skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Frustrated magnetic interactions in an S = 3 / 2 bilayer honeycomb lattice compound Bi 3 Mn 4 O 12 ( NO 3 )

Journal Article · · Physical Review B

An inelastic neutron scattering study has been performed in an S = 3 / 2 bilayer honeycomb lattice compound Bi 3 Mn 4 O 12 ( NO 3 ) at ambient and high magnetic fields. Relatively broad and monotonically dispersive magnetic excitations were observed at ambient field, where no long-range magnetic order exists. In the magnetic-field-induced long-range ordered state at 10 T, the magnetic dispersions become slightly more intense, albeit still broad as in the disordered state, and two excitation gaps, probably originating from an easy-plane magnetic anisotropy and intrabilayer interactions, develop. Here, analyzing the magnetic dispersions using the linear spin-wave theory, we estimated the intraplane and intrabilayer magnetic interactions, which are almost consistent with those determined by ab initio density functional theory calculations, except the third and fourth neighbor intrabilayer interactions. Most importantly, as predicted by the theory, there is no significant frustration in the honeycomb plane but frustrating intrabilayer interactions probably give rise to the disordered ground state.

Research Organization:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
AC05-00OR22725
OSTI ID:
1571846
Journal Information:
Physical Review B, Vol. 100, Issue 13; ISSN 2469-9950
Publisher:
American Physical Society (APS)Copyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 4 works
Citation information provided by
Web of Science

References (49)

