A pair of metal organic framework (MOF)-derived oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) catalysts for zinc-air batteries

Agarwal, Soham; Yu, Xingwen; Manthiram, Arumugam

doi:10.1016/j.mtener.2020.100405

Title: A pair of metal organic framework (MOF)-derived oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) catalysts for zinc-air batteries

Journal Article · Tue Mar 31 00:00:00 EDT 2020 · Materials Today Energy

DOI:https://doi.org/10.1016/j.mtener.2020.100405· OSTI ID:1801681

^[1]; Yu, Xingwen ^[1];

^[1]

University of Texas, Austin, TX (United States)

Metal organic frameworks (MOFs) are amazing precursors for the development of functional catalysts due to their ability of being modified both structurally and in terms of composition. Here this work presents a pair of MOF - derived oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) catalysts for the advancement of zinc-air batteries. Zeolitic imidazolate frameworks (ZIF) are known as ideal materials to create doped carbons. Combining with a sacrificial tellurium template, we have developed a “pseudo-carbon nanotube” with a ZIF-8 that is doped with a mixture of zinc, cobalt, and iron. The resulting mixed-metal doped porous carbon nanotubes (CoFeZn@pCNT) show excellent catalytic activity for ORR with a half-way ORR potential (E_1/2) of 0.87 V vs. RHE (reverse hydrogen electrode). Iridium-based catalysts are known as the best option for OER so far, but it is not viable for practical applications due to cost restrictions. Previous research into alternative catalysts has focused on metal oxides with first-row transition metals. Metal sulfides provide superior conductivity compared to metal oxides and are a new frontier in the search for affordable, active, and stable OER catalysts. By combining cobalt, iron, and nickel into a MOF structure (ZIF-67), followed by a sulfurization process, a MOF-derived mixed-metal sulfide catalyst (FeCoNi–S@ZIF) has been developed in this study. The resulting catalysts show an onset OER potential of 1.65 V vs. RHE at 10 mA cm^-2 and exhibit remarkable stability for the operation of zinc-air batteries.

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Research Organization:: Univ. of Texas, Austin, TX (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE)

Grant/Contract Number:: SC0005397

OSTI ID:: 1801681

Journal Information:: Materials Today Energy, Vol. 16, Issue C; ISSN 2468-6069

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (58)

