Skip to main content
OSTI.GOVU.S. Department of Energy Office of Scientific and Technical Information
U.S. Department of Energy
Office of Scientific and Technical Information
 

An Aqueous Symmetric Sodium-Ion Battery with NASICON-Structured Na3MnTi(PO4)3

Journal Article · · Angewandte Chemie (International Edition)
 [1];  [2]
  1. Univ. of Texas, Austin, TX (United States). Texas Materials Inst.; DOE/OSTI
  2. Univ. of Texas, Austin, TX (United States). Texas Materials Inst.
+ Show Author Affiliations
A symmetric sodium-ion battery with an aqueous electrolyte is demonstrated; it utilizes the NASICON-structured Na3MnTi(PO4)3 as both the anode and the cathode. The NASICON-structured Na3MnTi(PO4)3 possesses two electrochemically active transition metals with the redox couples of Ti4+/Ti3+ and Mn3+/Mn2+ working on the anode and cathode sides, respectively. The symmetric cell based on this bipolar electrode material exhibits a well-defined voltage plateau centered at about 1.4 V in an aqueous electrolyte with a stable cycle performance and superior rate capability. The advent of aqueous symmetric sodium-ion battery with high safety and low cost may provide a solution for large-scale stationary energy storage.
Research Organization:
Univ. of Texas, Austin, TX (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0005397
OSTI ID:
1533083
Journal Information:
Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 41 Vol. 55; ISSN 1433-7851
Publisher:
WileyCopyright Statement
Country of Publication:
United States
Language:
English

References (58)

