An Aqueous Symmetric Sodium-Ion Battery with NASICON-Structured Na3MnTi(PO4)3

Gao, Hongcai; Goodenough, John B.

doi:10.1002/anie.201606508

An Aqueous Symmetric Sodium-Ion Battery with NASICON-Structured Na₃MnTi(PO₄)₃

Journal Article · Tue Sep 13 00:00:00 EDT 2016 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.201606508· OSTI ID:1533083

Gao, Hongcai ^[1]; Goodenough, John B. ^[2]

Univ. of Texas, Austin, TX (United States). Texas Materials Inst.; DOE/OSTI
Univ. of Texas, Austin, TX (United States). Texas Materials Inst.

A symmetric sodium-ion battery with an aqueous electrolyte is demonstrated; it utilizes the NASICON-structured Na₃MnTi(PO₄)₃ as both the anode and the cathode. The NASICON-structured Na₃MnTi(PO₄)₃ possesses two electrochemically active transition metals with the redox couples of Ti⁴⁺/Ti³⁺ and Mn³⁺/Mn²⁺ working on the anode and cathode sides, respectively. The symmetric cell based on this bipolar electrode material exhibits a well-defined voltage plateau centered at about 1.4 V in an aqueous electrolyte with a stable cycle performance and superior rate capability. The advent of aqueous symmetric sodium-ion battery with high safety and low cost may provide a solution for large-scale stationary energy storage.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Texas, Austin, TX (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0005397