Interface engineered in situ anchoring of Co ₉ S ₈ nanoparticles into a multiple doped carbon matrix: highly efficient zinc–air batteries Li, Yang; Zhou, Wei; Dong, Juncai Nanoscale, Vol. 10, Issue 5 https://doi.org/10.1039/C7NR07235J	journal	January 2018
Nanoporous Nitrogen-Doped Graphene Oxide/Nickel Sulfide Composite Sheets Derived from a Metal-Organic Framework as an Efficient Electrocatalyst for Hydrogen and Oxygen Evolution Jayaramulu, Kolleboyina; Masa, Justus; Tomanec, Ondrej Advanced Functional Materials, Vol. 27, Issue 33 https://doi.org/10.1002/adfm.201700451	journal	July 2017
Nitrogen-Doped Carbon Nanotube Arrays with High Electrocatalytic Activity for Oxygen Reduction Gong, K.; Du, F.; Xia, Z. Science, Vol. 323, Issue 5915, p. 760-764 https://doi.org/10.1126/science.1168049	journal	February 2009
Renewable Energy Sources and the Realities of Setting an Energy Agenda Potocnik, J. Science, Vol. 315, Issue 5813 https://doi.org/10.1126/science.1139086	journal	February 2007
(Fe,Co)@nitrogen-doped graphitic carbon nanocubes derived from polydopamine-encapsulated metal–organic frameworks as a highly stable and selective non-precious oxygen reduction electrocatalyst Xi, Jiangbo; Xia, Yating; Xu, Yangyang Chemical Communications, Vol. 51, Issue 52 https://doi.org/10.1039/C5CC03946K	journal	January 2015
Co/CoP embedded in a hairy nitrogen-doped carbon polyhedron as an advanced tri-functional electrocatalyst Hao, Yongchao; Xu, Yuqi; Liu, Wen Materials Horizons, Vol. 5, Issue 1 https://doi.org/10.1039/C7MH00706J	journal	January 2018
The geographical distribution of fossil fuels unused when limiting global warming to 2 °C McGlade, Christophe; Ekins, Paul Nature, Vol. 517, Issue 7533 https://doi.org/10.1038/nature14016	journal	January 2015
MOF derived catalysts for electrochemical oxygen reduction Wang, Xiaojuan; Zhou, Junwen; Fu, He J. Mater. Chem. A, Vol. 2, Issue 34 https://doi.org/10.1039/C4TA01506A	journal	January 2014
In Situ Synthesis Strategy for Hierarchically Porous Ni ₂ P Polyhedrons from MOFs Templates with Enhanced Electrochemical Properties for Hydrogen Evolution Yan, Liting; Dai, Pengcheng; Wang, Ying ACS Applied Materials & Interfaces, Vol. 9, Issue 13 https://doi.org/10.1021/acsami.7b01037	journal	March 2017
Mechanism of oxygen reactions at porous oxide electrodes. Part 2—Oxygen evolution at RuO2, IrO2 and IrxRu1−xO2 electrodes in aqueous acid and alkaline solution Lyons, Michael E. G.; Floquet, Stephane Physical Chemistry Chemical Physics, Vol. 13, Issue 12 https://doi.org/10.1039/c0cp02875d	journal	January 2011
Energy from Fossil Fuels Hubbert, M. K. Science, Vol. 109, Issue 2823 https://doi.org/10.1126/science.109.2823.103	journal	February 1949
A lithium–oxygen battery with a long cycle life in an air-like atmosphere Asadi, Mohammad; Sayahpour, Baharak; Abbasi, Pedram Nature, Vol. 555, Issue 7697 https://doi.org/10.1038/nature25984	journal	March 2018
Mixed Metal Sulfides for Electrochemical Energy Storage and Conversion Yu, Xin Yao; David Lou, Xiong Wen Advanced Energy Materials, Vol. 8, Issue 3 https://doi.org/10.1002/aenm.201701592	journal	September 2017
The Lithium/Air Battery: Still an Emerging System or a Practical Reality? Grande, Lorenzo; Paillard, Elie; Hassoun, Jusef Advanced Materials, Vol. 27, Issue 5 https://doi.org/10.1002/adma.201403064	journal	December 2014
Electrochemical reduction of oxygen on platinum nanoparticles in alkaline media Geniès, L.; Faure, R.; Durand, R. Electrochimica Acta, Vol. 44, Issue 8-9 https://doi.org/10.1016/S0013-4686(98)00254-0	journal	December 1998
