An Aqueous Symmetric Sodium-Ion Battery with NASICON-Structured Na3MnTi(PO4)3

Gao, Hongcai; Goodenough, John B.

doi:10.1002/anie.201606508

Title: An Aqueous Symmetric Sodium-Ion Battery with NASICON-Structured Na₃MnTi(PO₄)₃

Journal Article · Tue Sep 13 00:00:00 EDT 2016 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.201606508· OSTI ID:1533083

Gao, Hongcai ^[1]; Goodenough, John B. ^[1]

Univ. of Texas, Austin, TX (United States). Texas Materials Inst.

A symmetric sodium-ion battery with an aqueous electrolyte is demonstrated; it utilizes the NASICON-structured Na₃MnTi(PO₄)₃ as both the anode and the cathode. The NASICON-structured Na₃MnTi(PO₄)₃ possesses two electrochemically active transition metals with the redox couples of Ti⁴⁺/Ti³⁺ and Mn³⁺/Mn²⁺ working on the anode and cathode sides, respectively. The symmetric cell based on this bipolar electrode material exhibits a well-defined voltage plateau centered at about 1.4 V in an aqueous electrolyte with a stable cycle performance and superior rate capability. The advent of aqueous symmetric sodium-ion battery with high safety and low cost may provide a solution for large-scale stationary energy storage.

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Research Organization:: Univ. of Texas, Austin, TX (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0005397

OSTI ID:: 1533083

Journal Information:: Angewandte Chemie (International Edition), Vol. 55, Issue 41; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 197 works

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References (58)

