry, Graduate School of Sciences and Technology for Innovation, Yamaguchi University, Ube 755-8611, Japan
Department of Material Science and Engineering, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States
Battery Science Branch, Sensor and Electron Devices Directorate, U.S. Army Research Laboratory, Adelphi, Maryland 20783-1197, United States
Electrochemical Energy Laboratory, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States, Department of Mechanical Engineering, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States, Department of Material Science and Engineering, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States

Not Available

View Journal Article

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI ID:: 1815183

Journal Information:: JACS Au, Journal Name: JACS Au Journal Issue: 10 Vol. 1; ISSN 2691-3704

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (78)

Electron Transfer Reactions in Chemistry: Theory and Experiment (Nobel Lecture) Marcus, Rudolph A. Angewandte Chemie International Edition in English, Vol. 32, Issue 8 https://doi.org/10.1002/anie.199311113	journal	August 1993
Changing the Activity of Electrocatalysts for Oxygen Reduction by Tuning the Surface Electronic Structure Stamenkovic, Vojislav; Mun, Bongjin Simon; Mayrhofer, Karl J. J. Angewandte Chemie International Edition, Vol. 45, Issue 18 https://doi.org/10.1002/anie.200504386	journal	April 2006
Co-adsorption of Cations as the Cause of the Apparent pH Dependence of Hydrogen Adsorption on a Stepped Platinum Single-Crystal Electrode Chen, Xiaoting; McCrum, Ian T.; Schwarz, Kathleen A. Angewandte Chemie International Edition, Vol. 56, Issue 47 https://doi.org/10.1002/anie.201709455	journal	October 2017
The Hydrogen Evolution Reaction in Alkaline Solution: From Theory, Single Crystal Models, to Practical Electrocatalysts Zheng, Yao; Jiao, Yan; Vasileff, Anthony Angewandte Chemie International Edition, Vol. 57, Issue 26 https://doi.org/10.1002/anie.201710556	journal	May 2018
Influence of Alkali Metal Cations on the Hydrogen Evolution Reaction Activity of Pt, Ir, Au, and Ag Electrodes in Alkaline Electrolytes Xue, Song; Garlyyev, Batyr; Watzele, Sebastian ChemElectroChem, Vol. 5, Issue 17 https://doi.org/10.1002/celc.201800690	journal	June 2018
ViscosityB-coefficients, structural entropies and heat capacities, and the effects of ions on the structure of water Marcus, Y. Journal of Solution Chemistry, Vol. 23, Issue 7 https://doi.org/10.1007/BF00972677	journal	July 1994
The radial distribution functions of water and ice from 220 to 673 K and at pressures up to 400 MPa Soper, A. K. Chemical Physics, Vol. 258, Issue 2-3 https://doi.org/10.1016/S0301-0104(00)00179-8	journal	August 2000
On the pH dependence of electrochemical proton transfer barriers Rossmeisl, Jan; Chan, Karen; Skúlason, Egill Catalysis Today, Vol. 262 https://doi.org/10.1016/j.cattod.2015.08.016	journal	March 2016
The potential of zero total charge of Pt nanoparticles and polycrystalline electrodes with different surface structure: The role of anion adsorption in fundamental electrocatalysis Chen, Qing-Song; Solla-Gullón, José; Sun, Shi-Gang Electrochimica Acta, Vol. 55, Issue 27 https://doi.org/10.1016/j.electacta.2010.03.050	journal	November 2010
Marcus–Hush–Chidsey theory of electron transfer applied to voltammetry: A review Henstridge, Martin C.; Laborda, Eduardo; Rees, Neil V. Electrochimica Acta, Vol. 84 https://doi.org/10.1016/j.electacta.2011.10.026	journal	December 2012
