Recent advances in understanding the pH dependence of the hydrogen oxidation and evolution reactions

Giles, Stephen A.; Wilson, Jon C.; Nash, Jared; Xu, Bingjun; Vlachos, Dionisios G.; Yan, Yushan

doi:10.1016/j.jcat.2018.09.030

Recent advances in understanding the pH dependence of the hydrogen oxidation and evolution reactions

Journal Article · Thu Nov 01 00:00:00 EDT 2018 · Journal of Catalysis

DOI:https://doi.org/10.1016/j.jcat.2018.09.030· OSTI ID:1543557

Giles, Stephen A.; Wilson, Jon C.; Nash, Jared; Xu, Bingjun; Vlachos, Dionisios G.; Yan, Yushan

Not provided.

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Catalysis Center for Energy Innovation (CCEI); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC); Univ. of Delaware, Newark, DE (United States)

Sponsoring Organization:: USDOE Advanced Research Projects Agency - Energy (ARPA-E); USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: AC02-05CH11231; AR0000771; SC0001004

OSTI ID:: 1543557

Journal Information:: Journal of Catalysis, Journal Name: Journal of Catalysis Journal Issue: C Vol. 367; ISSN 0021-9517

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

References (31)

Partial oxidation of step-bound water leads to anomalous pH effects on metal electrode step-edges Schwarz, Kathleen; Xu, Bingjun; Yan, Yushan Physical Chemistry Chemical Physics, Vol. 18, Issue 24 https://doi.org/10.1039/C6CP01652A	journal	January 2016
Further considerations on the thermodynamics of chemical equilibria and reaction rates Evans, M. G.; Polanyi, M. Transactions of the Faraday Society, Vol. 32 https://doi.org/10.1039/tf9363201333	journal	January 1936
pH and Alkali Cation Effects on the Pt Cyclic Voltammogram Explained Using Density Functional Theory McCrum, Ian T.; Janik, Michael J. The Journal of Physical Chemistry C, Vol. 120, Issue 1 https://doi.org/10.1021/acs.jpcc.5b10979	journal	December 2015
Trends in activity for the water electrolyser reactions on 3d M(Ni,Co,Fe,Mn) hydr(oxy)oxide catalysts Subbaraman, Ram; Tripkovic, Dusan; Chang, Kee-Chul Nature Materials, Vol. 11, Issue 6 https://doi.org/10.1038/nmat3313	journal	May 2012
Electrode Potentials and Hydration Energies. Theories and Correlations Rosseinsky, D. R. Chemical Reviews, Vol. 65, Issue 4 https://doi.org/10.1021/cr60236a004	journal	August 1965
Correlation between CO Oxidation and H Adsorption/Desorption on Pt Surfaces in a Wide pH Range: The Role of Alkali Cations García, Gonzalo ChemElectroChem, Vol. 4, Issue 3 https://doi.org/10.1002/celc.201600731	journal	January 2017
Die katalytische Zersetzung des Nitramids und ihre physikalisch-chemische Bedeutung Brönsted, J. N.; Pedersen, Kai Zeitschrift für Physikalische Chemie, Vol. 108U, Issue 1 https://doi.org/10.1515/zpch-1924-10814	journal	January 1924
Improving the hydrogen oxidation reaction rate by promotion of hydroxyl adsorption Strmcnik, Dusan; Uchimura, Masanobu; Wang, Chao Nature Chemistry, Vol. 5, Issue 4 https://doi.org/10.1038/nchem.1574	journal	February 2013
Interfacial water reorganization as a pH-dependent descriptor of the hydrogen evolution rate on platinum electrodes Ledezma-Yanez, Isis; Wallace, W. David Z.; Sebastián-Pascual, Paula Nature Energy, Vol. 2, Issue 4 https://doi.org/10.1038/nenergy.2017.31	journal	March 2017
Density functional theory calculations for the hydrogen evolution reaction in an electrochemical double layer on the Pt(111) electrode Skúlason, Egill; Karlberg, Gustav S.; Rossmeisl, Jan Phys. Chem. Chem. Phys., Vol. 9, Issue 25 https://doi.org/10.1039/B700099E	journal	January 2007
Explanation of Dramatic pH-Dependence of Hydrogen Binding on Noble Metal Electrode: Greatly Weakened Water Adsorption at High pH Cheng, Tao; Wang, Lu; Merinov, Boris V. Journal of the American Chemical Society, Vol. 140, Issue 25 https://doi.org/10.1021/jacs.8b04006	journal	May 2018
DFT Study of the Water–Gas Shift Reaction and Coke Formation on Ni(111) and Ni(211) Surfaces Catapan, Rafael C.; Oliveira, Amir A. M.; Chen, Ying The Journal of Physical Chemistry C, Vol. 116, Issue 38 https://doi.org/10.1021/jp302488f	journal	September 2012
Quaternary Ammonium Cation Specific Adsorption on Platinum Electrodes: A Combined Experimental and Density Functional Theory Study McCrum, I. T.; Hickner, M. A.; Janik, M. J. Journal of The Electrochemical Society, Vol. 165, Issue 2 https://doi.org/10.1149/2.1351802jes	journal	January 2018