Nature of the Spin Liquid State of the Hubbard Model on a Honeycomb Lattice journal August 2011
The Disk Chopper Spectrometer at NIST: a new instrument for quasielastic neutron scattering studies journal August 2003
Phase diagram of a frustrated quantum antiferromagnet on the honeycomb lattice: Magnetic order versus valence-bond crystal formation journal July 2011
Anyons in an exactly solved model and beyond journal January 2006
DAVE: A Comprehensive Software Suite for the Reduction, Visualization, and Analysis of Low Energy Neutron Spectroscopic Data
  • Azuah, Richard Tumanjong; Kneller, Larry R.; Qiu, Yiming
  • Journal of Research of the National Institute of Standards and Technology, Vol. 114, Issue 6 https://doi.org/10.6028/jres.114.025
journal November 2009
Spiral order by disorder and lattice nematic order in a frustrated Heisenberg antiferromagnet on the honeycomb lattice journal June 2010
Broken discrete symmetries in a frustrated honeycomb antiferromagnet journal March 2013
Ground-state properties, excitation spectra, and phase transitions in the S = 1 2 and S = 3 2 bilayer Heisenberg models on the honeycomb lattice journal January 2012
Z 2 spin liquid and chiral antiferromagnetic phase in the Hubbard model on a honeycomb lattice journal July 2011
Synthesis, Crystal Structure, and Magnetic Properties of Bi 3 Mn 4 O 12 (NO 3 ) Oxynitrate Comprising S = 3/2 Honeycomb Lattice journal June 2009
Origin of magnetic frustration in Bi 3 Mn 4 O 12 ( NO 3 ) journal October 2017
Dzyaloshinsky-Moriya interaction and field-induced magnetic order in an antiferromagnetic honeycomb lattice compound Bi 3 Mn 4 O 12 (NO 3 ) studied by high-field electron spin resonance journal October 2012
Néel to dimer transition in spin- S antiferromagnets: Comparing bond operator theory with quantum Monte Carlo simulations for bilayer Heisenberg models journal December 2011
Quantum phases in the frustrated Heisenberg model on the bilayer honeycomb lattice journal January 2014
Quantum paramagnetic ground states on the honeycomb lattice and field-induced Néel order journal April 2011
Calculation of magnetic exchange couplings in the S = 3 / 2 honeycomb system (Bi 3 Mn 4 O 12 )NO 3 from first principles journal April 2011
Magnetic ground state of the frustrated honeycomb lattice antiferromagnet Bi 3 Mn 4 O 12 (NO 3 ) journal May 2012
Complete phase diagram of the spin- 1 2 J 1 - J 2 - J 3 model (with J 3 = J 2 ) on the honeycomb lattice journal April 2012
Deconfined Criticality in the Frustrated Heisenberg Honeycomb Antiferromagnet journal March 2013
Unexpected z -Direction Ising Antiferromagnetic Order in a Frustrated Spin- 1 / 2 J 1 J 2 X Y Model on the Honeycomb Lattice journal December 2013
Weak Plaquette Valence Bond Order in the S = 1 / 2 Honeycomb J 1 J 2 Heisenberg Model journal March 2013
Design and operation of the wide angular-range chopper spectrometer ARCS at the Spallation Neutron Source journal January 2012
Quantum disordered phase on the frustrated honeycomb lattice journal March 2011
Short and Long Range Magnetic Ordering in β-MnO 2 –A Temperature Study– journal December 2004
Disordered Ground State and Magnetic Field-Induced Long-Range Order in an S = 3 / 2 Antiferromagnetic Honeycomb Lattice Compound Bi 3 Mn 4 O 12 ( NO 3 ) journal October 2010
Neutron-scattering study of antiferromagnetism in YBa 2 Cu 3 O 6.15 journal November 1993
Field-induced multiple order-by-disorder state selection in an antiferromagnetic honeycomb bilayer lattice journal April 2016
Magnetic Structure of β -MnO 2 : X-ray Magnetic Scattering Study journal January 2001
Linear spin wave theory for single-Q incommensurate magnetic structures journal March 2015
Quantum phase diagram of a frustrated antiferromagnet on the bilayer honeycomb lattice journal June 2016
Spin-gap phase of a quantum spin system on a honeycomb lattice journal October 2006
The ground states of the classical heisenberg and planar models on the triangular and plane hexagonal lattices journal February 1986
Plaquette valence bond ordering in a J 1J 2 Heisenberg antiferromagnet on a honeycomb lattice journal May 2011
Novel Spin-Liquid States in the Frustrated Heisenberg Antiferromagnet on the Honeycomb Lattice journal November 2010
Exotic disordered phases in the quantum J 1 - J 2 model on the honeycomb lattice journal January 2013
Impact of Mn–O–O–Mn superexchange pathways in a honeycomb lattice Mn oxide with small charge-transfer energy journal May 2013
Schwinger boson mean field theories of spin liquid states on a honeycomb lattice: Projective symmetry group analysis and critical field theory journal July 2010
Quantum disordered phase on the frustrated honeycomb lattice text January 2010
Spiral order by disorder and lattice nematic order in a frustrated Heisenberg antiferromagnet on the honeycomb lattice text January 2010
Novel spin-liquid states in the frustrated Heisenberg antiferromagnet on the honeycomb lattice text January 2010
Plaquette valence-bond ordering in J_1-J_2 Heisenberg antiferromagnet on the honeycomb lattice text January 2010
Calculation of magnetic exchange couplings in S=3/2 honeycomb system Bi$_3$Mn$_4$O$_{12}$(NO$_3$)} from first principles text January 2011
Phase Diagram of a Frustrated Quantum Antiferromagnet on the Honeycomb Lattice: Magnetic Order versus Valence-Bond Crystal formation text January 2011
Deconfined criticality in the frustrated Heisenberg honeycomb antiferromagnet text January 2013
Linear spin wave theory for single-Q incommensurate magnetic structures text January 2014
Field induced multiple order-by-disorder state selection in antiferromagnetic honeycomb bilayer lattice text January 2015
Quantum phase diagram of a frustrated antiferromagnet on the bilayer honeycomb lattice text January 2015
Origin of magnetic frustration in Bi$_3$Mn$_4$O$_{12}$(NO$_3$) text January 2017
Anyons in an exactly solved model and beyond text January 2005

Figures / Tables (7)


Similar Records

Structural and electronic properties of the first iridium containing mixed B-site spinel oxide: Cu[Ir1.5Cu0.5]O4
Journal Article · Mon Sep 27 00:00:00 EDT 2021 · Physical Review Materials · OSTI ID:1571846

Consequences of magnetic ordering in chiral Mn1/3NbS2
Journal Article · Mon Nov 11 00:00:00 EST 2019 · Physical Review B · OSTI ID:1571846

Towards cubic symmetry for Ir4+: Structure and magnetism of the antifluorite K2IrBr6
Journal Article · Mon Mar 29 00:00:00 EDT 2021 · Physical Review B · OSTI ID:1571846