A High-Rate and Ultralong-Life Sodium-Ion Battery Based on NaTi ₂ (PO ₄ ) ₃ Nanocubes with Synergistic Coating of Carbon and Rutile TiO ₂ Yang, Jie; Wang, Hua; Hu, Pengfei Small, Vol. 11, Issue 31 https://doi.org/10.1002/smll.201500144	journal	April 2015
A New Water Oxidation Catalyst: Lithium Manganese Pyrophosphate with Tunable Mn Valency Park, Jimin; Kim, Hyunah; Jin, Kyoungsuk Journal of the American Chemical Society, Vol. 136, Issue 11 https://doi.org/10.1021/ja410223j	journal	March 2014
Fast Na+-ion transport in skeleton structures Goodenough, J. B.; Hong, H. Y-P.; Kafalas, J. A. Materials Research Bulletin, Vol. 11, Issue 2 https://doi.org/10.1016/0025-5408(76)90077-5	journal	February 1976
A High Rate 1.2V Aqueous Sodium-ion Battery Based on All NASICON Structured NaTi2(PO4)3 and Na3V2(PO4)3 Zhang, Qing; Liao, Chaoyi; Zhai, Tianyou Electrochimica Acta, Vol. 196 https://doi.org/10.1016/j.electacta.2016.03.007	journal	April 2016
Lithium Batteries and Cathode Materials Whittingham, M. Stanley Chemical Reviews, Vol. 104, Issue 10, p. 4271-4302 https://doi.org/10.1021/cr020731c	journal	October 2004
XPS and ionic conductivity studies on Li2O–Al2O3–(TiO2 or GeO2)–P2O5 glass–ceramics Chowdari, B. Solid State Ionics, Vol. 136-137, Issue 1-2 https://doi.org/10.1016/S0167-2738(00)00500-2	journal	November 2000
Na3Ti2(PO4)3 as a sodium-bearing anode for rechargeable aqueous sodium-ion batteries Li, Zheng; Ravnsbæk, Dorthe B.; Xiang, Kai Electrochemistry Communications, Vol. 44 https://doi.org/10.1016/j.elecom.2014.04.003	journal	July 2014
Flexible Aqueous Lithium-Ion Battery with High Safety and Large Volumetric Energy Density Dong, Xiaoli; Chen, Long; Su, Xiuli Angewandte Chemie, Vol. 128, Issue 26 https://doi.org/10.1002/ange.201602766	journal	May 2016
Full open-framework batteries for stationary energy storage Pasta, Mauro; Wessells, Colin D.; Liu, Nian Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4007	journal	January 2014
Hybrid aqueous battery based on Na3V2(PO4)3/C cathode and zinc anode for potential large-scale energy storage Li, Guolong; Yang, Ze; Jiang, Yan Journal of Power Sources, Vol. 308 https://doi.org/10.1016/j.jpowsour.2016.01.058	journal	March 2016
High-performance symmetric sodium-ion batteries using a new, bipolar O3-type material, Na _0.8 Ni _0.4 Ti _0.6 O ₂ Guo, Shaohua; Yu, Haijun; Liu, Pan Energy & Environmental Science, Vol. 8, Issue 4 https://doi.org/10.1039/C4EE03361B	journal	January 2015
A High-Voltage and Ultralong-Life Sodium Full Cell for Stationary Energy Storage Guo, Shaohua; Liu, Pan; Sun, Yang Angewandte Chemie International Edition, Vol. 54, Issue 40 https://doi.org/10.1002/anie.201505215	journal	August 2015
Natriumionenbatterien für die elektrochemische Energiespeicherung Kundu, Dipan; Talaie, Elahe; Duffort, Victor Angewandte Chemie, Vol. 127, Issue 11 https://doi.org/10.1002/ange.201410376	journal	February 2015
Highly Reversible and Ultrafast Sodium Storage in NaTi ₂ (PO ₄ ) ₃ Nanoparticles Embedded in Nanocarbon Networks Jiang, Yu; Shi, Jinan; Wang, Min ACS Applied Materials & Interfaces, Vol. 8, Issue 1 https://doi.org/10.1021/acsami.5b09811	journal	December 2015
Towards High Power High Energy Aqueous Sodium-Ion Batteries: The NaTi ₂ (PO ₄ ) ₃ /Na _0.44 MnO ₂ System Li, Zheng; Young, David; Xiang, Kai Advanced Energy Materials, Vol. 3, Issue 3 https://doi.org/10.1002/aenm.201200598	journal	October 2012
