Photocatalytic CO2 reduction by a mixed metal (Zr/Ti), mixed ligand metal–organic framework under visible light irradiation

Lee, Yeob; Kim, Sangjun; Kang, Jeung Ku; Cohen, Seth M.

doi:10.1039/c5cc00686d

Photocatalytic CO₂ reduction by a mixed metal (Zr/Ti), mixed ligand metal–organic framework under visible light irradiation

Journal Article · Wed Feb 18 00:00:00 EST 2015 · ChemComm

DOI:https://doi.org/10.1039/c5cc00686d· OSTI ID:1781413

Lee, Yeob ^[1]; Kim, Sangjun ^[2]; Kang, Jeung Ku ^[2]; Cohen, Seth M. ^[3]

Univ. of California, San Diego, CA (United States); U.C. San Diego
Korea Advanced Inst. Science and Technology (KAIST), Daejeon (Korea, Republic of)
Univ. of California, San Diego, CA (United States)

Postsynthetic exchange (PSE) of Ti(IV) into a Zr(IV)-based MOF enabled photocatalytic CO₂ reduction to HCOOH under visible light irradiation with the aid of BNAH and TEOA. Use of a mixedligand strategy enhanced the photocatalytic activity of the MOF by introducing new energy levels in the band structure of the MOF.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of California, San Diego, CA (United States)

Sponsoring Organization:: National Research Foundation of Korea; USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division

Grant/Contract Number:: FG02-08ER46519

OSTI ID:: 1781413

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 26 Vol. 51; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Metal ion exchange in Prussian blue analogues: Cu( ii )-exchanged Zn–Co PBAs as highly selective catalysts for A ³ coupling Marquez, Carlos; Cirujano, Francisco G.; Smolders, Simon Dalton Transactions, Vol. 48, Issue 12 https://doi.org/10.1039/c9dt00388f	journal	January 2019
Different functional group modified zirconium frameworks for the photocatalytic reduction of carbon dioxide Wei, Yuan-Ping; Liu, Yi; Guo, Fan Dalton Transactions, Vol. 48, Issue 23 https://doi.org/10.1039/c9dt01767d	journal	January 2019
Recent development of covalent organic frameworks (COFs): synthesis and catalytic (organic-electro-photo) applications Sharma, Rakesh Kumar; Yadav, Priya; Yadav, Manavi Materials Horizons, Vol. 7, Issue 2 https://doi.org/10.1039/c9mh00856j	journal	January 2020
Recent advances in MOF-based photocatalysis: environmental remediation under visible light Wang, Qi; Gao, Qiaoyuan; Al-Enizi, Abdullah M. Inorganic Chemistry Frontiers, Vol. 7, Issue 2 https://doi.org/10.1039/c9qi01120j	journal	January 2020
CdSe/ZIF-8- x : synthesis and photocatalytic CO ₂ reduction performance Peng, Hui-Juan; Zheng, Pei-Qin; Chao, Hsiu-Yi RSC Advances, Vol. 10, Issue 1 https://doi.org/10.1039/c9ra08801f	journal	January 2020
Layered Zn ₂ [Co(CN) ₆ ](CH ₃ COO) double metal cyanide: a two-dimensional DMC phase with excellent catalytic performance Marquez, Carlos; Simonov, Arkadiy; Wharmby, Michael T. Chemical Science, Vol. 10, Issue 18 https://doi.org/10.1039/c9sc00527g	journal	January 2019
An exceptionally stable octacobalt-cluster-based metal–organic framework for enhanced water oxidation catalysis Huang, Ning-Yu; Shen, Jian-Qiang; Ye, Zi-Ming Chemical Science, Vol. 10, Issue 42 https://doi.org/10.1039/c9sc03224j	journal	January 2019
An insight into the effect of azobenzene functionalities studied in UiO-66 frameworks for low energy CO ₂ capture and CO ₂ /N ₂ membrane separation Prasetya, Nicholaus; Ladewig, Bradley P. Journal of Materials Chemistry A, Vol. 7, Issue 25 https://doi.org/10.1039/c9ta02096a	journal	January 2019
A novel BODIPY-based MOF photocatalyst for efficient visible-light-driven hydrogen evolution Yang, Heng; Wang, Jinming; Ma, Ji Journal of Materials Chemistry A, Vol. 7, Issue 17 https://doi.org/10.1039/c9ta02357g	journal	January 2019
A noble-metal-free photocatalyst system obtained using BODIPY-based MOFs for highly efficient visible-light-driven H ₂ evolution Yang, Heng; Zhao, Ming; Zhang, Jing Journal of Materials Chemistry A, Vol. 7, Issue 36 https://doi.org/10.1039/c9ta06989e	journal	January 2019
A microporous mixed-metal (Na/Cu) mixed-ligand (flexible/rigid) metal–organic framework for photocatalytic H ₂ generation Shi, Dongying; Cui, Chao-Jie; Hu, Min Journal of Materials Chemistry C, Vol. 7, Issue 33 https://doi.org/10.1039/c9tc03342d	journal	January 2019
Metal doping in cerium metal-organic frameworks for visible-response water splitting photocatalysts Gagliardi, Laura; Truhlar, Donald G. The Journal of Chemical Physics, Vol. 150, Issue 4 https://doi.org/10.1063/1.5043538	journal	January 2019
Recent progress in the synthesis of metal–organic frameworks Sun, Yujia; Zhou, Hong-Cai Science and Technology of Advanced Materials, Vol. 16, Issue 5 https://doi.org/10.1088/1468-6996/16/5/054202	journal	October 2015
Functionalization of a Metal-Organic Framework Semiconductor for Tuned Band Structure and Catalytic Activity Li, Jiangtian; Musho, Terence; Bright, Joeseph Journal of The Electrochemical Society, Vol. 166, Issue 5 https://doi.org/10.1149/2.0051905jes	journal	December 2018

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