High-Temperature Oxidation Study in a Multi-Oxidant Environment Using 18O Tracer

Lehmusto, Juho; Ievlev, Anton; Kurley III, James; Pint, Bruce A.

doi:10.1007/s11085-024-10323-1

High-Temperature Oxidation Study in a Multi-Oxidant Environment Using ¹⁸O Tracer

Journal Article · Thu Nov 28 00:00:00 EST 2024 · High Temperature Corrosion of Materials

DOI:https://doi.org/10.1007/s11085-024-10323-1· OSTI ID:2538377

Lehmusto, Juho ^[1]; ^[2]; ^[2]; ^[2]

Abo Akademi University, Turku (Finland)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

The goal of this study was to use ¹⁸O-enriched water to better understand the role of H₂O in high-temperature oxidation. Seven model and three commercial M-Cr and M-Cr-Al alloys were studied in air with 10% of H₂O at 800 °C for 5 h. Oxygen from water vapor was more reactive than oxygen from the air and ¹⁸O enriched at the outermost layers of the formed Cr- and Al-rich oxides. Alloys with Al and/or Ti additions showed signs of internal oxidation but ¹⁸O was not enriched inside the alloy in locations with internal oxidation. In conclusion, depending on the alloy Al content, the oxide went from Al oxidation beneath a chromia scale to external alumina scale formation.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Energy Efficiency Office. Industrial Efficiency & Decarbonization Office (IEDO)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 2538377

Journal Information:: High Temperature Corrosion of Materials, Journal Name: High Temperature Corrosion of Materials Journal Issue: 1 Vol. 102; ISSN 2731-8397

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

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36 MATERIALS SCIENCE
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