Photocatalytic metal–organic frameworks for organic transformations

Yu, Xiao; Wang, Le; Cohen, Seth M.

doi:10.1039/c7ce00398f

Photocatalytic metal–organic frameworks for organic transformations

Journal Article · Wed Apr 12 00:00:00 EDT 2017 · CrystEngComm

DOI:https://doi.org/10.1039/c7ce00398f· OSTI ID:1780608

Yu, Xiao ^[1]; Wang, Le ^[2]; ^[2]

Univ. of California, San Diego, La Jolla, CA (United States); U.C. San Diego
Univ. of California, San Diego, La Jolla, CA (United States)

Metal–organic frameworks (MOFs) have attracted increasing attention for applications in heterogeneous photocatalysis. Here, modifications of metal nodes and organic linkers, as well as encapsulation of active species in the pores of MOFs enable the generation of photoactive materials for catalyzing organic transformations. MOF composites integrating noble metal nanoparticles or traditional photoactive semiconductors can combine the advantages of both materials, and also improve the photocatalytic performance via synergistic effects. In this Highlight, we discuss recent examples of photoactive MOFs and their use as photocatalysts for organic reactions.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of California, San Diego, La Jolla, CA (United States)

Sponsoring Organization:: National Science Foundation; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: FG02-08ER46519

OSTI ID:: 1780608

Alternate ID(s):: OSTI ID: 1535184

Journal Information:: CrystEngComm, Journal Name: CrystEngComm Journal Issue: 29 Vol. 19; ISSN 1466-8033