Atomic Structure and Kinetics of NASICON Na x V 2 (PO 4 ) 3 Cathode for Sodium-Ion Batteries journal April 2014
Towards High Power High Energy Aqueous Sodium-Ion Batteries: The NaTi 2 (PO 4 ) 3 /Na 0.44 MnO 2 System journal October 2012
The First Report on Excellent Cycling Stability and Superior Rate Capability of Na 3 V 2 (PO 4 ) 3 for Sodium Ion Batteries journal November 2012
A Superior Low-Cost Cathode for a Na-Ion Battery journal January 2013
Natriumionenbatterien für die elektrochemische Energiespeicherung journal February 2015
A High-Voltage and Ultralong-Life Sodium Full Cell for Stationary Energy Storage journal August 2015
Flexible Aqueous Lithium-Ion Battery with High Safety and Large Volumetric Energy Density journal May 2016
A Superior Low-Cost Cathode for a Na-Ion Battery journal January 2013
The Emerging Chemistry of Sodium Ion Batteries for Electrochemical Energy Storage journal February 2015
A High-Voltage and Ultralong-Life Sodium Full Cell for Stationary Energy Storage journal August 2015
Flexible Aqueous Lithium-Ion Battery with High Safety and Large Volumetric Energy Density journal May 2016
Lithium Batteries and Cathode Materials journal December 2004
Energetic Aqueous Rechargeable Sodium-Ion Battery Based on Na 2 CuFe(CN) 6 -NaTi 2 (PO 4 ) 3 Intercalation Chemistry journal January 2014
A Polyionic, Large-Format Energy Storage Device Using an Aqueous Electrolyte and Thick-Format Composite NaTi 2 (PO 4 ) 3 /Activated Carbon Negative Electrodes journal November 2014
A High-Rate and Ultralong-Life Sodium-Ion Battery Based on NaTi 2 (PO 4 ) 3 Nanocubes with Synergistic Coating of Carbon and Rutile TiO 2 journal April 2015
Electrochemical studies of LiMnPO4 as aqueous rechargeable lithium–ion battery electrode journal November 2011
Fast Na+-ion transport in skeleton structures journal February 1976
Lithium insertion into Fe2(SO4)3 frameworks journal May 1989
XPS and ionic conductivity studies on Li2O–Al2O3–(TiO2 or GeO2)–P2O5 glass–ceramics journal November 2000
Carbon coated Na3V2(PO4)3 as novel electrode material for sodium ion batteries journal January 2012
A low-cost and environmentally benign aqueous rechargeable sodium-ion battery based on NaTi2(PO4)3–Na2NiFe(CN)6 intercalation chemistry journal June 2013
Na3Ti2(PO4)3 as a sodium-bearing anode for rechargeable aqueous sodium-ion batteries journal July 2014
Fabrication and performances of all solid-state symmetric sodium battery based on NASICON-related compounds journal July 2013
A High Rate 1.2V Aqueous Sodium-ion Battery Based on All NASICON Structured NaTi2(PO4)3 and Na3V2(PO4)3 journal April 2016
Lithium batteries: Status, prospects and future journal May 2010
Hybrid aqueous battery based on Na3V2(PO4)3/C cathode and zinc anode for potential large-scale energy storage journal March 2016
High-performance aqueous sodium-ion batteries with K0.27MnO2 cathode and their sodium storage mechanism journal April 2014
Mechanisms and Performances of Na 1.5 Fe 0.5 Ti 1.5 (PO 4 ) 3 /C Composite as Electrode Material for Na-Ion Batteries journal November 2015
Highly Reversible and Ultrafast Sodium Storage in NaTi 2 (PO 4 ) 3 Nanoparticles Embedded in Nanocarbon Networks journal December 2015
NASICON-Structured NaTi 2 (PO 4 ) 3 @C Nanocomposite as the Low Operation-Voltage Anode Material for High-Performance Sodium-Ion Batteries journal January 2016
Evolution of Strategies for Modern Rechargeable Batteries journal June 2012
Lithium Batteries and Cathode Materials journal October 2004
Electrochemical Energy Storage for Green Grid journal May 2011
Aqueous Rechargeable Li and Na Ion Batteries journal September 2014
The Li-Ion Rechargeable Battery: A Perspective journal January 2013
A New Water Oxidation Catalyst: Lithium Manganese Pyrophosphate with Tunable Mn Valency journal March 2014
Tunable Reaction Potentials in Open Framework Nanoparticle Battery Electrodes for Grid-Scale Energy Storage journal January 2012
Building better batteries journal February 2008
Full open-framework batteries for stationary energy storage journal January 2014
A 3.8-V earth-abundant sodium battery electrode journal July 2014
Ti-substituted tunnel-type Na0.44MnO2 oxide as a negative electrode for aqueous sodium-ion batteries journal March 2015
P2-type Nax[Fe1/2Mn1/2]O2 made from earth-abundant elements for rechargeable Na batteries journal April 2012
A study into the extracted ion number for NASICON structured Na 3 V 2 (PO 4 ) 3 in sodium-ion batteries journal January 2014
A comprehensive review of sodium layered oxides: powerful cathodes for Na-ion batteries journal January 2015
High-performance symmetric sodium-ion batteries using a new, bipolar O3-type material, Na 0.8 Ni 0.4 Ti 0.6 O 2 journal January 2015
Understanding the stability of MnPO 4 journal January 2014
An aqueous rechargeable sodium ion battery based on a NaMnO 2 –NaTi 2 (PO 4 ) 3 hybrid system for stationary energy storage journal January 2015
Nanostructured alkali cation incorporated δ-MnO 2 cathode materials for aqueous sodium-ion batteries journal January 2015
Improving the energy density of Na 3 V 2 (PO 4 ) 3 -based positive electrodes through V/Al substitution journal January 2015
Aqueous rechargeable lithium batteries as an energy storage system of superfast charging journal January 2013
High-quality Prussian blue crystals as superior cathode materials for room-temperature sodium-ion batteries journal January 2014
Na2FeP2O7 as a positive electrode material for rechargeable aqueous sodium-ion batteries journal January 2014
Environmentally-friendly aqueous Li (or Na)-ion battery with fast electrode kinetics and super-long life journal January 2016
Mapping of Transition Metal Redox Energies in Phosphates with NASICON Structure by Lithium Intercalation journal January 1997
Electrochemical Behavior of Olivine-Type LiMnPO[sub 4] in Aqueous Solutions journal January 2006
Performance of NASICON Symmetric Cell with Ionic Liquid Electrolyte journal January 2010
Electrochemical Properties of NaTi2(PO4)3 Anode for Rechargeable Aqueous Sodium-Ion Batteries journal January 2011
Electrochemical and Thermal Properties of NASICON Structured Na 3 V 2 (PO 4 ) 3 as a Sodium Rechargeable Battery Cathode: A Combined Experimental and Theoretical Study journal January 2012

Cited By (63)

