Polycation ionic liquid tailored PEO-based solid polymer electrolytes for high temperature lithium metal batteries

Tan, Jiewen; Ao, Xin; Dai, Alvin; Yuan, Yifei; Zhuo, Hao; Lu, Hao; Zhuang, Libin; Ke, Yuxuan; Su, Chenliang; Peng, Xinwen; Tian, Bingbing; Lu, Jun

doi:10.1016/j.ensm.2020.08.009

Title: Polycation ionic liquid tailored PEO-based solid polymer electrolytes for high temperature lithium metal batteries

Journal Article · Sat Aug 29 00:00:00 EDT 2020 · Energy Storage Materials

DOI:https://doi.org/10.1016/j.ensm.2020.08.009· OSTI ID:1774582

Tan, Jiewen ^[1]; Ao, Xin ^[2]; Dai, Alvin ^[3]; Yuan, Yifei ^[3]; Zhuo, Hao ^[4]; Lu, Hao ^[4]; Zhuang, Libin ^[2]; Ke, Yuxuan ^[2]; Su, Chenliang ^[2]; Peng, Xinwen ^[4]; Tian, Bingbing ^[2]; Lu, Jun ^[3]

South China Univ. of Technology (SCUT), Guangzhou (China); Shenzhen University (China)
Shenzhen University (China)
Argonne National Lab. (ANL), Argonne, IL (United States)
South China Univ. of Technology (SCUT), Guangzhou (China)

Poly(ethylene oxide) (PEO)-based polymer electrolytes are promising candidates for solid-state electrolytes in safer, next generation lithium metal batteries. Despite their benefits however, PEO-based electrolyte exhibits highly crystalline ethylene oxide chains that provide poor ionic conductivity and, thus severely limit its practical application. Here, we report the use of hydroxypropyl trimethylammonium bis(trifluoromethane) sulfonimide chitosan salt (HACC-TFSI), which is an amorphous poly(ionic liquid) based biomass chitosan derivative, as a modifier for PEO-based solid polymer electrolytes (SPEs) to address these deficiencies. Hybrid SPEs with HACC-TFSI display enlarged amorphous regions with enhanced ionic conductivity. Interactions between quaternary ammonium cations and TFSI-anions in hybrid SPEs are also found to promote dissociation between Li⁺ and TFSI^-, which further increases ionic mobility. Moreover, the electrochemical stability, mechanical strength, and thermal stability of hybrid SPEs are collectively superior to blank SPEs without HACC-TFSI. LiFePO₄/SPEs/Li full-cells assembled using 10wt% HACC-TFSI in PEO (10%HACC-TFSI/SPEs) electrolyte provide a capacity of 161.3 mAh g^-1 and operate with excellent cycle performances at 0.2 C and 60 C. Finally, even when the temperature is increased to 150 C, LiFePO₄/SPEs/Li cells with 10%HACC-TFSI/SPEs still display remarkable cycle performance with 73% capacity retention after 100 cycles at 1 C rate.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office; National Natural Science Foundation of China (NSFC)

Grant/Contract Number:: AC02-06CH11357; 2019A151501675; 2017A030313130; JCYJ20180305125106329; ZDSYS201707271014468; 827-000273; KQJSCX20180328094001794; KQTD2016053112042971; 2016A030306027; 201904010078; 2019T120725; 2019M652882; 2020C03

OSTI ID:: 1774582

Journal Information:: Energy Storage Materials, Vol. 33; ISSN 2405-8297

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (42)