Increased Use of Renewable Energy Abelson, P. H. Science, Vol. 253, Issue 5024 https://doi.org/10.1126/science.253.5024.1073	journal	September 1991
Metal-Organic Frameworks as Platforms for Catalytic Applications Jiao, Long; Wang, Yang; Jiang, Hai-Long Advanced Materials, Vol. 30, Issue 37 https://doi.org/10.1002/adma.201703663	journal	November 2017
Developments of Metal Phosphides as Efficient OER Precatalysts Dutta, Anirban; Pradhan, Narayan The Journal of Physical Chemistry Letters, Vol. 8, Issue 1 https://doi.org/10.1021/acs.jpclett.6b02249	journal	December 2016
Electrical Energy Storage for the Grid: A Battery of Choices Dunn, B.; Kamath, H.; Tarascon, J. -M. Science, Vol. 334, Issue 6058 https://doi.org/10.1126/science.1212741	journal	November 2011
Metal-organic frameworks James, Stuart L. Chemical Society Reviews, Vol. 32, Issue 5 https://doi.org/10.1039/b200393g	journal	January 2003
Metal and metal oxidenanoparticle synthesis from metal organic frameworks (MOFs): finding the border of metal and metal oxides Das, Raja; Pachfule, Pradip; Banerjee, Rahul Nanoscale, Vol. 4, Issue 2 https://doi.org/10.1039/C1NR10944H	journal	January 2012
A Versatile Iron-Tannin-Framework Ink Coating Strategy to Fabricate Biomass-Derived Iron Carbide/Fe-N-Carbon Catalysts for Efficient Oxygen Reduction Wei, Jing; Liang, Yan; Hu, Yaoxin Angewandte Chemie International Edition, Vol. 55, Issue 4 https://doi.org/10.1002/anie.201509024	journal	December 2015
Controllable Construction of Core-Shell Polymer@Zeolitic Imidazolate Frameworks Fiber Derived Heteroatom-Doped Carbon Nanofiber Network for Efficient Oxygen Electrocatalysis Zhao, Yingxuan; Lai, Qingxue; Zhu, Junjie Small, Vol. 14, Issue 19 https://doi.org/10.1002/smll.201704207	journal	March 2018
One-Dimensional Arrays of Co ₃ O ₄ Nanoparticles: Synthesis, Characterization, and Optical and Electrochemical Properties Wang, Xiong; Chen, Xiangying; Gao, Lisheng The Journal of Physical Chemistry B, Vol. 108, Issue 42 https://doi.org/10.1021/jp048016p	journal	October 2004
Syntheses and Characterization of Six Coordination Polymers of Zinc(II) and Cobalt(II) with 1,3,5-Benzenetricarboxylate Anion and Bis(imidazole) Ligands Liu, Ying-Ying; Ma, Jian-Fang; Yang, Jin Inorganic Chemistry, Vol. 46, Issue 8 https://doi.org/10.1021/ic061575l	journal	April 2007
Trimetallic Sulfide Mesoporous Nanospheres as Superior Electrocatalysts for Rechargeable Zn-Air Batteries Yang, Haozhou; Wang, Bin; Li, Haoyi Advanced Energy Materials, Vol. 8, Issue 34 https://doi.org/10.1002/aenm.201801839	journal	October 2018
Food Security: Fossil Fuels White, R. E.; Grossman, R. Science, Vol. 328, Issue 5975 https://doi.org/10.1126/science.328.5975.173-a	journal	April 2010
Electrocatalytic oxygen evolution on reactively sputtered electrochromic iridium oxide films Beni, G.; Schiavone, L. M.; Shay, J. L. Nature, Vol. 282, Issue 5736 https://doi.org/10.1038/282281a0	journal	November 1979
Heteroatom-Doped Graphitic Carbon Catalysts for Efficient Electrocatalysis of Oxygen Reduction Reaction Zhang, Jintao; Dai, Liming ACS Catalysis, Vol. 5, Issue 12 https://doi.org/10.1021/acscatal.5b01563	journal	November 2015
Recent Progress in MOF-Derived, Heteroatom-Doped Porous Carbons as Highly Efficient Electrocatalysts for Oxygen Reduction Reaction in Fuel Cells Yang, Liu; Zeng, Xiaofei; Wang, Wenchuan Advanced Functional Materials, Vol. 28, Issue 7 https://doi.org/10.1002/adfm.201704537	journal	December 2017
