Metal Oxide Sorbents for the Separation of Radium and Actinium
Abstract
The inorganic, normal-phase sorbents alumina, titania, and zirconia were evaluated and screened for the separation of Ba, La, 228Ra, 228Ac, and 212Pb in a dilute acid matrix. The results show that the sorbents are capable of fractionating the ions between pH 1 and 8. A stationary zirconia column was used to isolate Ba from La and Ra from Ac/Pb; elution profiles of each separation are presented. The utility and implications of these sorbents are discussed with respect to large-scale production of 225Ac from radium targets.
- Authors:
-
- Argonne National Lab. (ANL), Lemont, IL (United States)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Nuclear Physics (NP)
- OSTI Identifier:
- 1774592
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- Industrial and Engineering Chemistry Research
- Additional Journal Information:
- Journal Volume: 59; Journal Issue: 46; Journal ID: ISSN 0888-5885
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; oxides; sorbents; organic polymers; ions; organic compounds
Citation Formats
Brown, M. Alex. Metal Oxide Sorbents for the Separation of Radium and Actinium. United States: N. p., 2020.
Web. doi:10.1021/acs.iecr.0c04084.
Brown, M. Alex. Metal Oxide Sorbents for the Separation of Radium and Actinium. United States. https://doi.org/10.1021/acs.iecr.0c04084
Brown, M. Alex. 2020.
"Metal Oxide Sorbents for the Separation of Radium and Actinium". United States. https://doi.org/10.1021/acs.iecr.0c04084. https://www.osti.gov/servlets/purl/1774592.
@article{osti_1774592,
title = {Metal Oxide Sorbents for the Separation of Radium and Actinium},
author = {Brown, M. Alex},
abstractNote = {The inorganic, normal-phase sorbents alumina, titania, and zirconia were evaluated and screened for the separation of Ba, La, 228Ra, 228Ac, and 212Pb in a dilute acid matrix. The results show that the sorbents are capable of fractionating the ions between pH 1 and 8. A stationary zirconia column was used to isolate Ba from La and Ra from Ac/Pb; elution profiles of each separation are presented. The utility and implications of these sorbents are discussed with respect to large-scale production of 225Ac from radium targets.},
doi = {10.1021/acs.iecr.0c04084},
url = {https://www.osti.gov/biblio/1774592},
journal = {Industrial and Engineering Chemistry Research},
issn = {0888-5885},
number = 46,
volume = 59,
place = {United States},
year = {Tue Nov 03 00:00:00 EST 2020},
month = {Tue Nov 03 00:00:00 EST 2020}
}
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