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Die Molybdän(V)‐ und Wolfram(VI)‐oxoazide [MoO(N 3 ) 3 ], [MoO(N 3 ) 3 ⋅2 CH 3 CN], [(bipy)MoO(N 3 ) 3 ], [MoO(N 3 ) 5 ] 2− , [WO(N 3 ) 4 ] und [WO(N 3 ) 4 ⋅CH 3 CN] (in German)

Journal Article · · Angewandte Chemie
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Abstract

Eine Serie neuartiger Molybdän(V)‐ und Wolfram(VI)‐oxoazide wurde ausgehend von [MOF 4 ] (M=Mo, W) und Me 3 SiN 3 synthetisiert. Während [WO(N 3 ) 4 ] durch Fluorid‐Azid‐Austausch in der Umsetzung von Me 3 SiN 3 mit [WOF 4 ] in SO 2 ‐Lösung erhalten wurde, resultierte die Reaktion mit MoOF 4 in einer Reduktion von Mo VI zu Mo V unter Bildung von [MoO(N 3 ) 3 ]. Entsprechende Umsetzungen in Acetonitrillösung führten zur Isolierung der Addukte [MoO(N 3 ) 3 ⋅2 CH 3 CN] und [WO(N 3 ) 4 ⋅CH 3 CN]. [(bipy)MoO(N 3 ) 3 ] und [PPh 4 ] 2 [MoO(N 3 ) 5 ] konnten nach anschließenden Umsetzungen von [MoO(N 3 ) 3 ] mit 2,2′‐Bipyridin bzw. [PPh 4 ][N 3 ] isoliert werden. Die Molybdän(V)‐ und Wolfram(VI)‐oxoazide wurden schwingungsspektroskopisch, bezüglich ihrer Empfindlichkeit gegenüber Schlag, Reibung und Erhitzen, und im Fall von [WO(N 3 ) 4 ⋅CH 3 CN], [(bipy)MoO(N 3 ) 3 ] und [PPh 4 ] 2 [MoO(N 3 ) 5 ] auch durch Kristallstrukturanalysen charakterisiert.

Sponsoring Organization:
USDOE
OSTI ID:
1786183
Journal Information:
Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 51 Vol. 127; ISSN 0044-8249
Publisher:
Wiley Blackwell (John Wiley & Sons)Copyright Statement
Country of Publication:
Germany
Language:
German

References (53)