Energetic Aqueous Rechargeable Sodium-Ion Battery Based on Na ₂ CuFe(CN) ₆ -NaTi ₂ (PO ₄ ) ₃ Intercalation Chemistry Wu, Xian-yong; Sun, Meng-ying; Shen, Yi-fei ChemSusChem, Vol. 7, Issue 2 https://doi.org/10.1002/cssc.201301036	journal	January 2014
Tunable Reaction Potentials in Open Framework Nanoparticle Battery Electrodes for Grid-Scale Energy Storage Wessells, Colin D.; McDowell, Matthew T.; Peddada, Sandeep V. ACS Nano, Vol. 6, Issue 2, p. 1688-1694 https://doi.org/10.1021/nn204666v	journal	January 2012
Fabrication and performances of all solid-state symmetric sodium battery based on NASICON-related compounds Noguchi, Yoshinori; Kobayashi, Eiji; Plashnitsa, Larisa S. Electrochimica Acta, Vol. 101 https://doi.org/10.1016/j.electacta.2012.11.038	journal	July 2013
Mechanisms and Performances of Na _1.5 Fe _0.5 Ti _1.5 (PO ₄ ) ₃ /C Composite as Electrode Material for Na-Ion Batteries Difi, Siham; Saadoune, Ismael; Sougrati, Moulay Tahar The Journal of Physical Chemistry C, Vol. 119, Issue 45 https://doi.org/10.1021/acs.jpcc.5b07931	journal	November 2015
NASICON-Structured NaTi ₂ (PO ₄ ) ₃ @C Nanocomposite as the Low Operation-Voltage Anode Material for High-Performance Sodium-Ion Batteries Wang, Dongxue; Liu, Qiang; Chen, Chaoji ACS Applied Materials & Interfaces, Vol. 8, Issue 3 https://doi.org/10.1021/acsami.5b11003	journal	January 2016
A Polyionic, Large-Format Energy Storage Device Using an Aqueous Electrolyte and Thick-Format Composite NaTi ₂ (PO ₄ ) ₃ /Activated Carbon Negative Electrodes Whitacre, J. F.; Shanbhag, S.; Mohamed, A. Energy Technology, Vol. 3, Issue 1 https://doi.org/10.1002/ente.201402127	journal	November 2014
The Li-Ion Rechargeable Battery: A Perspective Goodenough, John B.; Park, Kyu-Sung Journal of the American Chemical Society, Vol. 135, Issue 4 https://doi.org/10.1021/ja3091438	journal	January 2013
Atomic Structure and Kinetics of NASICON Na _x V ₂ (PO ₄ ) ₃ Cathode for Sodium-Ion Batteries Jian, Zelang; Yuan, Chenchen; Han, Wenze Advanced Functional Materials, Vol. 24, Issue 27 https://doi.org/10.1002/adfm.201400173	journal	April 2014
Lithium insertion into Fe2(SO4)3 frameworks Manthiram, A.; Goodenough, J. B. Journal of Power Sources, Vol. 26, Issue 3-4 https://doi.org/10.1016/0378-7753(89)80153-3	journal	May 1989
Aqueous rechargeable lithium batteries as an energy storage system of superfast charging Tang, Wei; Zhu, Yusong; Hou, Yuyang Energy & Environmental Science, Vol. 6, Issue 7 https://doi.org/10.1039/c3ee24249h	journal	January 2013
Na2FeP2O7 as a positive electrode material for rechargeable aqueous sodium-ion batteries Jung, Young Hwa; Lim, Chek Hai; Kim, Joo-Hyung RSC Advances, Vol. 4, Issue 19 https://doi.org/10.1039/c3ra47560c	journal	January 2014
A comprehensive review of sodium layered oxides: powerful cathodes for Na-ion batteries Han, Man Huon; Gonzalo, Elena; Singh, Gurpreet Energy & Environmental Science, Vol. 8, Issue 1 https://doi.org/10.1039/C4EE03192J	journal	January 2015
Electrochemical Behavior of Olivine-Type LiMnPO[sub 4] in Aqueous Solutions Minakshi, Manickam; Singh, Pritam; Thurgate, Stephen Electrochemical and Solid-State Letters, Vol. 9, Issue 10 https://doi.org/10.1149/1.2236379	journal	January 2006