Towards the understanding of the interfacial pH scale at Pt(1 1 1) electrodes Rizo, Rubén; Sitta, Elton; Herrero, Enrique Electrochimica Acta, Vol. 162 https://doi.org/10.1016/j.electacta.2015.01.069	journal	April 2015
Theory of coupled ion-electron transfer kinetics Fraggedakis, Dimitrios; McEldrew, Michael; Smith, Raymond B. Electrochimica Acta, Vol. 367 https://doi.org/10.1016/j.electacta.2020.137432	journal	January 2021
On the presence of surface bound hydroxyl species on polycrystalline Pt electrodes in the “hydrogen potential region” (0–0.4 V-RHE) Janik, Michael J.; McCrum, Ian T.; Koper, Marc T. M. Journal of Catalysis, Vol. 367 https://doi.org/10.1016/j.jcat.2018.09.031	journal	November 2018
Simple formula for Marcus–Hush–Chidsey kinetics Zeng, Yi; Smith, Raymond B.; Bai, Peng Journal of Electroanalytical Chemistry, Vol. 735 https://doi.org/10.1016/j.jelechem.2014.09.038	journal	December 2014
Design principles for hydrogen evolution reaction catalyst materials Strmcnik, Dusan; Lopes, Pietro Papa; Genorio, Bostjan Nano Energy, Vol. 29 https://doi.org/10.1016/j.nanoen.2016.04.017	journal	November 2016
Importance of Water Structure and Catalyst–Electrolyte Interface on the Design of Water Splitting Catalysts Zhang, Ronguang; Pearce, Paul E.; Duan, Yan Chemistry of Materials, Vol. 31, Issue 20 https://doi.org/10.1021/acs.chemmater.9b02318	journal	August 2019
How the Nature of the Alkali Metal Cations Influences the Double-Layer Capacitance of Cu, Au, and Pt Single-Crystal Electrodes Xue, Song; Garlyyev, Batyr; Auer, Andrea The Journal of Physical Chemistry C, Vol. 124, Issue 23 https://doi.org/10.1021/acs.jpcc.0c01715	journal	May 2020
Theory of Electrochemical Proton-Coupled Electron Transfer in Diabatic Vibronic Representation: Application to Proton Discharge on Metal Electrodes in Alkaline Solution Lam, Yan-Choi; Soudackov, Alexander V.; Hammes-Schiffer, Sharon The Journal of Physical Chemistry C, Vol. 124, Issue 50 https://doi.org/10.1021/acs.jpcc.0c08096	journal	December 2020
Cation-Dependent Interfacial Structures and Kinetics for Outer-Sphere Electron-Transfer Reactions Huang, Botao; Myint, Kyaw Hpone; Wang, Yanming The Journal of Physical Chemistry C, Vol. 125, Issue 8 https://doi.org/10.1021/acs.jpcc.0c10492	journal	February 2021
Surface (Electro)chemistry of CO ₂ on Pt Surface: An in Situ Surface-Enhanced Infrared Absorption Spectroscopy Study Katayama, Yu; Giordano, Livia; Rao, Reshma R. The Journal of Physical Chemistry C, Vol. 122, Issue 23 https://doi.org/10.1021/acs.jpcc.8b03556	journal	May 2018
Effect of Step Density and Orientation on the Apparent pH Dependence of Hydrogen and Hydroxide Adsorption on Stepped Platinum Surfaces McCrum, Ian T.; Chen, Xiaoting; Schwarz, Kathleen A. The Journal of Physical Chemistry C, Vol. 122, Issue 29 https://doi.org/10.1021/acs.jpcc.8b03660	journal	July 2018
Influence of the Nature of the Alkali Metal Cations on the Electrical Double-Layer Capacitance of Model Pt(111) and Au(111) Electrodes Garlyyev, Batyr; Xue, Song; Watzele, Sebastian The Journal of Physical Chemistry Letters, Vol. 9, Issue 8 https://doi.org/10.1021/acs.jpclett.8b00610	journal	March 2018
Effect of Hydrogen Bonds on the Dielectric Properties of Interfacial Water Varghese, Sleeba; Kannam, Sridhar Kumar; Hansen, Jesper Schmidt Langmuir, Vol. 35, Issue 24 https://doi.org/10.1021/acs.langmuir.9b00543	journal	May 2019