High-Strength Internal Cross-Linking Bacterial Cellulose-Network-Based Gel Polymer Electrolyte for Dendrite-Suppressing and High-Rate Lithium Batteries Xu, Dong; Wang, Bangrun; Wang, Qing ACS Applied Materials & Interfaces, Vol. 10, Issue 21 https://doi.org/10.1021/acsami.8b00034	journal	May 2018
Self-healing electrostatic shield enabling uniform lithium deposition in all-solid-state lithium batteries Yang, Xiaofei; Sun, Qian; Zhao, Changtai Energy Storage Materials, Vol. 22 https://doi.org/10.1016/j.ensm.2019.07.015	journal	November 2019
A novel polymer electrolyte with improved high-temperature-tolerance up to 170 °C for high-temperature lithium-ion batteries Li, Yan-Hua; Wu, Xing-Long; Kim, Jee-Hoon Journal of Power Sources, Vol. 244 https://doi.org/10.1016/j.jpowsour.2013.01.148	journal	December 2013
Microporous polymer electrolyte based on PVDF/PEO star polymer blends for lithium ion batteries Deng, Fangli; Wang, Xiaoen; He, Dan Journal of Membrane Science, Vol. 491 https://doi.org/10.1016/j.memsci.2015.05.021	journal	October 2015
Nanoporous Adsorption Effect on Alteration of the Li ⁺ Diffusion Pathway by a Highly Ordered Porous Electrolyte Additive for High-Rate All-Solid-State Lithium Metal Batteries Li, Wenwen; Zhang, Sanpei; Wang, Bangrun ACS Applied Materials & Interfaces, Vol. 10, Issue 28 https://doi.org/10.1021/acsami.8b06574	journal	June 2018
New Single Ion Conducting Blend Based on PEO and PA-LiTFSI Piszcz, Michał; Garcia-Calvo, Oihane; Oteo, Uxue Electrochimica Acta, Vol. 255 https://doi.org/10.1016/j.electacta.2017.09.139	journal	November 2017
Lithium solvation and diffusion in the 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide ionic liquid Duluard, Sandrine; Grondin, Joseph; Bruneel, Jean-Luc Journal of Raman Spectroscopy, Vol. 39, Issue 5 https://doi.org/10.1002/jrs.1896	journal	January 2008
Gel polymer electrolytes for lithium ion batteries: Fabrication, characterization and performance Liang, Shishuo; Yan, Wenqi; Wu, Xu Solid State Ionics, Vol. 318 https://doi.org/10.1016/j.ssi.2017.12.023	journal	May 2018
Recent advances in solid polymer electrolytes for lithium batteries Zhang, Qingqing; Liu, Kai; Ding, Fei Nano Research, Vol. 10, Issue 12 https://doi.org/10.1007/s12274-017-1763-4	journal	August 2017
Poly(ethylene oxide)-based electrolytes for lithium-ion batteries Xue, Zhigang; He, Dan; Xie, Xiaolin Journal of Materials Chemistry A, Vol. 3, Issue 38 https://doi.org/10.1039/C5TA03471J	journal	January 2015
Anion exchanged polymerized ionic liquids: High free volume single ion conductors Ye, Yuesheng; Elabd, Yossef A. Polymer, Vol. 52, Issue 5 https://doi.org/10.1016/j.polymer.2011.01.031	journal	March 2011
Solid-State Li-Ion Batteries Using Fast, Stable, Glassy Nanocomposite Electrolytes for Good Safety and Long Cycle-Life Tan, Guoqiang; Wu, Feng; Zhan, Chun Nano Letters, Vol. 16, Issue 3 https://doi.org/10.1021/acs.nanolett.5b05234	journal	February 2016
Facile preparation of polymer electrolytes based on the polymerized ionic liquid poly((4-vinylbenzyl)trimethylammonium bis(trifluoromethanesulfonylimide)) for lithium secondary batteries Li, Mingtao; Wang, Lu; Yang, Bolun Electrochimica Acta, Vol. 123 https://doi.org/10.1016/j.electacta.2013.12.179	journal	March 2014
Single ion solid-state composite electrolytes with high electrochemical stability based on a poly(perfluoroalkylsulfonyl)-imide ionene polymer Shi, Qianru; Xue, Lixin; Qin, Dejun J. Mater. Chem. A, Vol. 2, Issue 38 https://doi.org/10.1039/C4TA02810D	journal	January 2014
Biomimetic ant-nest ionogel electrolyte boosts the performance of dendrite-free lithium batteries Chen, Nan; Dai, Yujuan; Xing, Yi Energy & Environmental Science, Vol. 10, Issue 7 https://doi.org/10.1039/C7EE00988G	journal	January 2017
Preparation and characterization of PEO-PMMA polymer composite electrolytes doped with nano-Al2O3 Liang, Bo; Tang, Siqi; Jiang, Qingbai Electrochimica Acta, Vol. 169 https://doi.org/10.1016/j.electacta.2015.04.039	journal	July 2015
A solid-state single-ion polymer electrolyte with ultrahigh ionic conductivity for dendrite-free lithium metal batteries Cao, Chen; Li, Yu; Feng, Yiyu Energy Storage Materials, Vol. 19 https://doi.org/10.1016/j.ensm.2019.03.004	journal	May 2019
Mastering the interface for advanced all-solid-state lithium rechargeable batteries Li, Yutao; Zhou, Weidong; Chen, Xi Proceedings of the National Academy of Sciences, Vol. 113, Issue 47 https://doi.org/10.1073/pnas.1615912113	journal	November 2016
Development of a novel type of solid polymer electrolyte for solid state lithium battery applications based on lithium enriched poly (ethylene oxide) (PEO)/poly (vinyl pyrrolidone) (PVP) blend polymer B., Jinisha; Km, Anilkumar; M., Manoj Electrochimica Acta, Vol. 235 https://doi.org/10.1016/j.electacta.2017.03.118	journal	May 2017
Cycling profile of innovative nanochitin-incorporated poly (ethylene oxide) based electrolytes for lithium batteries Angulakhsmi, N.; Thomas, S.; Nair, Jijeesh R. Journal of Power Sources, Vol. 228 https://doi.org/10.1016/j.jpowsour.2012.11.007	journal	April 2013