Explosives book July 2007
Kovalente anorganische Azide journal March 1995
Polyazide Chemistry: Preparation and Characterization of As(N3)5, Sb(N3)5, and [P(C6H5)4][Sb(N3)6] journal December 2004
Polyazide Chemistry: The First Binary Group 6 Azides, Mo(N3)6, W(N3)6, [Mo(N3)7]?, and [W(N3)7]?, and the [NW(N3)4]? and [NMo(N3)4]? Ions journal March 2005
Coordination Adducts of Niobium(V) and Tantalum(V) Azide M(N 3 ) 5 (M=Nb, Ta) with Nitrogen Donor Ligands and their Self-Ionization journal April 2014
Preparation of the First Manganese(III) and Manganese(IV) Azides journal July 2014
The Vanadium(V) Oxoazides [VO(N 3 ) 3 ], [(bipy)VO(N 3 ) 3 ], and [VO(N 3 ) 5 ] 2− journal June 2015
The First Molybdenum(VI) and Tungsten(VI) Oxoazides MO 2 (N 3 ) 2 , MO 2 (N 3 ) 2 ⋅2 CH 3 CN, (bipy)MO 2 (N 3 ) 2 , and [MO 2 (N 3 ) 4 ] 2− (M=Mo, W) journal July 2015
Covalent Inorganic Azides journal March 1995
Polyazide Chemistry: Preparation and Characterization of As(N3)5, Sb(N3)5, and [P(C6H5)4][Sb(N3)6] journal December 2004
Polyazide Chemistry: The First Binary Group 6 Azides, Mo(N3)6, W(N3)6, [Mo(N3)7]?, and [W(N3)7]?, and the [NW(N3)4]? and [NMo(N3)4]? Ions journal March 2005
Coordination Adducts of Niobium(V) and Tantalum(V) Azide M(N 3 ) 5 (M=Nb, Ta) with Nitrogen Donor Ligands and their Self-Ionization journal April 2014
Preparation of the First Manganese(III) and Manganese(IV) Azides journal July 2014
The Vanadium(V) Oxoazides [VO(N 3 ) 3 ], [(bipy)VO(N 3 ) 3 ], and [VO(N 3 ) 5 ] 2− journal June 2015
The First Molybdenum(VI) and Tungsten(VI) Oxoazides MO 2 (N 3 ) 2 , MO 2 (N 3 ) 2 ⋅2 CH 3 CN, (bipy)MO 2 (N 3 ) 2 , and [MO 2 (N 3 ) 4 ] 2− (M=Mo, W) journal July 2015
Recent Developments in the Chemistry of Covalent Azides journal April 1997
First Structural Characterization of Binary AsIII and SbIII Azides journal January 2004
Molpro: a general-purpose quantum chemistry program package: Molpro
  • Werner, Hans-Joachim; Knowles, Peter J.; Knizia, Gerald
  • Wiley Interdisciplinary Reviews: Computational Molecular Science, Vol. 2, Issue 2 https://doi.org/10.1002/wcms.82
journal July 2011
Azide Chemistry - An Inorganic Perspective, Part I Metal ­Azides: Overview, General Trends and Recent Developments journal June 2013
Perturbative corrections to account for triple excitations in closed and open shell coupled cluster theories journal September 1994
A fifth-order perturbation comparison of electron correlation theories journal May 1989
Restricted Møller—Plesset theory for open-shell molecules journal November 1991
Quantum Mechanical Continuum Solvation Models journal August 2005
Why Are [P(C 6 H 5 ) 4 ] + N 3 − and [As(C 6 H 5 ) 4 ] + N 3 − Ionic Salts and Sb(C 6 H 5 ) 4 N 3 and Bi(C 6 H 5 ) 4 N 3 Covalent Solids? A Theoretical Study Provides an Unexpected Answer journal April 2011
Third Row Transition Metal Hexafluorides, Extraordinary Oxidizers, and Lewis Acids: Electron Affinities, Fluoride Affinities, and Heats of Formation of WF 6 , ReF 6 , OsF 6 , IrF 6 , PtF 6 , and AuF 6 † journal February 2010
Electron Affinities, Fluoride Affinities, and Heats of Formation of the Second Row Transition Metal Hexafluorides: MF 6 (M = Mo, Tc, Ru, Rh, Pd, Ag) journal June 2010
Oxidation, Reduction, and Condensation of Alcohols over (MO 3 ) 3 (M = Mo, W) Nanoclusters journal September 2014
Dehydration, dehydrogenation, and condensation of alcohols on supported oxide catalysts based on cyclic (WO 3 ) 3 and (MoO 3 ) 3 clusters journal January 2014
COSMO: a new approach to dielectric screening in solvents with explicit expressions for the screening energy and its gradient journal January 1993
Fluoride crystal structures. Part I. Tungsten oxide tetrafluoride journal January 1968
Fluoride crystal structures. Part II. Molybdenum oxide tetrafluoride journal January 1968
Systematically convergent basis sets for transition metals. I. All-electron correlation consistent basis sets for the 3d elements Sc–Zn journal August 2005
Basis set limit electronic excitation energies, ionization potentials, and electron affinities for the 3d transition metal atoms: Coupled cluster and multireference methods journal August 2006
Energy-consistent relativistic pseudopotentials and correlation consistent basis sets for the 4d elements Y–Pd journal March 2007
Energy-consistent pseudopotentials and correlation consistent basis sets for the 5d elements Hf–Pt journal April 2009
A full coupled‐cluster singles and doubles model: The inclusion of disconnected triples journal February 1982
Electron affinities of the first‐row atoms revisited. Systematic basis sets and wave functions journal May 1992
Coupled‐cluster methods with noniterative triple excitations for restricted open‐shell Hartree–Fock and other general single determinant reference functions. Energies and analytical gradients journal June 1993
Density‐functional thermochemistry. III. The role of exact exchange journal April 1993
Coupled cluster theory for high spin, open shell reference wave functions journal October 1993
Erratum: “Coupled cluster theory for high spin, open shell reference wave functions” [ J. Chem. Phys. 99 , 5219 (1993)] journal February 2000
Note on an Approximation Treatment for Many-Electron Systems journal October 1934
Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density journal January 1988
Coupled-cluster theory in quantum chemistry journal February 2007
ShelXle : a Qt graphical user interface for SHELXL journal November 2011
ORTEP -3 for Windows - a version of ORTEP -III with a Graphical User Interface (GUI) journal October 1997
A short history of SHELX journal December 2007
Crystal structure refinement with SHELXL journal January 2015
SHELXT – Integrated space-group and crystal-structure determination journal January 2015
Accurate spin-dependent electron liquid correlation energies for local spin density calculations: a critical analysis journal August 1980
Optimization of Gaussian-type basis sets for local spin density functional calculations. Part I. Boron through neon, optimization technique and validation journal February 1992
Tetrazido-Nitrido-Molybdat(VI); Darstellung, IR-Spektrum und Kristallstruktur von AsPh4[MoN(N3)4] / Tetrazido-nitrido-molybdate(VI); Preparation, IR Spectrum and Crystal Structure of AsPh4[MoN(N3)4] journal September 1980
Inorganic and Transition Metal Azides journal April 2010

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