Static and dynamic magnetic properties of honeycomb lattice antiferromagnets Na 2 M 2 TeO 6 , M = Co and Ni

Samarakoon, Anjana M.; Chen, Qiang; Zhou, Haidong; Garlea, V. Ovidiu

doi:10.1103/physrevb.104.184415

Static and dynamic magnetic properties of honeycomb lattice antiferromagnets ${Na}_{2} M_{2} {TeO}_{6}$ , $M = Co$ and Ni

Journal Article · Sun Nov 14 23:00:00 EST 2021 · Physical Review B

DOI:https://doi.org/10.1103/physrevb.104.184415· OSTI ID:1831674

Samarakoon, Anjana M. ^[1]; ^[2]; Zhou, Haidong ^[2]; ^[3]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Argonne National Lab. (ANL), Argonne, IL (United States)
Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

The magnetic structures and spin dynamics of ${Na}_{2} {CO}_{2} {TeO}_{6}$ and ${Na}_{2} {Ni}_{2} {TeO}_{6}$ are investigated by means of elastic and inelastic neutron scattering measurements and the results are discussed in the context of a generalized Kitaev-Heisenberg model on a honeycomb lattice with strong spin-orbit coupling. The large number of parameters involved in the Hamiltonian model is evaluated by using an iterative optimization algorithm capable of extracting model solutions and simultaneously estimating their uncertainty. The analyses indicate that both Co²⁺ (d⁷) and Ni²⁺ (d⁸) antiferromagnets realize bond-dependent anisotropic nearest-neighbor interactions and support the theoretical predictions for the realization of Kitaev physics in 3 d electron systems with effective spins S = 1/2 and 1. By studying the Na-doped system Na_2.4Ni₂TeO₆, we show that the control of Na content can provide an effective route for fine-tuning the magnetic lattice dimensionality, as well as to controlling the bond-dependent anisotropic interactions.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1831674

Journal Information:: Physical Review B, Journal Name: Physical Review B Journal Issue: 18 Vol. 104; ISSN 2469-9950

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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