A Tracer Study on sCO2 Corrosion with Multiple Oxygen-Bearing Impurities

Lehmusto, Juho; Ievlev, Anton V.; Cakmak, Ercan; Keiser, James R.; Pint, Bruce A.

doi:10.1007/s11085-021-10071-6

A Tracer Study on sCO2 Corrosion with Multiple Oxygen-Bearing Impurities

Journal Article · Thu Jul 22 00:00:00 EDT 2021 · Oxidation of Metals

DOI:https://doi.org/10.1007/s11085-021-10071-6· OSTI ID:1809330

; Ievlev, Anton V.; Cakmak, Ercan; Keiser, James R.; Pint, Bruce A.

Abstract

Several modern power production systems utilize supercritical CO ₂ (sCO ₂ ), which can contain O ₂ and H ₂ O as impurities. These impurities may degrade the compatibility of structural alloys through accelerated oxidation. However, it remains unclear which of these impurities plays a bigger role in high-temperature reactions taking place in sCO ₂ . In this study, various model and commercial Fe‐ and Ni‐based alloys were exposed in 300 bar sCO ₂ at 750 °C to low levels (50 ppm) of O ₂ and H ₂ O for 1,000 h. ¹⁸ O-enriched water was used to enable the identification of the oxygen source in the post-exposure characterization of the samples. However, oxygen from the water did not accumulate in the scale, which consisted of Cr ₂ O ₃ in the cases where a protective oxide formed. A 2wt.% Ti addition to a Ni-22%Cr model alloy resulted in the formation of thicker oxides in sCO ₂ , while a 1wt.% Al addition reduced the scale thickness. A synergistic effect of both Al and Ti additions resulted in an even thicker oxide than what was formed solely by Ti, similar to observations for Ni-based alloy 282.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE; USDOE Office of Fossil Energy (FE)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1809330

Alternate ID(s):: OSTI ID: 1828265

Journal Information:: Oxidation of Metals, Journal Name: Oxidation of Metals Journal Issue: 5-6 Vol. 96; ISSN 0030-770X

Publisher:: Springer Science + Business MediaCopyright Statement

Country of Publication:: United States

Language:: English

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