Fossil-fuel divestment campaign hits resistance Tollefson, Jeff Nature, Vol. 521, Issue 7550 https://doi.org/10.1038/521016a	journal	May 2015
Amorphous MOF Introduced N-Doped Graphene: An Efficient and Versatile Electrocatalyst for Zinc–Air Battery and Water Splitting Niu, Wenhan; Yang, Yang ACS Applied Energy Materials, Vol. 1, Issue 6 https://doi.org/10.1021/acsaem.8b00594	journal	May 2018
“Wiring” Fe-N _x -Embedded Porous Carbon Framework onto 1D Nanotubes for Efficient Oxygen Reduction Reaction in Alkaline and Acidic Media Ahn, Sung Hoon; Yu, Xingwen; Manthiram, Arumugam Advanced Materials, Vol. 29, Issue 26 https://doi.org/10.1002/adma.201606534	journal	April 2017
Synthesis and Activities of Rutile IrO ₂ and RuO ₂ Nanoparticles for Oxygen Evolution in Acid and Alkaline Solutions Lee, Youngmin; Suntivich, Jin; May, Kevin J. The Journal of Physical Chemistry Letters, Vol. 3, Issue 3 https://doi.org/10.1021/jz2016507	journal	January 2012
Studies on Imidazole Compounds. I. A Synthesis of Imidazoles with Functional Groups in the 2-Position Jones, Reuben G. Journal of the American Chemical Society, Vol. 71, Issue 2 https://doi.org/10.1021/ja01170a002	journal	February 1949
The food-energy-water nexus and urban complexity Romero-Lankao, Patricia; McPhearson, Timon; Davidson, Debra J. Nature Climate Change, Vol. 7, Issue 4 https://doi.org/10.1038/nclimate3260	journal	April 2017
Room temperature synthesis of metal-organic frameworks: MOF-5, MOF-74, MOF-177, MOF-199, and IRMOF-0 Tranchemontagne, David J.; Hunt, Joseph R.; Yaghi, Omar M. Tetrahedron, Vol. 64, Issue 36, p. 8553-8557 https://doi.org/10.1016/j.tet.2008.06.036	journal	September 2008
Alveoli-Inspired Facile Transport Structure of N-Doped Porous Carbon for Electrochemical Energy Applications Chung, Dong Young; Lee, Kyung Jae; Yu, Seung-Ho Advanced Energy Materials, Vol. 5, Issue 3 https://doi.org/10.1002/aenm.201401309	journal	October 2014
The mechanism and kinetics of electrochemical water oxidation at oxidized metal and metal oxide electrodes. Part 2. The surfaquo group mechanism: A mini review Lyons, Michael E. G.; Doyle, Richard L.; Fernandez, Damaris Electrochemistry Communications, Vol. 45 https://doi.org/10.1016/j.elecom.2014.04.019	journal	August 2014
Atomically Dispersed Fe-N _x /C Electrocatalyst Boosts Oxygen Catalysis via a New Metal-Organic Polymer Supramolecule Strategy Miao, Zhengpei; Wang, Xiaoming; Tsai, Meng-Che Advanced Energy Materials, Vol. 8, Issue 24 https://doi.org/10.1002/aenm.201801226	journal	July 2018
Long-Life, High-Voltage Acidic Zn-Air Batteries Li, Longjun; Manthiram, Arumugam Advanced Energy Materials, Vol. 6, Issue 5 https://doi.org/10.1002/aenm.201502054	journal	December 2015
Hierarchical iridium-based multimetallic alloy with double-core-shell architecture for efficient overall water splitting Zhang, Jie; Chen, Zelin; Liu, Chang Science China Materials, Vol. 63, Issue 2 https://doi.org/10.1007/s40843-019-1176-6	journal	September 2019
Atomic Radii in Crystals Slater, J. C. The Journal of Chemical Physics, Vol. 41, Issue 10 https://doi.org/10.1063/1.1725697	journal	November 1964
A dual-electrolyte rechargeable Li-air battery with phosphate buffer catholyte Li, Longjun; Zhao, Xinsheng; Manthiram, Arumugam Electrochemistry Communications, Vol. 14, Issue 1, p. 78-81 https://doi.org/10.1016/j.elecom.2011.11.007	journal	January 2012
Bimetal–Organic Framework Self-Adjusted Synthesis of Support-Free Nonprecious Electrocatalysts for Efficient Oxygen Reduction You, Bo; Jiang, Nan; Sheng, Meili ACS Catalysis, Vol. 5, Issue 12 https://doi.org/10.1021/acscatal.5b02325	journal	October 2015