“Beyond Adsorption” Descriptors in Hydrogen Electrocatalysis Rebollar, Luis; Intikhab, Saad; Oliveira, Nicholas J. ACS Catalysis, Vol. 10, Issue 24 https://doi.org/10.1021/acscatal.0c03801	journal	December 2020
Enhanced Supply of Hydroxyl Species in CeO ₂ -Modified Platinum Catalyst Studied by in Situ ATR-FTIR Spectroscopy Katayama, Yu; Okanishi, Takeou; Muroyama, Hiroki ACS Catalysis, Vol. 6, Issue 3 https://doi.org/10.1021/acscatal.6b00108	journal	February 2016
Adsorbed Hydroxide Does Not Participate in the Volmer Step of Alkaline Hydrogen Electrocatalysis Intikhab, Saad; Snyder, Joshua D.; Tang, Maureen H. ACS Catalysis, Vol. 7, Issue 12 https://doi.org/10.1021/acscatal.7b02787	journal	November 2017
pH Effects on Hydrogen Evolution and Oxidation over Pt(111): Insights from First-Principles Lamoureux, Philomena Schlexer; Singh, Aayush R.; Chan, Karen ACS Catalysis, Vol. 9, Issue 7 https://doi.org/10.1021/acscatal.9b00268	journal	May 2019
Transient Voltammetry with Ultramicroelectrodes Reveals the Electron Transfer Kinetics of Lithium Metal Anodes Boyle, David T.; Kong, Xian; Pei, Allen ACS Energy Letters, Vol. 5, Issue 3 https://doi.org/10.1021/acsenergylett.0c00031	journal	February 2020
Effect of Ions on the Structure of Water: Structure Making and Breaking Marcus, Yizhak Chemical Reviews, Vol. 109, Issue 3 https://doi.org/10.1021/cr8003828	journal	March 2009
Solvent, ligand, and ionic charge effects on reaction entropies for simple transition-metal redox couples Hupp, Joseph T.; Weaver, Michael J. Inorganic Chemistry, Vol. 23, Issue 22 https://doi.org/10.1021/ic00190a042	journal	October 1984
Reorganization Energy for Electron Transfer at Film-Modified Electrode Surfaces: A Dielectric Continuum Model Liu, Yi-Ping; Newton, Marshall D. The Journal of Physical Chemistry, Vol. 98, Issue 29 https://doi.org/10.1021/j100080a011	journal	July 1994
The missing term in effective pair potentials Berendsen, H. J. C.; Grigera, J. R.; Straatsma, T. P. The Journal of Physical Chemistry, Vol. 91, Issue 24 https://doi.org/10.1021/j100308a038	journal	November 1987
THE DIELECTRIC CONSTANT OF WATER AS A FUNCTION OF TEMPERATURE AND PRESSURE ^1,2 Owen, Benton B.; Miller, Robert C.; Milner, Clifford E. The Journal of Physical Chemistry, Vol. 65, Issue 11 https://doi.org/10.1021/j100828a035	journal	November 1961
The Activity Coefficient of Lithium Hydroxide in Water and in Aqueous Lithium Chloride Solutions, and the Dissociation of Water in Lithium Chloride Solutions Harned, Herbert S.; Swindells, Frank Evans Journal of the American Chemical Society, Vol. 48, Issue 1 https://doi.org/10.1021/ja01412a017	journal	January 1926
Electrochemical Approach to Concerted Proton and Electron Transfers. Reduction of the Water−Superoxide Ion Complex Costentin, Cyrille; Evans, Dennis H.; Robert, Marc Journal of the American Chemical Society, Vol. 127, Issue 36 https://doi.org/10.1021/ja053911n	journal	September 2005
Hydrolysis of Electrolyte Cations Enhances the Electrochemical Reduction of CO ₂ over Ag and Cu Singh, Meenesh R.; Kwon, Youngkook; Lum, Yanwei Journal of the American Chemical Society, Vol. 138, Issue 39 https://doi.org/10.1021/jacs.6b07612	journal	September 2016
Structure- and Potential-Dependent Cation Effects on CO Reduction at Copper Single-Crystal Electrodes Pérez-Gallent, Elena; Marcandalli, Giulia; Figueiredo, Marta Costa Journal of the American Chemical Society, Vol. 139, Issue 45 https://doi.org/10.1021/jacs.7b10142	journal	November 2017