An Efficient Evaluation of F-doped Polyanion Cathode Materials with Long Cycle Life for Na-Ion Batteries Applications journal November 2017
Three Electron Reversible Redox Reaction in Sodium Vanadium Chromium Phosphate as a High‐Energy‐Density Cathode for Sodium‐Ion Batteries journal January 2020
Challenges and Perspectives for NASICON-Type Electrode Materials for Advanced Sodium-Ion Batteries journal June 2017
Polarity-Switchable Symmetric Graphite Batteries with High Energy and High Power Densities journal August 2018
High‐Voltage Aqueous Na‐Ion Battery Enabled by Inert‐Cation‐Assisted Water‐in‐Salt Electrolyte journal November 2019
Electrospun NaVPO 4 F/C Nanofibers as Self-Standing Cathode Material for Ultralong Cycle Life Na-Ion Batteries journal April 2017
Sodium-Ion Batteries: From Academic Research to Practical Commercialization journal September 2017
Progress in Aqueous Rechargeable Sodium-Ion Batteries journal March 2018
Transition Metal Sulfides Based on Graphene for Electrochemical Energy Storage journal February 2018
Rational Architecture Design Enables Superior Na Storage in Greener NASICON-Na 4 MnV(PO 4 ) 3 Cathode journal June 2018
Frogspawn‐Coral‐Like Hollow Sodium Sulfide Nanostructured Cathode for High‐Rate Performance Sodium–Sulfur Batteries journal December 2018
Realizing Three-Electron Redox Reactions in NASICON-Structured Na 3 MnTi(PO 4 ) 3 for Sodium-Ion Batteries journal January 2019
Intermixed Cation–Anion Aqueous Battery Based on an Extremely Fast and Long‐Cycling Di‐Block Bipyridinium–Naphthalene Diimide Oligomer journal May 2019
High Capacity and High‐Rate NASICON‐Na 3.75 V 1.25 Mn 0.75 (PO 4 ) 3 Cathode for Na‐Ion Batteries via Modulating Electronic and Crystal Structures journal December 2019
Electrolytes and Interphases in Sodium‐Based Rechargeable Batteries: Recent Advances and Perspectives journal April 2020
Enhancing Capacity Performance by Utilizing the Redox Chemistry of the Electrolyte in a Dual-Electrolyte Sodium-Ion Battery journal March 2018
An Abnormal 3.7 Volt O3‐Type Sodium‐Ion Battery Cathode journal July 2018
A Multi-Ion Strategy towards Rechargeable Sodium-Ion Full Batteries with High Working Voltage and Rate Capability journal November 2018
A Hydrostable Cathode Material Based on the Layered P2@P3 Composite that Shows Redox Behavior for Copper in High-Rate and Long-Cycling Sodium-Ion Batteries journal January 2019
A Dual‐Ion Organic Symmetric Battery Constructed from Phenazine‐Based Artificial Bipolar Molecules journal April 2019
Aqueous Batteries Operated at −50 °C journal November 2019
Proton Intercalation/De‐Intercalation Dynamics in Vanadium Oxides for Aqueous Aluminum Electrochemical Cells journal January 2020
Enhancing Capacity Performance by Utilizing the Redox Chemistry of the Electrolyte in a Dual-Electrolyte Sodium-Ion Battery journal March 2018
An Abnormal 3.7 Volt O3-Type Sodium-Ion Battery Cathode journal May 2018
A Multi-Ion Strategy towards Rechargeable Sodium-Ion Full Batteries with High Working Voltage and Rate Capability journal November 2018
A Hydrostable Cathode Material Based on the Layered P2@P3 Composite that Shows Redox Behavior for Copper in High-Rate and Long-Cycling Sodium-Ion Batteries journal January 2019
A Dual‐Ion Organic Symmetric Battery Constructed from Phenazine‐Based Artificial Bipolar Molecules journal July 2019
Aqueous Batteries Operated at −50 °C journal November 2019
Proton Intercalation/De‐Intercalation Dynamics in Vanadium Oxides for Aqueous Aluminum Electrochemical Cells journal February 2020
Carbon-Coated Na 2.2 V 1.2 Ti 0.8 (PO 4 ) 3 Cathode with Excellent Cycling Performance for Aqueous Sodium-Ion Batteries journal June 2018
Nanocrystal-Assembled Porous Na 3 MgTi(PO 4 ) 3 Aggregates as Highly Stable Anode for Aqueous Sodium-Ion Batteries journal August 2017
Towards High-Performance Aqueous Sodium-Ion Batteries: Stabilizing the Solid/Liquid Interface for NASICON-Type Na 2 VTi(PO 4 ) 3 using Concentrated Electrolytes journal April 2018
Hollow NaTi 1.9 Sn 0.1 (PO 4 ) 3 @C Nanoparticles for Anodes of Sodium‐Ion Batteries with Superior Rate and Cycling Properties journal April 2019
Functionalized Carboxyl Carbon/NaBOB Composite as Highly Conductive Electrolyte for Sodium Ion Batteries journal August 2018
Conversion Synthesis of Self‐Standing Potassium Zinc Hexacyanoferrate Arrays as Cathodes for High‐Voltage Flexible Aqueous Rechargeable Sodium‐Ion Batteries journal December 2019
