Counterrotating magnetic order in the honeycomb layers of NaNi2BiO6-δ

Scheie, A.; Ross, K.; Stavropoulos, P. Peter; Seibel, E.; Rodriguez-Rivera, J. A.; Tang, J. A.; Li, Yi; Kee, Hae-Young; Cava, R. J.; Broholm, C.

doi:10.1103/PhysRevB.100.214421

Title: Counterrotating magnetic order in the honeycomb layers of ${NaNi}_{2} {BiO}_{6 - δ}$

Journal Article · Wed Dec 18 00:00:00 EST 2019 · Physical Review B

DOI:https://doi.org/10.1103/PhysRevB.100.214421· OSTI ID:1767739

^[1]; Ross, K. ^[2]; Stavropoulos, P. Peter ^[3]; Seibel, E. ^[4]; Rodriguez-Rivera, J. A. ^[5]; Tang, J. A. ^[1]; Li, Yi ^[1]; Kee, Hae-Young ^[6]; Cava, R. J. ^[4]; Broholm, C. ^[7]

Johns Hopkins Univ., Baltimore, MD (United States)
Colorado State Univ., Fort Collins, CO (United States); Canadian Inst. for Advanced Research (CIFAR), Toronto, ON (Canada)
Univ. of Toronto, ON (Canada)
Princeton Univ., NJ (United States)
National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States); Univ. of Maryland, College Park, MD (United States)
Univ. of Toronto, ON (Canada); Canadian Inst. for Advanced Research (CIFAR), Toronto, ON (Canada)
Johns Hopkins Univ., Baltimore, MD (United States); National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States); Johns Hopkins Univ., Baltimore, MD (United States)

In this paper we report the magnetic structure and electronic properties of the honeycomb antiferromagnet NaNi₂BiO_5.66. We find magnetic order with moments along the c axis for temperatures below $$T_{c1}$$ = 6.3(1)K and then in the honeycomb plane for $$T < T_{c2}$$ = 4.8(1) K with a counterrotating pattern and an ordering wave vector q = (1/3, 1/3, 0.15(1)). Density functional theory and electron spin resonance indicate this is high-spin Ni³⁺ magnetism near a high to low spin transition. The ordering wave vector, in-plane magnetic correlations, missing entropy, spin state, and superexchange pathways are all consistent with bond-dependent Kitaev-Γ-Heisenberg exchange interactions in NaNi₂BiO_6–δ .

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Institute for Quantum Matter (IQM); Johns Hopkins Univ., Baltimore, MD (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); Natural Sciences and Engineering Research Council of Canada (NSERC); Canada Foundation for Innovation (CFI); Gordon and Betty Moore Foundation; National Institute of Standards and Technology (NIST); National Science Foundation (NSF)

Grant/Contract Number:: SC0019331; DMR-1508249

OSTI ID:: 1767739

Journal Information:: Physical Review B, Vol. 100, Issue 21; ISSN 2469-9950

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Title: Counterrotating magnetic order in the honeycomb layers of ${NaNi}_{2} {BiO}_{6 - δ}$