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Metal-Organic Frameworks Encapsulating Active Nanoparticles as Emerging Composites for Catalysis: Recent Progress and Perspectives Li, Guodong; Zhao, Shenlong; Zhang, Yin Advanced Materials, Vol. 30, Issue 51 https://doi.org/10.1002/adma.201800702	journal	September 2018
Visible-Light-Responsive 2D Cadmium-Organic Framework Single Crystals with Dual Functions of Water Reduction and Oxidation Xiao, Yejun; Qi, Yu; Wang, Xiuli Advanced Materials, Vol. 30, Issue 44 https://doi.org/10.1002/adma.201803401	journal	September 2018
Metal-organic frameworks for CO2 photoreduction Zhang, Lei; Zhang, Junqing Frontiers in Energy, Vol. 13, Issue 2 https://doi.org/10.1007/s11708-019-0629-8	journal	May 2019
Tailoring exciton and excimer emission in an exfoliated ultrathin 2D metal-organic framework Liao, Wei-Ming; Zhang, Jian-Hua; Yin, Shao-Yun Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04833-1	journal	June 2018
Photochemistry and photophysics of MOFs: steps towards MOF-based sensing enhancements Dolgopolova, Ekaterina A.; Rice, Allison M.; Martin, Corey R. Chemical Society Reviews, Vol. 47, Issue 13 https://doi.org/10.1039/c7cs00861a	journal	January 2018
Metal–organic frameworks (MOFs) for photocatalytic CO ₂ reduction Chen, Yi; Wang, Dengke; Deng, Xiaoyu Catal. Sci. Technol., Vol. 7, Issue 21 https://doi.org/10.1039/c7cy01653k	journal	January 2017
Effects of electron-donating groups on the photocatalytic reaction of MOFs Li, Shixiong; Sun, Shengli; Wu, Haizhen Catalysis Science & Technology, Vol. 8, Issue 6 https://doi.org/10.1039/c7cy02622f	journal	January 2018
A multi-dye@MOF composite boosts highly efficient photodegradation of an ultra-stubborn dye reactive blue 21 under visible-light irradiation Li, Qing; Fan, Zeng-Lu; Xue, Dong-Xu Journal of Materials Chemistry A, Vol. 6, Issue 5 https://doi.org/10.1039/c7ta10184h	journal	January 2018
Enhancement of photoredox catalytic properties of porphyrinic metal–organic frameworks based on titanium incorporation via post-synthetic modification He, Junhui; Zhang, Yajun; He, Juan Chemical Communications, Vol. 54, Issue 62 https://doi.org/10.1039/c8cc04891f	journal	January 2018
Catalysis and photocatalysis by metal organic frameworks Dhakshinamoorthy, Amarajothi; Li, Zhaohui; Garcia, Hermenegildo Chemical Society Reviews, Vol. 47, Issue 22 https://doi.org/10.1039/c8cs00256h	journal	January 2018
Photocatalytic hydrogenation of nitroarenes: supporting effect of CoO _x on TiO ₂ nanoparticles Amanchi, Srinivasa Rao; Ashok Kumar, K. V.; Lakshminarayana, Bhairi New Journal of Chemistry, Vol. 43, Issue 2 https://doi.org/10.1039/c8nj05260c	journal	January 2019
Multicomponent metal–organic framework membranes for advanced functional composites Denny, Michael S.; Kalaj, Mark; Bentz, Kyle C. Chemical Science, Vol. 9, Issue 47 https://doi.org/10.1039/c8sc02356e	journal	January 2018
The fabrication of Au/Pd plasmonic alloys on UiO-66-NH ₂ : an efficient visible light-induced photocatalyst towards the Suzuki Miyaura coupling reaction under ambient conditions Subudhi, Satyabrata; Mansingh, Sriram; Tripathy, Suraj Prakash Catalysis Science & Technology, Vol. 9, Issue 23 https://doi.org/10.1039/c9cy01431d	journal	January 2019
Recent advances in MOF-based photocatalysis: environmental remediation under visible light Wang, Qi; Gao, Qiaoyuan; Al-Enizi, Abdullah M. Inorganic Chemistry Frontiers, Vol. 7, Issue 2 https://doi.org/10.1039/c9qi01120j	journal	January 2020
Visible-light-driven self-coupling and oxidative dehydrogenation of amines to imines via a Mn( ii )-based coordination polymer Liu, Hui; Guo, Zhifen; Lv, Hui Inorganic Chemistry Frontiers, Vol. 7, Issue 4 https://doi.org/10.1039/c9qi01396b	journal	January 2020
Metal–organic frameworks: preparation and applications in highly efficient heterogeneous photocatalysis Huang, Chao-Wei; Nguyen, Van-Huy; Zhou, Shi-Rong Sustainable Energy & Fuels, Vol. 4, Issue 2 https://doi.org/10.1039/c9se00972h	journal	January 2020
A porous zinc(II) metal–organic framework exhibiting high sensing ability for ferric and nitroaromatics as well as photocatalytic degradation activities against organic dyes Liu, Jianqiang; Wu, Jian; Luo, Zhidong Journal of Coordination Chemistry, Vol. 70, Issue 23 https://doi.org/10.1080/00958972.2017.1414202	journal	December 2017
Construction of a three-dimensional supramolecular framework based on an anionic cadmium(II) coordination network and protonated dipyridine organic cations Zhou, Qian-Kun; Wang, Lin; Liu, Dong Acta Crystallographica Section C Structural Chemistry, Vol. 74, Issue 8 https://doi.org/10.1107/s2053229618009233	journal	July 2018
Substituent effects of two isophthalate derivatives on the construction of cadmium coordination polymers incorporating a dipyridyl ligand Wang, Lin; Zhou, Qian-Kun; Xu, Yun Acta Crystallographica Section C Structural Chemistry, Vol. 74, Issue 8 https://doi.org/10.1107/s2053229618009312	journal	July 2018
Synthesis, structure and photoluminescence properties of a three-dimensional cadmium(II) (4,5)-connected coordination network Li, Ni-Ya; Liu, Dong Acta Crystallographica Section C Structural Chemistry, Vol. 74, Issue 12 https://doi.org/10.1107/s2053229618015073	journal	November 2018
A new three-dimensional cobalt(II) coordination polymer based on V-shaped 3,4′-oxydibenzoate: synthesis, crystal structure and magnetic properties Lan, Wenlong; Zhou, Zhen; Jia, Fu-Chao Acta Crystallographica Section C Structural Chemistry, Vol. 75, Issue 7 https://doi.org/10.1107/s2053229619008337	journal	June 2019
A porous zinc(II) metal–organic framework exhibiting high sensing ability for ferric and nitroaromatics as well as photocatalytic degradation activities against organic dyes Liu, Jianqiang; Wu, Jian; Luo, Zhidong Taylor & Francis https://doi.org/10.6084/m9.figshare.5677864	text	January 2017
A porous zinc(II) metal–organic framework exhibiting high sensing ability for ferric and nitroaromatics as well as photocatalytic degradation activities against organic dyes Liu, Jianqiang; Wu, Jian; Luo, Zhidong Taylor & Francis https://doi.org/10.6084/m9.figshare.5677864.v1	text	January 2017

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