The Emerging Chemistry of Sodium Ion Batteries for Electrochemical Energy Storage Kundu, Dipan; Talaie, Elahe; Duffort, Victor Angewandte Chemie International Edition, Vol. 54, Issue 11 https://doi.org/10.1002/anie.201410376	journal	February 2015
Electrochemical Properties of NaTi2(PO4)3 Anode for Rechargeable Aqueous Sodium-Ion Batteries Park, Sun Il; Gocheva, Irina; Okada, Shigeto Journal of The Electrochemical Society, Vol. 158, Issue 10 https://doi.org/10.1149/1.3611434	journal	January 2011
The First Report on Excellent Cycling Stability and Superior Rate Capability of Na ₃ V ₂ (PO ₄ ) ₃ for Sodium Ion Batteries Saravanan, Kuppan; Mason, Chad W.; Rudola, Ashish Advanced Energy Materials, Vol. 3, Issue 4 https://doi.org/10.1002/aenm.201200803	journal	November 2012
Flexible Aqueous Lithium-Ion Battery with High Safety and Large Volumetric Energy Density Dong, Xiaoli; Chen, Long; Su, Xiuli Angewandte Chemie International Edition, Vol. 55, Issue 26 https://doi.org/10.1002/anie.201602766	journal	May 2016
Electrochemical and Thermal Properties of NASICON Structured Na ₃ V ₂ (PO ₄ ) ₃ as a Sodium Rechargeable Battery Cathode: A Combined Experimental and Theoretical Study Lim, Soo Yeon; Kim, Heejin; Shakoor, R. A. Journal of The Electrochemical Society, Vol. 159, Issue 9 https://doi.org/10.1149/2.015209jes	journal	January 2012
Nanostructured alkali cation incorporated δ-MnO ₂ cathode materials for aqueous sodium-ion batteries Liu, Yang; Qiao, Yun; Zhang, Wuxing Journal of Materials Chemistry A, Vol. 3, Issue 15 https://doi.org/10.1039/C5TA00396B	journal	January 2015
Evolution of Strategies for Modern Rechargeable Batteries Goodenough, John B. Accounts of Chemical Research, Vol. 46, Issue 5 https://doi.org/10.1021/ar2002705	journal	June 2012
Electrochemical Energy Storage for Green Grid Yang, Zhenguo; Zhang, Jianlu; Kintner-Meyer, Michael C. W. Chemical Reviews, Vol. 111, Issue 5, p. 3577-3613 https://doi.org/10.1021/cr100290v	journal	May 2011
Aqueous Rechargeable Li and Na Ion Batteries Kim, Haegyeom; Hong, Jihyun; Park, Kyu-Young Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500232y	journal	September 2014
Environmentally-friendly aqueous Li (or Na)-ion battery with fast electrode kinetics and super-long life Dong, Xiaoli; Chen, Long; Liu, Jingyuan Science Advances, Vol. 2, Issue 1 https://doi.org/10.1126/sciadv.1501038	journal	January 2016
A 3.8-V earth-abundant sodium battery electrode Barpanda, Prabeer; Oyama, Gosuke; Nishimura, Shin-ichi Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5358	journal	July 2014
Electrochemical studies of LiMnPO4 as aqueous rechargeable lithium–ion battery electrode Manjunatha, H.; Venkatesha, T. V.; Suresh, G. S. Journal of Solid State Electrochemistry, Vol. 16, Issue 5 https://doi.org/10.1007/s10008-011-1593-3	journal	November 2011
Carbon coated Na3V2(PO4)3 as novel electrode material for sodium ion batteries Jian, Zelang; Zhao, Liang; Pan, Huilin Electrochemistry Communications, Vol. 14, Issue 1 https://doi.org/10.1016/j.elecom.2011.11.009	journal	January 2012
A Superior Low-Cost Cathode for a Na-Ion Battery Wang, Long; Lu, Yuhao; Liu, Jue Angewandte Chemie, Vol. 125, Issue 7 https://doi.org/10.1002/ange.201206854	journal	January 2013
Improving the energy density of Na ₃ V ₂ (PO ₄ ) ₃ -based positive electrodes through V/Al substitution Lalère, F.; Seznec, V.; Courty, M. Journal of Materials Chemistry A, Vol. 3, Issue 31 https://doi.org/10.1039/C5TA03528G	journal	January 2015