Explanation of Dramatic pH-Dependence of Hydrogen Binding on Noble Metal Electrode: Greatly Weakened Water Adsorption at High pH Cheng, Tao; Wang, Lu; Merinov, Boris V. Journal of the American Chemical Society, Vol. 140, Issue 25 https://doi.org/10.1021/jacs.8b04006	journal	May 2018
Unifying the Hydrogen Evolution and Oxidation Reactions Kinetics in Base by Identifying the Catalytic Roles of Hydroxyl-Water-Cation Adducts Liu, Ershuai; Li, Jingkun; Jiao, Li Journal of the American Chemical Society, Vol. 141, Issue 7 https://doi.org/10.1021/jacs.8b13228	journal	January 2019
Enhancing the Understanding of Hydrogen Evolution and Oxidation Reactions on Pt(111) through Ab Initio Simulation of Electrode/Electrolyte Kinetics Liu, Ling; Liu, Yuyang; Liu, Chungen Journal of the American Chemical Society, Vol. 142, Issue 11 https://doi.org/10.1021/jacs.9b13694	journal	March 2020
Dielectric Constant of Water Confined in a Nanocavity Senapati, Sanjib; Chandra, Amalendu The Journal of Physical Chemistry B, Vol. 105, Issue 22 https://doi.org/10.1021/jp011058i	journal	June 2001
Ubiquitous Strategy for Probing ATR Surface-Enhanced Infrared Absorption at Platinum Group Metal−Electrolyte Interfaces No authors listed The Journal of Physical Chemistry B, Vol. 109, Issue 16 https://doi.org/10.1021/jp044085s	journal	April 2005
Accurate Simulation of Surfaces and Interfaces of Face-Centered Cubic Metals Using 12−6 and 9−6 Lennard-Jones Potentials Heinz, Hendrik; Vaia, R. A.; Farmer, B. L. The Journal of Physical Chemistry C, Vol. 112, Issue 44 https://doi.org/10.1021/jp801931d	journal	October 2008
Potential-Dependent Reorientation of Water Molecules at an Electrode/Electrolyte Interface Studied by Surface-Enhanced Infrared Absorption Spectroscopy Ataka, Ken-ichi; Yotsuyanagi, Takao; Osawa, Masatoshi The Journal of Physical Chemistry, Vol. 100, Issue 25 https://doi.org/10.1021/jp953636z	journal	January 1996
Dielectric Properties of Aqueous NaCl Solutions at Microwave Frequencies Nörtemann, K.; Hilland, J.; Kaatze, U. The Journal of Physical Chemistry A, Vol. 101, Issue 37 https://doi.org/10.1021/jp971623a	journal	September 1997
Destruction of the Water Layer on a Hydrophobic Surface Induced by the Forced Approach of Hydrophilic and Hydrophobic Cations Yamakata, Akira; Osawa, Masatoshi The Journal of Physical Chemistry Letters, Vol. 1, Issue 9 https://doi.org/10.1021/jz100424e	journal	April 2010
Effects of Li ⁺ , K ⁺ , and Ba ²⁺ Cations on the ORR at Model and High Surface Area Pt and Au Surfaces in Alkaline Solutions Strmcnik, D.; van der Vliet, D. F.; Chang, K. -C. The Journal of Physical Chemistry Letters, Vol. 2, Issue 21 https://doi.org/10.1021/jz201215u	journal	October 2011
Building better batteries Armand, M.; Tarascon, J.-M. Nature, Vol. 451, Issue 7179, p. 652-657 https://doi.org/10.1038/451652a	journal	February 2008
Design principles for oxygen-reduction activity on perovskite oxide catalysts for fuel cells and metal–air batteries Suntivich, Jin; Gasteiger, Hubert A.; Yabuuchi, Naoaki Nature Chemistry, Vol. 3, Issue 7, p. 546-550 https://doi.org/10.1038/nchem.1069	journal	June 2011
Improving the hydrogen oxidation reaction rate by promotion of hydroxyl adsorption Strmcnik, Dusan; Uchimura, Masanobu; Wang, Chao Nature Chemistry, Vol. 5, Issue 4 https://doi.org/10.1038/nchem.1574	journal	February 2013
The role of non-covalent interactions in electrocatalytic fuel-cell reactions on platinum Strmcnik, D.; Kodama, K.; van der Vliet, D. Nature Chemistry, Vol. 1, Issue 6 https://doi.org/10.1038/nchem.330	journal	August 2009