An efficient Co–N–C oxygen reduction catalyst with highly dispersed Co sites derived from a ZnCo bimetallic zeolitic imidazolate framework Wang, Xiaojuan; Fan, Xinxin; Lin, Honghong RSC Advances, Vol. 6, Issue 44 https://doi.org/10.1039/C6RA04771H	journal	January 2016
The Global Food-Energy-Water Nexus D'Odorico, Paolo; Davis, Kyle Frankel; Rosa, Lorenzo Reviews of Geophysics, Vol. 56, Issue 3 https://doi.org/10.1029/2017RG000591	journal	July 2018
Zinc–Air Battery: Understanding the Structure and Morphology Changes of Graphene-Supported CoMn ₂ O ₄ Bifunctional Catalysts Under Practical Rechargeable Conditions Prabu, Moni; Ramakrishnan, Prakash; Nara, Hiroki ACS Applied Materials & Interfaces, Vol. 6, Issue 19 https://doi.org/10.1021/am5047476	journal	September 2014
MOFs nanosheets derived porous metal oxide-coated three-dimensional substrates for lithium-ion battery applications Fang, Guozhao; Zhou, Jiang; Liang, Caiwu Nano Energy, Vol. 26 https://doi.org/10.1016/j.nanoen.2016.05.009	journal	August 2016
Aromatic Poly(ether ketone)s with Pendant Sulfonic Acid Phenyl Groups Prepared by a Mild Sulfonation Method for Proton Exchange Membranes Liu, Baijun; Robertson, Gilles P.; Kim, Dae-Sik Macromolecules, Vol. 40, Issue 6 https://doi.org/10.1021/ma061705+	journal	February 2007
Hasten end of dated fossil-fuel subsidies Martin, Tara Nature, Vol. 538, Issue 7624 https://doi.org/10.1038/538171c	journal	October 2016
Thermodynamic Guidelines for the Design of Bimetallic Catalysts for Oxygen Electroreduction and Rapid Screening by Scanning Electrochemical Microscopy. M−Co (M: Pd, Ag, Au) Fernández, José L.; Walsh, Darren A.; Bard, Allen J. Journal of the American Chemical Society, Vol. 127, Issue 1 https://doi.org/10.1021/ja0449729	journal	January 2005
Electrically Rechargeable Zinc-Air Batteries: Progress, Challenges, and Perspectives Fu, Jing; Cano, Zachary Paul; Park, Moon Gyu Advanced Materials, Vol. 29, Issue 7 https://doi.org/10.1002/adma.201604685	journal	November 2016
Metal–Organic Framework Materials as Chemical Sensors Kreno, Lauren E.; Leong, Kirsty; Farha, Omar K. Chemical Reviews, Vol. 112, Issue 2, p. 1105-1125 https://doi.org/10.1021/cr200324t	journal	September 2011
Kinetic Analysis of Oxygen Reduction on Pt(111) in Acid Solutions: Intrinsic Kinetic Parameters and Anion Adsorption Effects Wang, J. X.; Markovic, N. M.; Adzic, R. R. The Journal of Physical Chemistry B, Vol. 108, Issue 13, p. 4127-4133 https://doi.org/10.1021/jp037593v	journal	April 2004
Switching effective oxygen reduction and evolution performance by controlled graphitization of a cobalt–nitrogen–carbon framework system Gadipelli, Srinivas; Zhao, Tingting; Shevlin, Stephen A. Energy & Environmental Science, Vol. 9, Issue 5 https://doi.org/10.1039/C6EE00551A	journal	January 2016
Smart grids: The energy storage problem Lindley, David Nature, Vol. 463, Issue 7277 https://doi.org/10.1038/463018a	journal	January 2010
The effect of synthesis temperature on the particle size of nano-ZIF-8 Tsai, Chih-Wei; Langner, Ernie H. G. Microporous and Mesoporous Materials, Vol. 221 https://doi.org/10.1016/j.micromeso.2015.08.041	journal	February 2016

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Title: A pair of metal organic framework (MOF)-derived oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) catalysts for zinc-air batteries

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