Building better batteries Armand, M.; Tarascon, J.-M. Nature, Vol. 451, Issue 7179, p. 652-657 https://doi.org/10.1038/451652a	journal	February 2008
An aqueous rechargeable sodium ion battery based on a NaMnO ₂ –NaTi ₂ (PO ₄ ) ₃ hybrid system for stationary energy storage Hou, Zhiguo; Li, Xiaona; Liang, Jianwen Journal of Materials Chemistry A, Vol. 3, Issue 4 https://doi.org/10.1039/C4TA06018K	journal	January 2015
Lithium batteries: Status, prospects and future Scrosati, Bruno; Garche, Jürgen Journal of Power Sources, Vol. 195, Issue 9 https://doi.org/10.1016/j.jpowsour.2009.11.048	journal	May 2010
P2-type Nax[Fe1/2Mn1/2]O2 made from earth-abundant elements for rechargeable Na batteries Yabuuchi, Naoaki; Kajiyama, Masataka; Iwatate, Junichi Nature Materials, Vol. 11, Issue 6 https://doi.org/10.1038/nmat3309	journal	April 2012
Mapping of Transition Metal Redox Energies in Phosphates with NASICON Structure by Lithium Intercalation Padhi, A. K. Journal of The Electrochemical Society, Vol. 144, Issue 8 https://doi.org/10.1149/1.1837868	journal	January 1997
Performance of NASICON Symmetric Cell with Ionic Liquid Electrolyte Plashnitsa, Larisa S.; Kobayashi, Eiji; Noguchi, Yoshinori Journal of The Electrochemical Society, Vol. 157, Issue 4 https://doi.org/10.1149/1.3298903	journal	January 2010
A study into the extracted ion number for NASICON structured Na ₃ V ₂ (PO ₄ ) ₃ in sodium-ion batteries Song, Weixin; Cao, Xiaoyu; Wu, Zhengping Phys. Chem. Chem. Phys., Vol. 16, Issue 33 https://doi.org/10.1039/C4CP01821D	journal	January 2014
Understanding the stability of MnPO ₄ Huang, Yiqing; Fang, Jin; Omenya, Fredrick Journal of Materials Chemistry A, Vol. 2, Issue 32 https://doi.org/10.1039/C4TA00434E	journal	January 2014
A Superior Low-Cost Cathode for a Na-Ion Battery Wang, Long; Lu, Yuhao; Liu, Jue Angewandte Chemie International Edition, Vol. 52, Issue 7 https://doi.org/10.1002/anie.201206854	journal	January 2013
High-quality Prussian blue crystals as superior cathode materials for room-temperature sodium-ion batteries You, Ya; Wu, Xing-Long; Yin, Ya-Xia Energy Environ. Sci., Vol. 7, Issue 5 https://doi.org/10.1039/c3ee44004d	journal	January 2014
Ti-substituted tunnel-type Na0.44MnO2 oxide as a negative electrode for aqueous sodium-ion batteries Wang, Yuesheng; Liu, Jue; Lee, Byungju Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7401	journal	March 2015
High-performance aqueous sodium-ion batteries with K0.27MnO2 cathode and their sodium storage mechanism Liu, Yang; Qiao, Yun; Zhang, Wuxing Nano Energy, Vol. 5 https://doi.org/10.1016/j.nanoen.2014.02.010	journal	April 2014
A low-cost and environmentally benign aqueous rechargeable sodium-ion battery based on NaTi2(PO4)3–Na2NiFe(CN)6 intercalation chemistry Wu, Xianyong; Cao, Yuliang; Ai, Xinping Electrochemistry Communications, Vol. 31 https://doi.org/10.1016/j.elecom.2013.03.013	journal	June 2013
A High-Voltage and Ultralong-Life Sodium Full Cell for Stationary Energy Storage Guo, Shaohua; Liu, Pan; Sun, Yang Angewandte Chemie, Vol. 127, Issue 40 https://doi.org/10.1002/ange.201505215	journal	August 2015
Lithium Batteries and Cathode Materials Whittingham, M. Stanley ChemInform, Vol. 35, Issue 50 https://doi.org/10.1002/chin.200450266	journal	December 2004

