Universal dependence of hydrogen oxidation and evolution reaction activity of platinum-group metals on pH and hydrogen binding energy

Zheng, Jie; Sheng, Wenchao; Zhuang, Zhongbin; Xu, Bingjun; Yan, Yushan

doi:10.1126/sciadv.1501602

Title: Universal dependence of hydrogen oxidation and evolution reaction activity of platinum-group metals on pH and hydrogen binding energy

Journal Article · Fri Mar 18 00:00:00 EDT 2016 · Science Advances

DOI:https://doi.org/10.1126/sciadv.1501602· OSTI ID:1466569

Zheng, Jie ^[1]; Sheng, Wenchao ^[2]; Zhuang, Zhongbin ^[1]; Xu, Bingjun ^[1]; Yan, Yushan ^[1]

Univ. of Delaware, Newark, DE (United States). Dept. of Chemical and Biomolecular Engineering and Center for Catalytic Science and Technology
Columbia Univ., New York, NY (United States). Dept. of Chemical Engineering

An understanding how pH affects the activity of hydrogen oxidation reaction (HOR) and hydrogen evolution reaction (HER) is key to developing active, stable, and affordable HOR/HER catalysts for hydroxide exchange membrane fuel cells and electrolyzers. A common linear correlation between hydrogen binding energy (HBE) and pH is observed for four supported platinum-group metal catalysts (Pt/C, Ir/C, Pd/C, and Rh/C) over a broad pH range (0 to 13), suggesting that the pH dependence of HBE is metal-independent. A universal correlation between exchange current density and HBE is also observed on the four metals, indicating that they may share the same elementary steps and rate-determining steps and that the HBE is the dominant descriptor for HOR/HER activities. The onset potential of CO stripping on the four metals decreases with pH, indicating a stronger OH adsorption, which provides evidence against the promoting effect of adsorbed OH on HOR/HER.

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Research Organization:: Univ. of Delaware, Newark, DE (United States)

Sponsoring Organization:: USDOE Advanced Research Projects Agency - Energy (ARPA-E)

Grant/Contract Number:: AR0000009

OSTI ID:: 1466569

Journal Information:: Science Advances, Vol. 2, Issue 3; ISSN 2375-2548

Publisher:: AAASCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 518 works

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References (41)

