Nanosecond X-ray diffraction of shock-compressed superionic water ice

Millot, Marius; Coppari, Federica; Rygg, J. Ryan; Barrios, Antonio Correa; Hamel, Sebastien; Swift, Damian C.; Eggert, Jon H.

doi:10.1038/s41586-019-1114-6

Nanosecond X-ray diffraction of shock-compressed superionic water ice

Journal Article · Wed May 08 00:00:00 EDT 2019 · Nature (London)

DOI:https://doi.org/10.1038/s41586-019-1114-6· OSTI ID:1568026

Millot, Marius ^[1]; Coppari, Federica ^[1]; Rygg, J. Ryan ^[2]; Barrios, Antonio Correa ^[1]; Hamel, Sebastien ^[1]; Swift, Damian C. ^[1]; Eggert, Jon H. ^[1]

Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Univ. of Rochester, Rochester, NY (United States)

Since Bridgman’s discovery of five solid water (H₂O) ice phases in 1912, studies on the extraordinary polymorphism of H₂O have documented more than seventeen crystalline and several amorphous ice structures, as well as rich metastability and kinetic effects. Here, this unique behaviour is due in part to the geometrical frustration of the weak intermolecular hydrogen bonds and the sizeable quantum motion of the light hydrogen ions (protons). Particularly intriguing is the prediction that H₂O becomes superionic—with liquid-like protons diffusing through the solid lattice of oxygen—when subjected to extreme pressures exceeding 100 gigapascals and high temperatures above 2,000 kelvin.

View Accepted Manuscript (DOE)

Research Organization:: Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC52-07NA27344

OSTI ID:: 1568026

Report Number(s):: LLNL-JRNL--740026; 892369

Journal Information:: Nature (London), Journal Name: Nature (London) Journal Issue: 7755 Vol. 569; ISSN 0028-0836

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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