Understanding materials challenges for rechargeable ion batteries with in situ transmission electron microscopy Yuan, Yifei; Amine, Khalil; Lu, Jun Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15806	journal	August 2017
Influence of TiO2 nano-particles on the transport properties of composite polymer electrolyte for lithium-ion batteries Lin, C. W.; Hung, C. L.; Venkateswarlu, M. Journal of Power Sources, Vol. 146, Issue 1-2 https://doi.org/10.1016/j.jpowsour.2005.03.028	journal	August 2005
Polymeric ionic liquids for lithium-based rechargeable batteries Eshetu, Gebrekidan Gebresilassie; Mecerreyes, David; Forsyth, Maria Molecular Systems Design & Engineering, Vol. 4, Issue 2 https://doi.org/10.1039/C8ME00103K	journal	January 2019
Single-ion BAB triblock copolymers as highly efficient electrolytes for lithium-metal batteries Bouchet, Renaud; Maria, Sébastien; Meziane, Rachid Nature Materials, Vol. 12, Issue 5 https://doi.org/10.1038/nmat3602	journal	March 2013
2D MXene-containing polymer electrolytes for all-solid-state lithium metal batteries Pan, Qiwei; Zheng, Yongwei; Kota, Sankalp Nanoscale Advances, Vol. 1, Issue 1 https://doi.org/10.1039/C8NA00206A	journal	January 2019
FTIR characterization of PEO + LiN(CF3SO2)2 electrolytes Wen, S. J.; Richardson, T. J.; Ghantous, D. I. Journal of Electroanalytical Chemistry, Vol. 408, Issue 1-2 https://doi.org/10.1016/0022-0728(96)04536-6	journal	May 1996
Fabrication and Characterization of Electrospun Chitosan Nanofibers Formed via Templating with Polyethylene Oxide Ojha, Satyajeet S.; Stevens, Derrick R.; Hoffman, Torissa J. Biomacromolecules, Vol. 9, Issue 9 https://doi.org/10.1021/bm800551q	journal	September 2008
Flexible and ion-conducting membrane electrolytes for solid-state lithium batteries: Dispersion of garnet nanoparticles in insulating polyethylene oxide Zhang, Jingxian; Zhao, Ning; Zhang, Miao Nano Energy, Vol. 28 https://doi.org/10.1016/j.nanoen.2016.09.002	journal	October 2016
Cationic Covalent Organic Framework Nanosheets for Fast Li-Ion Conduction Chen, Hongwei; Tu, Hangyu; Hu, Chenji Journal of the American Chemical Society, Vol. 140, Issue 3 https://doi.org/10.1021/jacs.7b12292	journal	January 2018
PEO based polymer electrolyte comprised of epoxidized natural rubber material (ENR50) for Li-Ion polymer battery application Lee, Tian Khoon; Zaini, Nur Farahidayu Mohd; Mobarak, Nadharatun Naiim Electrochimica Acta, Vol. 316 https://doi.org/10.1016/j.electacta.2019.05.143	journal	September 2019
An inorganic membrane as a separator for lithium-ion battery Xiang, Hongfa; Chen, Jingjuan; Li, Zhong Journal of Power Sources, Vol. 196, Issue 20 https://doi.org/10.1016/j.jpowsour.2011.06.055	journal	October 2011
Lithium-doped plastic crystal electrolytes exhibiting fast ion conduction for secondary batteries MacFarlane, Douglas R.; Huang, Junhua; Forsyth, Maria Nature, Vol. 402, Issue 6763 https://doi.org/10.1038/45514	journal	December 1999
High Ionic Conductivity of Composite Solid Polymer Electrolyte via In Situ Synthesis of Monodispersed SiO ₂ Nanospheres in Poly(ethylene oxide) Lin, Dingchang; Liu, Wei; Liu, Yayuan Nano Letters, Vol. 16, Issue 1 https://doi.org/10.1021/acs.nanolett.5b04117	journal	December 2015
Status, promises, and challenges of nanocomposite solid-state electrolytes for safe and high performance lithium batteries Wan, J.; Xie, J.; Mackanic, D. G. Materials Today Nano, Vol. 4 https://doi.org/10.1016/j.mtnano.2018.12.003	journal	December 2018
Charge–discharge studies of all-solid-state Li/LiFePO ₄ cells with PEO-based composite electrolytes encompassing metal organic frameworks Suriyakumar, Shruti; Kanagaraj, M.; Angulakshmi, N. RSC Advances, Vol. 6, Issue 99 https://doi.org/10.1039/C6RA17962B	journal	January 2016
Magnetic Field–Suppressed Lithium Dendrite Growth for Stable Lithium‐Metal Batteries Shen, Kang; Wang, Zeng; Bi, Xuanxuan Advanced Energy Materials, Vol. 9, Issue 20 https://doi.org/10.1002/aenm.201900260	journal	April 2019
Thermal Behavior of Ionic Liquids Containing the FSI Anion and the Li ⁺ Cation Huang, Junhua; Hollenkamp, Anthony F. The Journal of Physical Chemistry C, Vol. 114, Issue 49 https://doi.org/10.1021/jp107740p	journal	November 2010
Progress in flexible lithium batteries and future prospects Zhou, Guangmin; Li, Feng; Cheng, Hui-Ming Energy Environ. Sci., Vol. 7, Issue 4 https://doi.org/10.1039/C3EE43182G	journal	January 2014
A promising TPU/PEO blend polymer electrolyte for all-solid-state lithium ion batteries Tao, Can; Gao, Ming-Hao; Yin, Bo-Hao Electrochimica Acta, Vol. 257 https://doi.org/10.1016/j.electacta.2017.10.037	journal	December 2017
Electrolytes for solid-state lithium rechargeable batteries: recent advances and perspectives Quartarone, Eliana; Mustarelli, Piercarlo Chemical Society Reviews, Vol. 40, Issue 5 https://doi.org/10.1039/c0cs00081g	journal	January 2011
Recent progress on solid-state hybrid electrolytes for solid-state lithium batteries Liang, Jianneng; Luo, Jing; Sun, Qian Energy Storage Materials, Vol. 21 https://doi.org/10.1016/j.ensm.2019.06.021	journal	September 2019
Lithiophilic 3D Porous CuZn Current Collector for Stable Lithium Metal Batteries Zhang, Duo; Dai, Alvin; Wu, Min ACS Energy Letters, Vol. 5, Issue 1 https://doi.org/10.1021/acsenergylett.9b01987	journal	October 2019