Identification of Active Edge Sites for Electrochemical H₂ Evolution from MoS₂ Nanocatalysts Jaramillo, T. F.; Jorgensen, K. P.; Bonde, J. Science, Vol. 317, Issue 5834, p. 100-102 https://doi.org/10.1126/science.1141483	journal	July 2007
Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction Popczun, Eric J.; McKone, James R.; Read, Carlos G. Journal of the American Chemical Society, Vol. 135, Issue 25 https://doi.org/10.1021/ja403440e	journal	June 2013
Molybdenum Phosphosulfide: An Active, Acid-Stable, Earth-Abundant Catalyst for the Hydrogen Evolution Reaction Kibsgaard, Jakob; Jaramillo, Thomas F. Angewandte Chemie International Edition, Vol. 53, Issue 52 https://doi.org/10.1002/anie.201408222	journal	October 2014
CoSe ₂ Nanoparticles Grown on Carbon Fiber Paper: An Efficient and Stable Electrocatalyst for Hydrogen Evolution Reaction Kong, Desheng; Wang, Haotian; Lu, Zhiyi Journal of the American Chemical Society, Vol. 136, Issue 13 https://doi.org/10.1021/ja501497n	journal	March 2014
A nanoporous molybdenum carbide nanowire as an electrocatalyst for hydrogen evolution reaction Liao, Lei; Wang, Sinong; Xiao, Jingjing Energy Environ. Sci., Vol. 7, Issue 1 https://doi.org/10.1039/C3EE42441C	journal	January 2014
Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles Popczun, Eric J.; Read, Carlos G.; Roske, Christopher W. Angewandte Chemie International Edition, Vol. 53, Issue 21 https://doi.org/10.1002/anie.201402646	journal	April 2014
Non-precious metal electrocatalysts with high activity for hydrogen oxidation reaction in alkaline electrolytes Sheng, Wenchao; Bivens, Adam P.; Myint, MyatNoeZin Energy Environ. Sci., Vol. 7, Issue 5 https://doi.org/10.1039/C3EE43899F	journal	January 2014
Hydrogen evolution by a metal-free electrocatalyst Zheng, Yao; Jiao, Yan; Zhu, Yihan Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4783	journal	April 2014
Study of the Exchange Current Density for the Hydrogen Oxidation and Evolution Reactions Neyerlin, K. C.; Gu, Wenbin; Jorne, Jacob Journal of The Electrochemical Society, Vol. 154, Issue 7 https://doi.org/10.1149/1.2733987	journal	January 2007
Hydrogen Oxidation and Evolution Reaction Kinetics on Platinum: Acid vs Alkaline Electrolytes Sheng, Wenchao; Gasteiger, Hubert A.; Shao-Horn, Yang Journal of The Electrochemical Society, Vol. 157, Issue 11 https://doi.org/10.1149/1.3483106	journal	January 2010
New insights into the electrochemical hydrogen oxidation and evolution reaction mechanism Durst, J.; Siebel, A.; Simon, C. Energy Environ. Sci., Vol. 7, Issue 7 https://doi.org/10.1039/C4EE00440J	journal	January 2014
A basic solution Koper, Marc T. M. Nature Chemistry, Vol. 5, Issue 4 https://doi.org/10.1038/nchem.1600	journal	March 2013
Improving the hydrogen oxidation reaction rate by promotion of hydroxyl adsorption Strmcnik, Dusan; Uchimura, Masanobu; Wang, Chao Nature Chemistry, Vol. 5, Issue 4 https://doi.org/10.1038/nchem.1574	journal	February 2013
Correlating the hydrogen evolution reaction activity in alkaline electrolytes with the hydrogen binding energy on monometallic surfaces Sheng, Wenchao; Myint, MyatNoeZin; Chen, Jingguang G. Energy & Environmental Science, Vol. 6, Issue 5 https://doi.org/10.1039/c3ee00045a	journal	January 2013
Correlating hydrogen oxidation and evolution activity on platinum at different pH with measured hydrogen binding energy Sheng, Wenchao; Zhuang, Zhongbin; Gao, Minrui Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms6848	journal	January 2015
Pt–Ru catalyzed hydrogen oxidation in alkaline media: oxophilic effect or electronic effect? Wang, Ying; Wang, Gongwei; Li, Guangwei Energy & Environmental Science, Vol. 8, Issue 1 https://doi.org/10.1039/C4EE02564D	journal	January 2015
Work function, electronegativity, and electrochemical behaviour of metals Trasatti, Sergio Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 39, Issue 1 https://doi.org/10.1016/S0022-0728(72)80485-6	journal	September 1972
Trends in the Exchange Current for Hydrogen Evolution Nørskov, J. K.; Bligaard, T.; Logadottir, A. Journal of The Electrochemical Society, Vol. 152, Issue 3 https://doi.org/10.1149/1.1856988	journal	January 2005
(Invited) Hydrogen Oxidation and Evolution Reaction (HOR/HER) on Pt Electrodes in Acid vs. Alkaline Electrolytes: Mechanism, Activity and Particle Size Effects Durst, J.; Simon, C.; Siebel, A. ECS Transactions, Vol. 64, Issue 3 https://doi.org/10.1149/06403.1069ecst	journal	August 2014
Adsorption of phosphate species on poly-oriented Pt and Pt(111) electrodes over a wide range of pH Gisbert, Rubén; García, Gonzalo; Koper, Marc T. M. Electrochimica Acta, Vol. 55, Issue 27 https://doi.org/10.1016/j.electacta.2010.04.009	journal	November 2010
Water dissociation on well-defined platinum surfaces: The electrochemical perspective van der Niet, Maria J. T. C.; Garcia-Araez, Nuria; Hernández, Javier Catalysis Today, Vol. 202 https://doi.org/10.1016/j.cattod.2012.04.059	journal	March 2013
Near-surface ion distribution and buffer effects during electrochemical reactions Auinger, Michael; Katsounaros, Ioannis; Meier, Josef C. Physical Chemistry Chemical Physics, Vol. 13, Issue 36 https://doi.org/10.1039/c1cp21717h	journal	January 2011
The Potential of Zero Charge of Platinum and Its pH Dependence Gileadi, E.; Argade, S. D.; Bockris, J. O'M. The Journal of Physical Chemistry, Vol. 70, Issue 6 https://doi.org/10.1021/j100878a501	journal	June 1966