Making the hydrogen evolution reaction in polymer electrolyte membrane electrolysers even faster Tymoczko, Jakub; Calle-Vallejo, Federico; Schuhmann, Wolfgang Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms10990	journal	March 2016
Charge transfer kinetics at the solid–solid interface in porous electrodes Bai, Peng; Bazant, Martin Z. Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4585	journal	April 2014
Correlating hydrogen oxidation and evolution activity on platinum at different pH with measured hydrogen binding energy Sheng, Wenchao; Zhuang, Zhongbin; Gao, Minrui Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms6848	journal	January 2015
Interfacial water reorganization as a pH-dependent descriptor of the hydrogen evolution rate on platinum electrodes Ledezma-Yanez, Isis; Wallace, W. David Z.; Sebastián-Pascual, Paula Nature Energy, Vol. 2, Issue 4 https://doi.org/10.1038/nenergy.2017.31	journal	March 2017
Computational high-throughput screening of electrocatalytic materials for hydrogen evolution Greeley, Jeff; Jaramillo, Thomas F.; Bonde, Jacob Nature Materials, Vol. 5, Issue 11, p. 909-913 https://doi.org/10.1038/nmat1752	journal	October 2006
The role of adsorbed hydroxide in hydrogen evolution reaction kinetics on modified platinum McCrum, Ian T.; Koper, Marc T. M. Nature Energy, Vol. 5, Issue 11 https://doi.org/10.1038/s41560-020-00710-8	journal	October 2020
New insights into the electrochemical hydrogen oxidation and evolution reaction mechanism Durst, J.; Siebel, A.; Simon, C. Energy Environ. Sci., Vol. 7, Issue 7 https://doi.org/10.1039/C4EE00440J	journal	January 2014
Non-covalent interactions in electrochemical reactions and implications in clean energy applications Huang, Botao; Muy, Sokseiha; Feng, Shuting Physical Chemistry Chemical Physics, Vol. 20, Issue 23 https://doi.org/10.1039/C8CP02512F	journal	January 2018
The hydrogen evolution reaction: from material to interfacial descriptors Dubouis, Nicolas; Grimaud, Alexis Chemical Science, Vol. 10, Issue 40 https://doi.org/10.1039/C9SC03831K	journal	January 2019
The Dielectric Properties of Water in Solutions Haggis, G. H.; Hasted, J. B.; Buchanan, T. J. The Journal of Chemical Physics, Vol. 20, Issue 9 https://doi.org/10.1063/1.1700780	journal	September 1952
Evaluation of the constant potential method in simulating electric double-layer capacitors Wang, Zhenxing; Yang, Yang; Olmsted, David L. The Journal of Chemical Physics, Vol. 141, Issue 18 https://doi.org/10.1063/1.4899176	journal	November 2014
Dielectric constant of water in the interface Dinpajooh, Mohammadhasan; Matyushov, Dmitry V. The Journal of Chemical Physics, Vol. 145, Issue 1 https://doi.org/10.1063/1.4955203	journal	July 2016
Insights into proton-coupled electron transfer mechanisms of electrocatalytic H2 oxidation and production Horvath, S.; Fernandez, L. E.; Soudackov, A. V. Proceedings of the National Academy of Sciences, Vol. 109, Issue 39 https://doi.org/10.1073/pnas.1118333109	journal	April 2012
Model for the electrocatalysis of hydrogen evolution Santos, E.; Lundin, A.; Pötting, K. Physical Review B, Vol. 79, Issue 23 https://doi.org/10.1103/PhysRevB.79.235436	journal	June 2009
Universal dependence of hydrogen oxidation and evolution reaction activity of platinum-group metals on pH and hydrogen binding energy Zheng, Jie; Sheng, Wenchao; Zhuang, Zhongbin Science Advances, Vol. 2, Issue 3 https://doi.org/10.1126/sciadv.1501602	journal	March 2016