Recent Progress of Rechargeable Batteries Using Mild Aqueous Electrolytes journal September 2018
High-performance aqueous symmetric sodium-ion battery using NASICON-structured Na2VTi(PO4)3 journal June 2017
V2O5 Nanospheres with Mixed Vanadium Valences as High Electrochemically Active Aqueous Zinc-Ion Battery Cathode journal March 2019
NASICON-Structured NaTi2(PO4)3 for Sustainable Energy Storage journal May 2019
Building aqueous K-ion batteries for energy storage journal May 2019
Sodium-ion batteries: present and future journal January 2017
Achieving superb sodium storage performance on carbon anodes through an ether-derived solid electrolyte interphase journal January 2017
Cross-linked Na 2 VTi(PO 4 ) 3 @C hierarchical nanofibers as high-performance bi-functional electrodes for symmetric aqueous rechargeable sodium batteries journal January 2017
Coupled X-ray diffraction and electrochemical studies of the mixed Ti/V-containing NASICON: Na 2 TiV(PO 4 ) 3 journal January 2018
Synthesis of uniform hierarchical Na 3 V 1.95 Mn 0.05 (PO 4 ) 2 F 3 @C hollow microspheres as a cathode material for sodium-ion batteries journal January 2018
Ultrafast Na intercalation chemistry of Na 2 Ti 3/2 Mn 1/2 (PO 4 ) 3 nanodots planted in a carbon matrix as a low cost anode for aqueous sodium-ion batteries journal January 2019
Exploring competitive features of stationary sodium ion batteries for electrochemical energy storage journal January 2019
High rate and stable symmetric potassium ion batteries fabricated with flexible electrodes and solid-state electrolytes journal January 2018
A low-cost Mg 2+ /Na + hybrid aqueous battery journal January 2018
Cobalt nickel nitride coated by a thin carbon layer anchoring on nitrogen-doped carbon nanotube anodes for high-performance lithium-ion batteries journal January 2018
The top-down synthesis of sequentially controlled architectures for honeycomb-layered Na 3 Ni 2 BiO 6 towards high-voltage and superior performance cathodes for sodium-ion batteries journal January 2019
A highly integrated All-manganese battery with oxide nanoparticles supported on the cathode and anode by super-aligned carbon nanotubes journal January 2019
An ion-conducting SnS–SnS 2 hybrid coating for commercial activated carbons enabling their use as high performance anodes for sodium-ion batteries journal January 2019
Self-reductive synthesis of MXene/Na 0.55 Mn 1.4 Ti 0.6 O 4 hybrids for high-performance symmetric lithium ion batteries journal January 2019
Delicate lattice modulation enables superior Na storage performance of Na 3 V 2 (PO 4 ) 3 as both an anode and cathode material for sodium-ion batteries: understanding the role of calcium substitution for vanadium journal January 2019
Faradaic reactions in capacitive deionization for desalination and ion separation journal January 2019
Rechargeable aqueous electrolyte batteries: from univalent to multivalent cation chemistry journal January 2019
Rechargeable aqueous hybrid ion batteries: developments and prospects journal January 2019
Electrolytes and Interphases in Sodium-Based Rechargeable Batteries : Recent Advances and Perspectives text January 2020
In Situ SEM Observation of Structured Si/C Anodes Reactions in an Ionic-Liquid-Based Lithium-Ion Battery journal March 2019
Intermixed Cation-Anion Aqueous Battery Based on an Extremely Fast and Long-Cycling Di-Block Bipyridinium-Naphthalene Diimide Oligomer text January 2019
In Situ SEM Observation of Structured Si/C Anodes Reactions in an Ionic-Liquid-Based Lithium-Ion Battery text January 2019
Electrolytes and Interphases in Sodium-Based Rechargeable Batteries: Recent Advances and Perspectives text January 2020

Similar Records

Na 3 MnZr(PO 4 ) 3 : A High-Voltage Cathode for Sodium Batteries
Journal Article · Sat Dec 01 23:00:00 EST 2018 · Journal of the American Chemical Society · OSTI ID:1543730
NASICON Li 1.2 Mg 0.1 Zr 1.9 (PO 4 ) 3 Solid Electrolyte for an All‐Solid‐State Li‐Metal Battery
Journal Article · Sat Sep 12 20:00:00 EDT 2020 · Small Methods · OSTI ID:1804790
NASICON-type Na3Fe2(PO4)3 as a low-cost and high-rate anode material for aqueous sodium-ion batteries
Journal Article · Tue Jul 30 20:00:00 EDT 2019 · Nano Energy · OSTI ID:1561515

Related Subjects

25 ENERGY STORAGE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
aqueous electrolyte
energy storage
sodium-ion battery
symmetric battery