Hydrogen Oxidation and Evolution Reaction Kinetics on Carbon Supported Pt, Ir, Rh, and Pd Electrocatalysts in Acidic Media Durst, Julien; Simon, Christoph; Hasché, Frédéric Journal of The Electrochemical Society, Vol. 162, Issue 1 https://doi.org/10.1149/2.0981501jes	journal	November 2014
Correlating Hydrogen Oxidation/Evolution Reaction Activity with the Minority Weak Hydrogen-Binding Sites on Ir/C Catalysts Zheng, Jie; Zhuang, Zhongbin; Xu, Bingjun ACS Catalysis, Vol. 5, Issue 7 https://doi.org/10.1021/acscatal.5b00247	journal	June 2015
Temperature-Dependent Hydrogen Electrochemistry on Platinum Low-Index Single-Crystal Surfaces in Acid Solutions Marković, N. M.; Grgur, B. N.; Ross, P. N. The Journal of Physical Chemistry B, Vol. 101, Issue 27 https://doi.org/10.1021/jp970930d	journal	July 1997
Direct Observation of Electrocatalytic Synergy Zhuang, Lin; Jin, Jing; Abruña, Héctor D. Journal of the American Chemical Society, Vol. 129, Issue 36 https://doi.org/10.1021/ja0724792	journal	September 2007
Oxidation of carbon monoxide on poly-oriented and single-crystalline platinum electrodes over a wide range of pH Gisbert, Ruben; García, Gonzalo; Koper, Marc T. M. Electrochimica Acta, Vol. 56, Issue 5 https://doi.org/10.1016/j.electacta.2010.11.032	journal	February 2011
Kinetics of the Hydrogen Oxidation/Evolution Reaction on Polycrystalline Platinum in Alkaline Electrolyte Reaction Order with Respect to Hydrogen Pressure Rheinländer, Philipp J.; Herranz, Juan; Durst, Julien Journal of The Electrochemical Society, Vol. 161, Issue 14 https://doi.org/10.1149/2.0501414jes	journal	January 2014
Structural specificity of the kinetics of the hydrogen evolution reaction on the low-index surfaces of Pt single-crystal electrodes in 0.5 M dm−3 NaOH Barber, J. H.; Conway, B. E. Journal of Electroanalytical Chemistry, Vol. 461, Issue 1-2 https://doi.org/10.1016/S0022-0728(98)00161-2	journal	January 1999
Impedance spectroscopy of H and OH adsorption on stepped single-crystal platinum electrodes in alkaline and acidic media Schouten, K. J. P.; van der Niet, M. J. T. C.; Koper, M. T. M. Physical Chemistry Chemical Physics, Vol. 12, Issue 46 https://doi.org/10.1039/c0cp00104j	journal	January 2010
Effect of electrolyte environment and Pt crystallite size on hydrogen adsorption—V Kinoshita, K.; Ferrier, D. R.; Stonehart, P. Electrochimica Acta, Vol. 23, Issue 1 https://doi.org/10.1016/0013-4686(78)87032-7	journal	January 1978
Comparison of Hydrogen Electroadsorption from the Electrolyte with Hydrogen Adsorption from the Gas Phase Jerkiewicz, Gregory Journal of The Electrochemical Society, Vol. 143, Issue 4 https://doi.org/10.1149/1.1836623	journal	January 1996
Hydrogen adsorption on platinum, iridium and rhodium electrodes at reduced temperatures and the determination of real surface area Woods, R. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 49, Issue 2 https://doi.org/10.1016/S0022-0728(74)80229-9	journal	January 1974
The nature of adsorbed oxygen on rhodium, palladium and gold electrodes Rand, D. A. J.; Woods, R. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 31, Issue 1 https://doi.org/10.1016/S0022-0728(71)80039-6	journal	June 1971
Correcting the Hydrogen Diffusion Limitation in Rotating Disk Electrode Measurements of Hydrogen Evolution Reaction Kinetics Zheng, Jie; Yan, Yushan; Xu, Bingjun Journal of The Electrochemical Society, Vol. 162, Issue 14 https://doi.org/10.1149/2.0501514jes	journal	January 2015
Molybdenum Phosphosulfide: An Active, Acid-Stable, Earth-Abundant Catalyst for the Hydrogen Evolution Reaction Kibsgaard, Jakob; Jaramillo, Thomas F. Angewandte Chemie, Vol. 126, Issue 52 https://doi.org/10.1002/ange.201408222	journal	October 2014
Invited: Hydrogen Oxidation and Evolution Reaction (HOR/HER) on Pt Electrodes in Acid vs. Alkaline Electrolytes: Mechanism, Activity and Particle Size Effects Durst, Julien; Simon, Christoph; Siebel, Armin ECS Meeting Abstracts, Vol. MA2014-02, Issue 21, p. 1074-1074 https://doi.org/10.1149/ma2014-02/21/1074	journal	August 2014
Trends in the Exchange Current for Hydrogen Evolution. Noerskov, J. K.; Bligaard, T.; Logadottir, A. ChemInform, Vol. 36, Issue 24 https://doi.org/10.1002/chin.200524023	journal	June 2005
Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles Popczun, Eric J.; Read, Carlos G.; Roske, Christopher W. Angewandte Chemie, Vol. 126, Issue 21, p. 5531-5534 https://doi.org/10.1002/ange.201402646	journal	April 2014
Limiting oxygen coverage on platinized platinum; Relevance to determination of real platinum area by hydrogen adsorption Biegler, T.; Rand, D. A. J.; Woods, R. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 29, Issue 2 https://doi.org/10.1016/s0022-0728(71)80089-x	journal	February 1971

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Mediator-Free SECM for Probing the Diffusion Layer pH with Functionalized Gold Ultramicroelectrodes Monteiro, Mariana C. O.; Jacobse, Leon; Touzalin, Thomas Analytical Chemistry, Vol. 92, Issue 2 https://doi.org/10.1021/acs.analchem.9b04952	journal	December 2019
Electrodeposition of Rhodium Nanowires Arrays and Their Morphology-Dependent Hydrogen Evolution Activity Zhang, Liqiu; Liu, Lichun; Wang, Hongdan Nanomaterials, Vol. 7, Issue 5 https://doi.org/10.3390/nano7050103	journal	May 2017

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