Similar Records

Hyperbranched PEO-Based Hyperstar Solid Polymer Electrolytes with Simultaneous Improvement of Ion Transport and Mechanical Strength

Journal Article · Tue Feb 26 00:00:00 EST 2019 · ACS Applied Energy Materials · OSTI ID:1774582

Chen, Yang; Shi, Yi; Liang, Yanliang; +6 more

High voltage stable cycling of all-solid-state lithium metal batteries enabled by top-down direct fluorinated poly (ethylene oxide)-based electrolytes

Journal Article · Wed Dec 21 00:00:00 EST 2022 · Journal of Power Sources · OSTI ID:1774582

Yan, Hao; Wang, Tong; Liu, Lujuan; +6 more

Li ₂ S ₆ ‐Integrated PEO‐Based Polymer Electrolytes for All‐Solid‐State Lithium‐Metal Batteries

Journal Article · Wed Jun 30 00:00:00 EDT 2021 · Angewandte Chemie (International Edition) · OSTI ID:1774582

Fang, Ruyi; Xu, Biyi; Grundish, Nicholas S.; +6 more

Related Subjects

25 ENERGY STORAGE
chitosan
ionic conductivities
lithium metal batteries
poly(ionic liquid)
solid polymer electrolytes

Title: Polycation ionic liquid tailored PEO-based solid polymer electrolytes for high temperature lithium metal batteries

Citation Formats

References (42)

Similar Records

Related Subjects