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Ultrafast Na intercalation chemistry of Na ₂ Ti _3/2 Mn _1/2 (PO ₄ ) ₃ nanodots planted in a carbon matrix as a low cost anode for aqueous sodium-ion batteries Lei, Ping; Liu, Kelu; Wan, Xin Chemical Communications, Vol. 55, Issue 4 https://doi.org/10.1039/c8cc07668e	journal	January 2019
Exploring competitive features of stationary sodium ion batteries for electrochemical energy storage Liu, Tiefeng; Zhang, Yaping; Jiang, Zhanguo Energy & Environmental Science, Vol. 12, Issue 5 https://doi.org/10.1039/c8ee03727b	journal	January 2019
High rate and stable symmetric potassium ion batteries fabricated with flexible electrodes and solid-state electrolytes Lu, Ke; Zhang, Hong; Gao, Siyuan Nanoscale, Vol. 10, Issue 44 https://doi.org/10.1039/c8nr07268j	journal	January 2018
A low-cost Mg ²⁺ /Na ⁺ hybrid aqueous battery Cao, Xi; Wang, Lulu; Chen, Jitao Journal of Materials Chemistry A, Vol. 6, Issue 32 https://doi.org/10.1039/c8ta04930k	journal	January 2018
Cobalt nickel nitride coated by a thin carbon layer anchoring on nitrogen-doped carbon nanotube anodes for high-performance lithium-ion batteries Zou, Rujia; Xu, Mingdong; He, Shu-Ang Journal of Materials Chemistry A, Vol. 6, Issue 40 https://doi.org/10.1039/c8ta08537d	journal	January 2018
The top-down synthesis of sequentially controlled architectures for honeycomb-layered Na ₃ Ni ₂ BiO ₆ towards high-voltage and superior performance cathodes for sodium-ion batteries Wang, Chen; Zhang, Guoming; Qu, Weili Journal of Materials Chemistry A, Vol. 7, Issue 4 https://doi.org/10.1039/c8ta11288f	journal	January 2019
A highly integrated All-manganese battery with oxide nanoparticles supported on the cathode and anode by super-aligned carbon nanotubes Chen, Min; Pan, Zhenghui; Jin, Xiaojing Journal of Materials Chemistry A, Vol. 7, Issue 9 https://doi.org/10.1039/c8ta11415c	journal	January 2019
Self-reductive synthesis of MXene/Na _0.55 Mn _1.4 Ti _0.6 O ₄ hybrids for high-performance symmetric lithium ion batteries Zou, Guodong; Ge, Bingcheng; Zhang, Hao Journal of Materials Chemistry A, Vol. 7, Issue 13 https://doi.org/10.1039/c9ta00744j	journal	January 2019
Delicate lattice modulation enables superior Na storage performance of Na ₃ V ₂ (PO ₄ ) ₃ as both an anode and cathode material for sodium-ion batteries: understanding the role of calcium substitution for vanadium Zhao, Lina; Zhao, Hailei; Du, Zhihong Journal of Materials Chemistry A, Vol. 7, Issue 16 https://doi.org/10.1039/c9ta00869a	journal	January 2019
Faradaic reactions in capacitive deionization for desalination and ion separation Yu, Fei; Wang, Lei; Wang, Ying Journal of Materials Chemistry A, Vol. 7, Issue 27 https://doi.org/10.1039/c9ta01264h	journal	January 2019
Rechargeable aqueous electrolyte batteries: from univalent to multivalent cation chemistry Demir-Cakan, Rezan; Palacin, M. Rosa; Croguennec, Laurence Journal of Materials Chemistry A, Vol. 7, Issue 36 https://doi.org/10.1039/c9ta04735b	journal	January 2019
Rechargeable aqueous hybrid ion batteries: developments and prospects Ao, Huaisheng; Zhao, Yingyue; Zhou, Jie Journal of Materials Chemistry A, Vol. 7, Issue 32 https://doi.org/10.1039/c9ta06433h	journal	January 2019
In Situ SEM Observation of Structured Si/C Anodes Reactions in an Ionic-Liquid-Based Lithium-Ion Battery Shi, Huifeng; Liu, Xianqiang; Wu, Rui Applied Sciences, Vol. 9, Issue 5 https://doi.org/10.3390/app9050956	journal	March 2019