Ion Association. C. W. Davies. Butterworth, Washington, D.C., 1962. viii + 190 pp. Illus. $7.50 King, E. L. Science, Vol. 143, Issue 3601 https://doi.org/10.1126/science.143.3601.37	journal	January 1964
Free Energy and Temperature Dependence of Electron Transfer at the Metal-Electrolyte Interface Chidsey, C. E. D. Science, Vol. 251, Issue 4996 https://doi.org/10.1126/science.251.4996.919	journal	February 1991
"Water-in-salt" electrolyte enables high-voltage aqueous lithium-ion chemistries Suo, L.; Borodin, O.; Gao, T. Science, Vol. 350, Issue 6263 https://doi.org/10.1126/science.aab1595	journal	November 2015
Combining theory and experiment in electrocatalysis: Insights into materials design Seh, Zhi Wei; Kibsgaard, Jakob; Dickens, Colin F. Science, Vol. 355, Issue 6321 https://doi.org/10.1126/science.aad4998	journal	January 2017
Perovskites in catalysis and electrocatalysis Hwang, Jonathan; Rao, Reshma R.; Giordano, Livia Science, Vol. 358, Issue 6364 https://doi.org/10.1126/science.aam7092	journal	November 2017
Anomalously low dielectric constant of confined water Fumagalli, L.; Esfandiar, A.; Fabregas, R. Science, Vol. 360, Issue 6395 https://doi.org/10.1126/science.aat4191	journal	June 2018
The Kinetics of the Evolution and Dissolution of Hydrogen at Electrodes Bockris, J. O'M.; Mauser, H. Canadian Journal of Chemistry, Vol. 37, Issue 2 https://doi.org/10.1139/v59-061	journal	February 1959
(Invited) Hydrogen Oxidation and Evolution Reaction (HOR/HER) on Pt Electrodes in Acid vs. Alkaline Electrolytes: Mechanism, Activity and Particle Size Effects Durst, J.; Simon, C.; Siebel, A. ECS Transactions, Vol. 64, Issue 3 https://doi.org/10.1149/06403.1069ecst	journal	August 2014
Hydrogen Oxidation and Evolution Reaction Kinetics on Platinum: Acid vs Alkaline Electrolytes Sheng, Wenchao; Gasteiger, Hubert A.; Shao-Horn, Yang Journal of The Electrochemical Society, Vol. 157, Issue 11 https://doi.org/10.1149/1.3483106	journal	January 2010
Kinetics of the Hydrogen Oxidation/Evolution Reaction on Polycrystalline Platinum in Alkaline Electrolyte Reaction Order with Respect to Hydrogen Pressure Rheinländer, Philipp J.; Herranz, Juan; Durst, Julien Journal of The Electrochemical Society, Vol. 161, Issue 14 https://doi.org/10.1149/2.0501414jes	journal	January 2014
Perspective—Towards Establishing Apparent Hydrogen Binding Energy as the Descriptor for Hydrogen Oxidation/Evolution Reactions Zheng, Jie; Nash, Jared; Xu, Bingjun Journal of The Electrochemical Society, Vol. 165, Issue 2 https://doi.org/10.1149/2.0881802jes	journal	January 2018
Computer Simulation Using Particles Hockney, R.; Eastwood, J. CRC Press https://doi.org/10.1201/9781439822050	book	January 1988

Similar Records

Recent advances in understanding the pH dependence of the hydrogen oxidation and evolution reactions

Journal Article · Thu Nov 01 00:00:00 EDT 2018 · Journal of Catalysis · OSTI ID:1543557

Determining the hydronium pKα at platinum surfaces and the effect on pH-dependent hydrogen evolution reaction kinetics

Journal Article · Mon Sep 19 00:00:00 EDT 2022 · Proceedings of the National Academy of Sciences of the United States of America · OSTI ID:1888062

Universal dependence of hydrogen oxidation and evolution reaction activity of platinum-group metals on pH and hydrogen binding energy

Journal Article · Fri Mar 18 00:00:00 EDT 2016 · Science Advances · OSTI ID:1466569

Cation- and pH-Dependent Hydrogen Evolution and Oxidation Reaction Kinetics

Citation Formats

References (78)

Similar Records

Related Subjects