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InGaSb Defect Filter Layer to Improve Performance of GaSb Solar Cells Grown on GaAs Substrates

Journal Article · · Journal of Electronic Materials
 [1];  [2];  [1];  [1];  [1]
  1. Univ. of New Mexico, Albuquerque, NM (United States)
  2. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

The reduction of the threading dislocation density in metamorphic GaSb grown on GaAs substrates through the use of InGaSb defect filter layers has been investigated. More specifically, we study the effects of strain and thickness on the ability of a InGaSb defect filter layer to reduce threading dislocations in GaSb solar cells grown on GaAs substrates. The strain between the GaSb metamorphic layer on GaAs substrate (99.5% relaxed) and the InGaSb defect filter layer is varied by changing the indium composition in the InGaSb layer. Here, it is demonstrated that an InGaSb defect filter layer with 0.6% strain is more effective for blocking threading dislocations compared with higher-strain layers, resulting in improved short-circuit current (Jsc) and open-circuit voltage (Voc) for the metamorphic GaSb solar cell. The optimization of the defect filter layer involves varying the thickness of the layer to achieve the lowest possible threading dislocation density. This also takes into account the critical thickness of the InGaSb layer on GaSb to avoid generation of threading dislocations from the InGaSb layer itself. It is shown that adding an In0.11Ga0.89Sb defect filter layer with thickness of 250 nm and 0.6% strain beneath a GaSb solar cell grown on a GaAs substrate improves Voc from 0.1 V to 0.16 V and Jsc from 19.7 mA/cm2 to 24.7 mA/cm2.

Research Organization:
Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States). Center for Integrated Nanotechnologies (CINT)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)
Grant/Contract Number:
AC04-94AL85000
OSTI ID:
1760369
Report Number(s):
SAND--2020-13825J; 692979
Journal Information:
Journal of Electronic Materials, Journal Name: Journal of Electronic Materials Journal Issue: 12 Vol. 49; ISSN 0361-5235
Publisher:
SpringerCopyright Statement
Country of Publication:
United States
Language:
English

References (26)

Wafer bonded four-junction GaInP/GaAs//GaInAsP/GaInAs concentrator solar cells with 44.7% efficiency: Wafer bonded four-junction concentrator solar cells with 44.7% efficiency journal January 2014
Corrigendum to ‘Solar cell efficiency tables (version 49)’[Prog. Photovolt: Res. Appl. 2017; 25:3-13]: Corrigendum to ‘Solar cell efficiency tables (version 49)’[Prog. Photovolt: Res. Appl. 2017; 25:3-13] journal February 2017
Solar cell efficiency tables (version 52)
  • Green, Martin A.; Hishikawa, Yoshihiro; Dunlop, Ewan D.
  • Progress in Photovoltaics: Research and Applications, Vol. 26, Issue 7 https://doi.org/10.1002/pip.3040
journal June 2018
InGaP/GaAs-based multijunction solar cells
  • Takamoto, Tatsuya; Kaneiwa, Minoru; Imaizumi, Mitsuru
  • Progress in Photovoltaics: Research and Applications, Vol. 13, Issue 6 https://doi.org/10.1002/pip.642
journal January 2005
The measurement of threading dislocation densities in semiconductor crystals by X-ray diffraction journal January 1994
Use of misfit strain to remove dislocations from epitaxial thin films journal April 1976
Progress and challenges for next-generation high-efficiency multijunction solar cells journal December 2010
Dependence of the AlSb buffers on GaSb/GaAs(001) heterostructures journal April 2007
Reducing threading dislocation density in GaSb photovoltaic devices on GaAs by using AlSb dislocation filtering layers journal October 2018
Antimonide-based compound semiconductors for electronic devices: A review journal December 2005
Molecular beam epitaxy of GaSb on GaAs substrates with AlSb/GaSb compound buffer layers journal October 2010
29.5%‐efficient GaInP/GaAs tandem solar cells journal August 1994
Estimating the band discontinuity at GaInSb/GaSb heterojunction by investigation of single-quantum well photoluminescence journal January 2003
2.0 μm wavelength InAs quantum dashes grown on a GaAs substrate using a metamorphic buffer layer journal March 2004
40% efficient metamorphic GaInP∕GaInAs∕Ge multijunction solar cells journal April 2007
Transmission electron microscopy investigation of dislocation bending by GaAsP/GaAs strained‐layer superlattices on heteroepitaxial GaAs/Si journal November 1990
Strain relief at the GaSb/GaAs interface versus substrate surface treatment and AlSb interlayers thickness journal January 2011
GaSb solar cells grown on GaAs via interfacial misfit arrays for use in the III-Sb multi-junction cell journal December 2017
Calculation of critical layer thickness versus lattice mismatch for Ge x Si 1− x /Si strained‐layer heterostructures journal August 1985
AlAsSb/GaSb doped distributed Bragg reflectors for electrically pumped VCSELs emitting around 2.3 µm journal September 2007
Reduction of hetero-interface resistivity in n-type AlAsSb/GaSb distributed Bragg reflectors journal January 2008
Four-Junction Wafer-Bonded Concentrator Solar Cells journal January 2016
AlGaSb-Based Solar Cells Grown on GaAs: Structural Investigation and Device Performance journal November 2017
High-Performance $\hbox{In}_{0.5}\hbox{Ga}_{0.5} \hbox{As/GaAs}$ Quantum-Dot Lasers on Silicon With Multiple-Layer Quantum-Dot Dislocation Filters journal November 2007
Analysis of atomic structure in InAs quantum dashes grown on AlGaAsSb metamorphic buffers
  • Balakrishnan, Ganesh; Huang, Shenghong; Dawson, L. R.
  • Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 22, Issue 3 https://doi.org/10.1116/1.1755710
journal January 2004
Dislocation Density Reduction in GaSb Films Grown on GaAs Substrates by Molecular Beam Epitaxy journal April 1997

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