Current–Induced Ion Concentration Polarization at a Perfect Ion–Exchange Patch in an Infinite Insulating Wall

Bondarenko, Mykola P.; Bruening, Merlin L.; Yaroshchuk, Andriy E.

doi:10.1002/celc.201902068

Current–Induced Ion Concentration Polarization at a Perfect Ion–Exchange Patch in an Infinite Insulating Wall

Journal Article · Mon Mar 30 00:00:00 EDT 2020 · ChemElectroChem

DOI:https://doi.org/10.1002/celc.201902068· OSTI ID:1785977

Bondarenko, Mykola P. ^[1]; ^[2]; Yaroshchuk, Andriy E. ^[3]

National Academy of Sciences of Ukraine, Kyiv (Ukraine); University of Notre Dame
Univ. of Notre Dame, IN (United States)
ICREA, Barcelona (Spain); Polytechnic Univ. of Catalonia, Barcelona (Spain)

This research examines theoretically the ion concentration polarization, ion fluxes, and electrostatic fields near an ion exchange patch in the wall of an electrified fluidic channel. These phenomena are important in related microfluidic ion-preconcentration systems. Under an electric field, counterions enter the ion-exchange patch at one side and leave at the other, with salt depletion occurring near the entrance and accumulation near the exit. Furthermore, the high patch conductivity and the concentration profiles lead to local electric field perturbations that may facilitate preconcentration. This study includes analytical expressions of ion concentrations and electrochemical potentials at small to moderate electric fields, as well as numerical simulations. Additionally, a simple matrix of polynomial coefficients (obtained via fitting of numerical data) enables analytical calculation of the 2-dimensional concentration profiles at all electric fields within the range investigated in the numerical simulations. This is possible because a single dimensionless parameter controls this problem.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Notre Dame, IN (United States)

Sponsoring Organization:: Spanish Ministry of Economy and Competitiveness; USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: SC0017618

OSTI ID:: 1785977

Journal Information:: ChemElectroChem, Journal Name: ChemElectroChem Journal Issue: 6 Vol. 7; ISSN 2196-0216

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

References (27)