OSTI ID:: 1533083

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 41 Vol. 55; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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V2O5 Nanospheres with Mixed Vanadium Valences as High Electrochemically Active Aqueous Zinc-Ion Battery Cathode Liu, Fei; Chen, Zixian; Fang, Guozhao Nano-Micro Letters, Vol. 11, Issue 1 https://doi.org/10.1007/s40820-019-0256-2	journal	March 2019
NASICON-Structured NaTi2(PO4)3 for Sustainable Energy Storage Wu, Mingguang; Ni, Wei; Hu, Jin Nano-Micro Letters, Vol. 11, Issue 1 https://doi.org/10.1007/s40820-019-0273-1	journal	May 2019
Building aqueous K-ion batteries for energy storage Jiang, Liwei; Lu, Yaxiang; Zhao, Chenglong Nature Energy, Vol. 4, Issue 6 https://doi.org/10.1038/s41560-019-0388-0	journal	May 2019
Sodium-ion batteries: present and future Hwang, Jang-Yeon; Myung, Seung-Taek; Sun, Yang-Kook Chemical Society Reviews, Vol. 46, Issue 12 https://doi.org/10.1039/c6cs00776g	journal	January 2017
Achieving superb sodium storage performance on carbon anodes through an ether-derived solid electrolyte interphase Zhang, Jun; Wang, Da-Wei; Lv, Wei Energy & Environmental Science, Vol. 10, Issue 1 https://doi.org/10.1039/c6ee03367a	journal	January 2017
Cross-linked Na ₂ VTi(PO ₄ ) ₃ @C hierarchical nanofibers as high-performance bi-functional electrodes for symmetric aqueous rechargeable sodium batteries Dong, Jing; Zhang, Guoming; Wang, Xiaoguang Journal of Materials Chemistry A, Vol. 5, Issue 35 https://doi.org/10.1039/c7ta05361d	journal	January 2017
Coupled X-ray diffraction and electrochemical studies of the mixed Ti/V-containing NASICON: Na ₂ TiV(PO ₄ ) ₃ Lalère, F.; Seznec, V.; Courty, M. Journal of Materials Chemistry A, Vol. 6, Issue 15 https://doi.org/10.1039/c7ta10689k	journal	January 2018
Synthesis of uniform hierarchical Na ₃ V _1.95 Mn _0.05 (PO ₄ ) ₂ F ₃ @C hollow microspheres as a cathode material for sodium-ion batteries Zhang, Yu; Guo, Shirui; Xu, Huayun Journal of Materials Chemistry A, Vol. 6, Issue 10 https://doi.org/10.1039/c7ta11105c	journal	January 2018
Ultrafast Na intercalation chemistry of Na ₂ Ti _3/2 Mn _1/2 (PO ₄ ) ₃ nanodots planted in a carbon matrix as a low cost anode for aqueous sodium-ion batteries Lei, Ping; Liu, Kelu; Wan, Xin Chemical Communications, Vol. 55, Issue 4 https://doi.org/10.1039/c8cc07668e	journal	January 2019
Exploring competitive features of stationary sodium ion batteries for electrochemical energy storage Liu, Tiefeng; Zhang, Yaping; Jiang, Zhanguo Energy & Environmental Science, Vol. 12, Issue 5 https://doi.org/10.1039/c8ee03727b	journal	January 2019
High rate and stable symmetric potassium ion batteries fabricated with flexible electrodes and solid-state electrolytes Lu, Ke; Zhang, Hong; Gao, Siyuan Nanoscale, Vol. 10, Issue 44 https://doi.org/10.1039/c8nr07268j	journal	January 2018
A low-cost Mg ²⁺ /Na ⁺ hybrid aqueous battery Cao, Xi; Wang, Lulu; Chen, Jitao Journal of Materials Chemistry A, Vol. 6, Issue 32 https://doi.org/10.1039/c8ta04930k	journal	January 2018
Cobalt nickel nitride coated by a thin carbon layer anchoring on nitrogen-doped carbon nanotube anodes for high-performance lithium-ion batteries Zou, Rujia; Xu, Mingdong; He, Shu-Ang Journal of Materials Chemistry A, Vol. 6, Issue 40 https://doi.org/10.1039/c8ta08537d	journal	January 2018
The top-down synthesis of sequentially controlled architectures for honeycomb-layered Na ₃ Ni ₂ BiO ₆ towards high-voltage and superior performance cathodes for sodium-ion batteries Wang, Chen; Zhang, Guoming; Qu, Weili Journal of Materials Chemistry A, Vol. 7, Issue 4 https://doi.org/10.1039/c8ta11288f	journal	January 2019
A highly integrated All-manganese battery with oxide nanoparticles supported on the cathode and anode by super-aligned carbon nanotubes Chen, Min; Pan, Zhenghui; Jin, Xiaojing Journal of Materials Chemistry A, Vol. 7, Issue 9 https://doi.org/10.1039/c8ta11415c	journal	January 2019
An ion-conducting SnS–SnS ₂ hybrid coating for commercial activated carbons enabling their use as high performance anodes for sodium-ion batteries Zhang, Si-Wei; Lv, Wei; Qiu, Dong Journal of Materials Chemistry A, Vol. 7, Issue 17 https://doi.org/10.1039/c9ta00599d	journal	January 2019
Self-reductive synthesis of MXene/Na _0.55 Mn _1.4 Ti _0.6 O ₄ hybrids for high-performance symmetric lithium ion batteries Zou, Guodong; Ge, Bingcheng; Zhang, Hao Journal of Materials Chemistry A, Vol. 7, Issue 13 https://doi.org/10.1039/c9ta00744j	journal	January 2019
Delicate lattice modulation enables superior Na storage performance of Na ₃ V ₂ (PO ₄ ) ₃ as both an anode and cathode material for sodium-ion batteries: understanding the role of calcium substitution for vanadium Zhao, Lina; Zhao, Hailei; Du, Zhihong Journal of Materials Chemistry A, Vol. 7, Issue 16 https://doi.org/10.1039/c9ta00869a	journal	January 2019
Faradaic reactions in capacitive deionization for desalination and ion separation Yu, Fei; Wang, Lei; Wang, Ying Journal of Materials Chemistry A, Vol. 7, Issue 27 https://doi.org/10.1039/c9ta01264h	journal	January 2019
Rechargeable aqueous electrolyte batteries: from univalent to multivalent cation chemistry Demir-Cakan, Rezan; Palacin, M. Rosa; Croguennec, Laurence Journal of Materials Chemistry A, Vol. 7, Issue 36 https://doi.org/10.1039/c9ta04735b	journal	January 2019
Rechargeable aqueous hybrid ion batteries: developments and prospects Ao, Huaisheng; Zhao, Yingyue; Zhou, Jie Journal of Materials Chemistry A, Vol. 7, Issue 32 https://doi.org/10.1039/c9ta06433h	journal	January 2019
Electrolytes and Interphases in Sodium-Based Rechargeable Batteries : Recent Advances and Perspectives Eshetu, Gebrekidan Gebresilassie; Elia, Giuseppe Antonio; Armand, Michel RWTH Aachen University https://doi.org/10.18154/rwth-2020-04398	text	January 2020
In Situ SEM Observation of Structured Si/C Anodes Reactions in an Ionic-Liquid-Based Lithium-Ion Battery Shi, Huifeng; Liu, Xianqiang; Wu, Rui Applied Sciences, Vol. 9, Issue 5 https://doi.org/10.3390/app9050956	journal	March 2019
Intermixed Cation-Anion Aqueous Battery Based on an Extremely Fast and Long-Cycling Di-Block Bipyridinium-Naphthalene Diimide Oligomer Perticarari, Sofia; Doizy, Tom; Soudan, Patrick arXiv https://doi.org/10.48550/arxiv.1906.11087	text	January 2019
In Situ SEM Observation of Structured Si/C Anodes Reactions in an Ionic-Liquid-Based Lithium-Ion Battery Shi, Huifeng; Liu, Xianqiang; Wu, Rui Karlsruhe https://doi.org/10.5445/ir/1000094192	text	January 2019
Electrolytes and Interphases in Sodium-Based Rechargeable Batteries: Recent Advances and Perspectives Eshetu, Gebrekidan Gebresilassie; Elia, Giuseppe Antonio; Armand, Michel Karlsruhe https://doi.org/10.5445/ir/1000118522	text	January 2020

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Related Subjects

25 ENERGY STORAGE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
aqueous electrolyte
energy storage
sodium-ion battery
symmetric battery