Photocatalytic CO2 reduction using visible light by metal-monocatecholato species in a metal–organic framework

Lee, Yeob; Kim, Sangjun; Fei, Honghan; Kang, Jeung Ku; Cohen, Seth M.

doi:10.1039/c5cc04506a

Photocatalytic CO₂ reduction using visible light by metal-monocatecholato species in a metal–organic framework

Journal Article · Thu Jan 01 00:00:00 EST 2015 · ChemComm

DOI:https://doi.org/10.1039/c5cc04506a· OSTI ID:1781414

Lee, Yeob ^[1]; Kim, Sangjun ^[2]; Fei, Honghan ^[3]; Kang, Jeung Ku ^[2]; Cohen, Seth M. ^[3]

Univ. of California, San Diego, CA (United States); U.C. San Diego
Korea Advanced Inst. Science and Technology (KAIST), Daejeon (Korea, Republic of)
Univ. of California, San Diego, CA (United States)

Metal–organic frameworks (MOFs) with isolated metal-monocatecholato groups have been synthesized via postsynthetic exchange (PSE) for CO₂ reduction photocatalyst under visible light irradiation in the presence of 1-benzyl-1,4-dihydronicotinamide and triethanolamine. The Cr-monocatecholato species are more efficient than the Ga-monocatecholato species

View Accepted Manuscript (DOE)

Research Organization:: Univ. of California, San Diego, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: FG02-08ER46519

OSTI ID:: 1781414

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 92 Vol. 51; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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