Polyacids as Modulators for the Synthesis of UiO-66

Bentz, Kyle C.; Ayala, Sergio; Kalaj, Mark; Cohen, Seth M.

doi:10.1071/ch19271

Polyacids as Modulators for the Synthesis of UiO-66

Journal Article · Mon Dec 31 23:00:00 EST 2018 · Australian Journal of Chemistry

DOI:https://doi.org/10.1071/ch19271· OSTI ID:1610003

Bentz, Kyle C. ^[1]; Ayala, Sergio; Kalaj, Mark; Cohen, Seth M.

DOE/OSTI

Poly(acrylic acid) (PAA) and poly(vinylbenzoic acid) (PBA) were synthesized via reversible addition–fragmentation chain transfer (RAFT) polymerization and used as modulators for the synthesis of the metal–organic framework (MOF) UiO-66 (UiO=University of Oslo). Whereas typical syntheses of UiO-66 require large excesses of acid modulators, such as acetic acid or benzoic acid, to achieve controlled particle size and morphology of the resulting MOF particles, the use of polymerized acids allows for narrow particle size distributions at sub-stoichiometric quantities of modulator. We show using scanning electron microscopy and dynamic light scattering techniques that polyacids can act as alternative modulators for the growth of UiO-66.

Research Organization:: Univ. of California, San Diego, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: FG02-08ER46519

OSTI ID:: 1610003

Journal Information:: Australian Journal of Chemistry, Journal Name: Australian Journal of Chemistry Journal Issue: 10 Vol. 72; ISSN 0004-9425

Publisher:: CSIRO Publishing

Country of Publication:: United States

Language:: English

References (15)

Effect of Organic Polymer Additive on Crystallization of Porous Coordination Polymer Uemura, Takashi; Hoshino, Yousuke; Kitagawa, Susumu Chemistry of Materials, Vol. 18, Issue 4 https://doi.org/10.1021/cm052427g	journal	February 2006
Block co-polyMOFs: morphology control of polymer–MOF hybrid materials Ayala, Sergio; Bentz, Kyle C.; Cohen, Seth M. Chemical Science, Vol. 10, Issue 6 https://doi.org/10.1039/C8SC04250K	journal	January 2019
Defect Engineering: Tuning the Porosity and Composition of the Metal–Organic Framework UiO-66 via Modulated Synthesis Shearer, Greig C.; Chavan, Sachin; Bordiga, Silvia Chemistry of Materials, Vol. 28, Issue 11 https://doi.org/10.1021/acs.chemmater.6b00602	journal	May 2016
Poly(isophthalic acid)(ethylene oxide) as a Macromolecular Modulator for Metal–Organic Polyhedra Chen, Teng-Hao; Wang, Le; Trueblood, Jonathan V. Journal of the American Chemical Society, Vol. 138, Issue 30 https://doi.org/10.1021/jacs.6b04971	journal	July 2016
Role of Modulators in Controlling the Colloidal Stability and Polydispersity of the UiO-66 Metal–Organic Framework Morris, William; Wang, Shunzhi; Cho, David ACS Applied Materials & Interfaces, Vol. 9, Issue 39 https://doi.org/10.1021/acsami.7b01040	journal	April 2017
Supramolecular Metallopolymers: From Linear Materials to Infinite Networks Bentz, Kyle C.; Cohen, Seth M. Angewandte Chemie International Edition, Vol. 57, Issue 46 https://doi.org/10.1002/anie.201806912	journal	October 2018
Supramolecular templating of hierarchically porous metal–organic frameworks Bradshaw, Darren; El-Hankari, Samir; Lupica-Spagnolo, Lucia Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C4CS00127C	journal	January 2014
Hierarchical bicontinuous porosity in metal–organic frameworks templated from functional block co-oligomer micelles Cao, Shuai; Gody, Guillaume; Zhao, Wei Chemical Science, Vol. 4, Issue 9 https://doi.org/10.1039/c3sc51336j	journal	January 2013
Highly Monodisperse M ^III -Based soc -MOFs (M = In and Ga) with Cubic and Truncated Cubic Morphologies Pang, Maolin; Cairns, Amy J.; Liu, Yunling Journal of the American Chemical Society, Vol. 134, Issue 32 https://doi.org/10.1021/ja3049282	journal	August 2012
Modulated synthesis of monodisperse MOF-5 crystals with tunable sizes and shapes Wang, Sixia; Lv, Yuan; Yao, Youjin Inorganic Chemistry Communications, Vol. 93 https://doi.org/10.1016/j.inoche.2018.05.010	journal	July 2018
A Route to Bimodal Micro-Mesoporous Metal–Organic Frameworks Nanocrystals Pham, Minh-Hao; Vuong, Gia-Thanh; Fontaine, Frédéric-Georges Crystal Growth & Design, Vol. 12, Issue 2 https://doi.org/10.1021/cg201483y	journal	December 2011
New synthetic routes towards MOF production at scale Rubio-Martinez, Marta; Avci-Camur, Ceren; Thornton, Aaron W. Chemical Society Reviews, Vol. 46, Issue 11 https://doi.org/10.1039/C7CS00109F	journal	January 2017
Morphogenesis of Metal–Organic Mesocrystals Mediated by Double Hydrophilic Block Copolymers Hwang, Jongkook; Heil, Tobias; Antonietti, Markus Journal of the American Chemical Society, Vol. 140, Issue 8 https://doi.org/10.1021/jacs.7b12633	journal	February 2018
Synthesis and Self-Assembly of Monodispersed Metal-Organic Framework Microcrystals Lu, Guang; Cui, Chenlong; Zhang, Weina Chemistry - An Asian Journal, Vol. 8, Issue 1 https://doi.org/10.1002/asia.201200754	journal	October 2012
Additive-mediated size control of MOF nanoparticles Ranft, Annekathrin; Betzler, Sophia B.; Haase, Frederik CrystEngComm, Vol. 15, Issue 45 https://doi.org/10.1039/c3ce41152d	journal	January 2013

Similar Records

Polyacids as Modulators for the Synthesis of UiO-66

Journal Article · Thu Sep 05 00:00:00 EDT 2019 · Australian Journal of Chemistry · OSTI ID:1779866

Hierarchical structure and porosity in UiO-66 polyMOFs

Journal Article · Sat Dec 31 23:00:00 EST 2016 · ChemComm · OSTI ID:1535114

Hierarchical structure and porosity in UiO-66 polyMOFs

Journal Article · Mon Feb 20 23:00:00 EST 2017 · ChemComm · OSTI ID:1780606

Related Subjects

Chemistry

Polyacids as Modulators for the Synthesis of UiO-66

Citation Formats

References (15)

Similar Records

Related Subjects