Highly Selective Current‐Induced Accumulation of Trace Ions at Micro‐/NanoPorous Interfaces Bondarenko, Mykola P.; Bruening, Merlin L.; Yaroshchuk, Andriy Advanced Theory and Simulations, Vol. 2, Issue 6 https://doi.org/10.1002/adts.201900009	journal	April 2019
Simultaneous isolation and preconcentration of exosomes by ion concentration polarization Marczak, Steven; Richards, Katherine; Ramshani, Zeinab ELECTROPHORESIS, Vol. 39, Issue 15 https://doi.org/10.1002/elps.201700491	journal	March 2018
Ion exchange membranes: New developments and applications Ran, Jin; Wu, Liang; He, Yubin Journal of Membrane Science, Vol. 522 https://doi.org/10.1016/j.memsci.2016.09.033	journal	January 2017
Specific co-ion sorption and diffusion properties influence membrane permselectivity Ji, Yuanyuan; Luo, Hongxi; Geise, Geoffrey M. Journal of Membrane Science, Vol. 563 https://doi.org/10.1016/j.memsci.2018.06.010	journal	October 2018
High-ionic-strength pre-concentration via ion concentration polarization for blood-based biofluids Han, Sung Il; Yoo, Yong Kyoung; Lee, Junwoo Sensors and Actuators B: Chemical, Vol. 268 https://doi.org/10.1016/j.snb.2018.04.144	journal	September 2018
Million-fold Preconcentration of Proteins and Peptides by Nanofluidic Filter Wang, Ying-Chih; Stevens, Anna L.; Han, Jongyoon Analytical Chemistry, Vol. 77, Issue 14 https://doi.org/10.1021/ac050321z	journal	July 2005
Bipolar Electrodes: A Useful Tool for Concentration, Separation, and Detection of Analytes in Microelectrochemical Systems Mavré, François; Anand, Robbyn K.; Laws, Derek R. Analytical Chemistry, Vol. 82, Issue 21 https://doi.org/10.1021/ac101262v	journal	November 2010
High Yield Sample Preconcentration Using a Highly Ion-Conductive Charge-Selective Polymer Chun, Honggu; Chung, Taek Dong; Ramsey, J. Michael Analytical Chemistry, Vol. 82, Issue 14 https://doi.org/10.1021/ac101297t	journal	July 2010
Microfluidic Protein Preconcentrator Using a Microchannel-Integrated Nafion Strip: Experiment and Modeling Shen, M.; Yang, H.; Sivagnanam, V. Analytical Chemistry, Vol. 82, Issue 24 https://doi.org/10.1021/ac102149f	journal	December 2010
Multiphysics Simulation of Ion Concentration Polarization Induced by Nanoporous Membranes in Dual Channel Devices Jia, Mingjie; Kim, Taesung Analytical Chemistry, Vol. 86, Issue 15 https://doi.org/10.1021/ac500536w	journal	July 2014
Bipolar Electrode Focusing: Simultaneous Concentration Enrichment and Separation in a Microfluidic Channel Containing a Bipolar Electrode Laws, Derek R.; Hlushkou, Dzmitry; Perdue, Robbyn K. Analytical Chemistry, Vol. 81, Issue 21, p. 8923-8929 https://doi.org/10.1021/ac901545y	journal	November 2009
Bipolar Electrode Focusing: The Effect of Current and Electric Field on Concentration Enrichment Perdue, Robbyn K.; Laws, Derek R.; Hlushkou, Dzmitry Analytical Chemistry, Vol. 81, Issue 24, p. 10149-10155 https://doi.org/10.1021/ac901913r	journal	December 2009
A Limiting Case of Constant Counterion Electrochemical Potentials in the Membrane for Examining Ion Transfer at Ion-Exchange Membranes and Patches Yaroshchuk, Andriy; Bondarenko, Mykola; Tang, Chao Langmuir, Vol. 35, Issue 40 https://doi.org/10.1021/acs.langmuir.9b02456	journal	September 2019
Electrochemical Sensing in Microfluidic Systems Using Electrogenerated Chemiluminescence as a Photonic Reporter of Redox Reactions Zhan, Wei; Alvarez, Julio; Crooks, Richard M. Journal of the American Chemical Society, Vol. 124, Issue 44 https://doi.org/10.1021/ja020907s	journal	November 2002
Electrokinetic Trapping and Concentration Enrichment of DNA in a Microfluidic Channel Dai, Jinhua; Ito, Takashi; Sun, Li Journal of the American Chemical Society, Vol. 125, Issue 43 https://doi.org/10.1021/ja0374776	journal	October 2003
Pressure-Driven Bipolar Electrochemistry Dumitrescu, Ioana; Anand, Robbyn K.; Fosdick, Stephen E. Journal of the American Chemical Society, Vol. 133, Issue 13 https://doi.org/10.1021/ja111050h	journal	April 2011
Electrokinetics in Microfluidic Channels Containing a Floating Electrode Dhopeshwarkar, Rahul; Hlushkou, Dzmitry; Nguyen, Mark Journal of the American Chemical Society, Vol. 130, Issue 32, p. 10480-10481 https://doi.org/10.1021/ja8036405	journal	August 2008
Sample pre-concentration with high enrichment factors at a fixed location in paper-based microfluidic devices Yeh, Shih-Hao; Chou, Kuang-Hua; Yang, Ruey-Jen Lab on a Chip, Vol. 16, Issue 5 https://doi.org/10.1039/C5LC01365H	journal	January 2016
Deciphering ion concentration polarization-based electrokinetic molecular concentration at the micro-nanofluidic interface: theoretical limits and scaling laws Ouyang, Wei; Ye, Xinghui; Li, Zirui Nanoscale, Vol. 10, Issue 32 https://doi.org/10.1039/C8NR02170H	journal	January 2018
Electric field gradient focusing in microchannels with embedded bipolar electrode Hlushkou, Dzmitry; Perdue, Robbyn K.; Dhopeshwarkar, Rahul Lab on a Chip, Vol. 9, Issue 13 https://doi.org/10.1039/b822404h	journal	January 2009
Theory and experiments of concentration polarization and ion focusing at microchannel and nanochannel interfaces Zangle, Thomas A.; Mani, Ali; Santiago, Juan G. Chemical Society Reviews, Vol. 39, Issue 3 https://doi.org/10.1039/b902074h	journal	January 2010
Nanofluidic preconcentration device in a straight microchannel using ion concentration polarization Ko, Sung Hee; Song, Yong-Ak; Kim, Sung Jae Lab on a Chip, Vol. 12, Issue 21 https://doi.org/10.1039/c2lc21238b	journal	January 2012
Ion concentration polarization on paper-based microfluidic devices and its application to preconcentrate dilute sample solutions Yang, Ruey-Jen; Pu, Hao-Hsuan; Wang, Hsiang-Li Biomicrofluidics, Vol. 9, Issue 1 https://doi.org/10.1063/1.4913366	journal	January 2015
Effect of concentration polarization on permselectivity abu-Rjal, Ramadan; Chinaryan, Vahe; Bazant, Martin Z. Physical Review E, Vol. 89, Issue 1 https://doi.org/10.1103/PhysRevE.89.012302	journal	January 2014
Effect of advection on transient ion concentration-polarization phenomenon Rosentsvit, Leon; Park, Sinwook; Yossifon, Gilad Physical Review E, Vol. 96, Issue 2 https://doi.org/10.1103/PhysRevE.96.023104	journal	August 2017
Microfluidic Systems with Ion-Selective Membranes Slouka, Zdenek; Senapati, Satyajyoti; Chang, Hsueh-Chia Annual Review of Analytical Chemistry, Vol. 7, Issue 1 https://doi.org/10.1146/annurev-anchem-071213-020155	journal	June 2014
Understanding methods of preparation and characterization of pore-filling polymer composites for proton exchange membranes: a beginner’s guide Gloukhovski, Robert; Freger, Viatcheslav; Tsur, Yoed Reviews in Chemical Engineering, Vol. 34, Issue 4 https://doi.org/10.1515/revce-2016-0065	journal	September 2017

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Current–Induced Ion Concentration Polarization at a Perfect Ion–Exchange Patch in an Infinite Insulating Wall

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