Electrospun NaVPO ₄ F/C Nanofibers as Self-Standing Cathode Material for Ultralong Cycle Life Na-Ion Batteries Jin, Ting; Liu, Yongchang; Li, Yang Advanced Energy Materials, Vol. 7, Issue 15 https://doi.org/10.1002/aenm.201700087	journal	April 2017
Aqueous Batteries Operated at −50 °C Nian, Qingshun; Wang, Jiayue; Liu, Shuang Angewandte Chemie International Edition, Vol. 58, Issue 47 https://doi.org/10.1002/anie.201908913	journal	November 2019
Nanocrystal-Assembled Porous Na ₃ MgTi(PO ₄ ) ₃ Aggregates as Highly Stable Anode for Aqueous Sodium-Ion Batteries Zhang, Fang; Li, Wanfeng; Xiang, Xingde Chemistry - A European Journal, Vol. 23, Issue 52 https://doi.org/10.1002/chem.201703044	journal	August 2017
Conversion Synthesis of Self‐Standing Potassium Zinc Hexacyanoferrate Arrays as Cathodes for High‐Voltage Flexible Aqueous Rechargeable Sodium‐Ion Batteries He, Bing; Man, Ping; Zhang, Qichong Small, Vol. 15, Issue 52 https://doi.org/10.1002/smll.201905115	journal	December 2019
Sodium-ion batteries: present and future Hwang, Jang-Yeon; Myung, Seung-Taek; Sun, Yang-Kook Chemical Society Reviews, Vol. 46, Issue 12 https://doi.org/10.1039/c6cs00776g	journal	January 2017
An ion-conducting SnS–SnS ₂ hybrid coating for commercial activated carbons enabling their use as high performance anodes for sodium-ion batteries Zhang, Si-Wei; Lv, Wei; Qiu, Dong Journal of Materials Chemistry A, Vol. 7, Issue 17 https://doi.org/10.1039/c9ta00599d	journal	January 2019
A Multi-Ion Strategy towards Rechargeable Sodium-Ion Full Batteries with High Working Voltage and Rate Capability Jiang, Chunlei; Fang, Yue; Zhang, Wenyong Angewandte Chemie, Vol. 130, Issue 50 https://doi.org/10.1002/ange.201810575	journal	November 2018
An Abnormal 3.7 Volt O3-Type Sodium-Ion Battery Cathode Wang, Peng-Fei; Xin, Hanshen; Zuo, Tong-Tong Angewandte Chemie International Edition, Vol. 57, Issue 27 https://doi.org/10.1002/anie.201804130	journal	May 2018
A Hydrostable Cathode Material Based on the Layered P2@P3 Composite that Shows Redox Behavior for Copper in High-Rate and Long-Cycling Sodium-Ion Batteries Yan, Zichao; Tang, Liang; Huang, Yangyang Angewandte Chemie International Edition, Vol. 58, Issue 5 https://doi.org/10.1002/anie.201811882	journal	January 2019
In Situ SEM Observation of Structured Si/C Anodes Reactions in an Ionic-Liquid-Based Lithium-Ion Battery Shi, Huifeng; Liu, Xianqiang; Wu, Rui Karlsruhe https://doi.org/10.5445/ir/1000094192	text	January 2019
Electrolytes and Interphases in Sodium-Based Rechargeable Batteries : Recent Advances and Perspectives Eshetu, Gebrekidan Gebresilassie; Elia, Giuseppe Antonio; Armand, Michel RWTH Aachen University https://doi.org/10.18154/rwth-2020-04398	text	January 2020
Electrolytes and Interphases in Sodium-Based Rechargeable Batteries: Recent Advances and Perspectives Eshetu, Gebrekidan Gebresilassie; Elia, Giuseppe Antonio; Armand, Michel Karlsruhe https://doi.org/10.5445/ir/1000118522	text	January 2020
Intermixed Cation-Anion Aqueous Battery Based on an Extremely Fast and Long-Cycling Di-Block Bipyridinium-Naphthalene Diimide Oligomer Perticarari, Sofia; Doizy, Tom; Soudan, Patrick arXiv https://doi.org/10.48550/arxiv.1906.11087	text	January 2019
An Efficient Evaluation of F-doped Polyanion Cathode Materials with Long Cycle Life for Na-Ion Batteries Applications Muruganantham, Rasu; Chiu, Yi-Tang; Yang, Chun-Chuen Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-13718-0	journal	November 2017

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Title: An Aqueous Symmetric Sodium-Ion Battery with NASICON-Structured Na₃MnTi(PO₄)₃