Perspective—Towards Establishing Apparent Hydrogen Binding Energy as the Descriptor for Hydrogen Oxidation/Evolution Reactions Zheng, Jie; Nash, Jared; Xu, Bingjun Journal of The Electrochemical Society, Vol. 165, Issue 2 https://doi.org/10.1149/2.0881802jes	journal	January 2018
Hydration of metal surfaces can be dynamically heterogeneous and hydrophobic Limmer, David T.; Willard, Adam P.; Madden, Paul Proceedings of the National Academy of Sciences, Vol. 110, Issue 11 https://doi.org/10.1073/pnas.1301596110	journal	February 2013
Water dissociation on well-defined platinum surfaces: The electrochemical perspective van der Niet, Maria J. T. C.; Garcia-Araez, Nuria; Hernández, Javier Catalysis Today, Vol. 202 https://doi.org/10.1016/j.cattod.2012.04.059	journal	March 2013
New insights into the electrochemical hydrogen oxidation and evolution reaction mechanism Durst, J.; Siebel, A.; Simon, C. Energy Environ. Sci., Vol. 7, Issue 7 https://doi.org/10.1039/C4EE00440J	journal	January 2014
First-Principles-Based Kinetic Monte Carlo Simulation of the Structure Sensitivity of the Water–Gas Shift Reaction on Platinum Surfaces Stamatakis, Michail; Chen, Ying; Vlachos, Dionisios G. The Journal of Physical Chemistry C, Vol. 115, Issue 50 https://doi.org/10.1021/jp2071869	journal	November 2011
Enhancing Hydrogen Evolution Activity in Water Splitting by Tailoring Li+-Ni(OH)2-Pt Interfaces Subbaraman, R.; Tripkovic, D.; Strmcnik, D. Science, Vol. 334, Issue 6060 https://doi.org/10.1126/science.1211934	journal	December 2011
Infrared Reflection Absorption Spectroscopy of OH Adsorption on the Low Index Planes of Pt Tanaka, Hiroyuki; Sugawara, Seiho; Shinohara, Kazuhiko Electrocatalysis, Vol. 6, Issue 3 https://doi.org/10.1007/s12678-014-0245-7	journal	December 2014
Correlating Hydrogen Oxidation/Evolution Reaction Activity with the Minority Weak Hydrogen-Binding Sites on Ir/C Catalysts Zheng, Jie; Zhuang, Zhongbin; Xu, Bingjun ACS Catalysis, Vol. 5, Issue 7 https://doi.org/10.1021/acscatal.5b00247	journal	June 2015
Calculated Phase Diagrams for the Electrochemical Oxidation and Reduction of Water over Pt(111) Rossmeisl, Jan; Nørskov, Jens K.; Taylor, Christopher D. The Journal of Physical Chemistry B, Vol. 110, Issue 43 https://doi.org/10.1021/jp0631735	journal	November 2006
Correlating hydrogen oxidation and evolution activity on platinum at different pH with measured hydrogen binding energy Sheng, Wenchao; Zhuang, Zhongbin; Gao, Minrui Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms6848	journal	January 2015
Surface enhanced spectroscopic investigations of adsorption of cations on electrochemical interfaces Dunwell, M.; Wang, Junhua; Yan, Y. Physical Chemistry Chemical Physics, Vol. 19, Issue 2 https://doi.org/10.1039/C6CP07207K	journal	January 2017
A surface-enhanced infrared absorption spectroscopic study of pH dependent water adsorption on Au Dunwell, Marco; Yan, Yushan; Xu, Bingjun Surface Science, Vol. 650 https://doi.org/10.1016/j.susc.2015.12.019	journal	August 2016
Hydrated metal ions in aqueous solution: How regular are their structures? Persson, Ingmar Pure and Applied Chemistry, Vol. 82, Issue 10 https://doi.org/10.1351/PAC-CON-09-10-22	journal	August 2010
Work function, electronegativity, and electrochemical behaviour of metals Trasatti, Sergio Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 39, Issue 1 https://doi.org/10.1016/S0022-0728(72)80485-6	journal	September 1972
The role of non-covalent interactions in electrocatalytic fuel-cell reactions on platinum Strmcnik, D.; Kodama, K.; van der Vliet, D. Nature Chemistry, Vol. 1, Issue 6 https://doi.org/10.1038/nchem.330	journal	August 2009
Experimental Proof of the Bifunctional Mechanism for the Hydrogen Oxidation in Alkaline Media Li, Jingkun; Ghoshal, Shraboni; Bates, Michael K. Angewandte Chemie International Edition, Vol. 56, Issue 49 https://doi.org/10.1002/anie.201708484	journal	November 2017
Adsorbed Hydroxide Does Not Participate in the Volmer Step of Alkaline Hydrogen Electrocatalysis Intikhab, Saad; Snyder, Joshua D.; Tang, Maureen H. ACS Catalysis, Vol. 7, Issue 12 https://doi.org/10.1021/acscatal.7b02787	journal	November 2017
Co-adsorption of Cations as the Cause of the Apparent pH Dependence of Hydrogen Adsorption on a Stepped Platinum Single-Crystal Electrode Chen, Xiaoting; McCrum, Ian T.; Schwarz, Kathleen A. Angewandte Chemie International Edition, Vol. 56, Issue 47 https://doi.org/10.1002/anie.201709455	journal	October 2017

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