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Title: An Aqueous Symmetric Sodium-Ion Battery with NASICON-Structured Na3MnTi(PO4)3

Abstract

A symmetric sodium-ion battery with an aqueous electrolyte is demonstrated; it utilizes the NASICON-structured Na3MnTi(PO4)3 as both the anode and the cathode. The NASICON-structured Na3MnTi(PO4)3 possesses two electrochemically active transition metals with the redox couples of Ti4+/Ti3+ and Mn3+/Mn2+ working on the anode and cathode sides, respectively. The symmetric cell based on this bipolar electrode material exhibits a well-defined voltage plateau centered at about 1.4 V in an aqueous electrolyte with a stable cycle performance and superior rate capability. The advent of aqueous symmetric sodium-ion battery with high safety and low cost may provide a solution for large-scale stationary energy storage.

Authors:
 [1];  [1]
  1. Univ. of Texas, Austin, TX (United States). Texas Materials Inst.
Publication Date:
Research Org.:
Univ. of Texas, Austin, TX (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1533083
Grant/Contract Number:  
SC0005397
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Angewandte Chemie (International Edition)
Additional Journal Information:
Journal Volume: 55; Journal Issue: 41; Journal ID: ISSN 1433-7851
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 25 ENERGY STORAGE; aqueous electrolyte; energy storage; sodium-ion battery; symmetric battery

Citation Formats

Gao, Hongcai, and Goodenough, John B. An Aqueous Symmetric Sodium-Ion Battery with NASICON-Structured Na3MnTi(PO4)3. United States: N. p., 2016. Web. doi:10.1002/anie.201606508.
Gao, Hongcai, & Goodenough, John B. An Aqueous Symmetric Sodium-Ion Battery with NASICON-Structured Na3MnTi(PO4)3. United States. https://doi.org/10.1002/anie.201606508
Gao, Hongcai, and Goodenough, John B. 2016. "An Aqueous Symmetric Sodium-Ion Battery with NASICON-Structured Na3MnTi(PO4)3". United States. https://doi.org/10.1002/anie.201606508. https://www.osti.gov/servlets/purl/1533083.
@article{osti_1533083,
title = {An Aqueous Symmetric Sodium-Ion Battery with NASICON-Structured Na3MnTi(PO4)3},
author = {Gao, Hongcai and Goodenough, John B.},
abstractNote = {A symmetric sodium-ion battery with an aqueous electrolyte is demonstrated; it utilizes the NASICON-structured Na3MnTi(PO4)3 as both the anode and the cathode. The NASICON-structured Na3MnTi(PO4)3 possesses two electrochemically active transition metals with the redox couples of Ti4+/Ti3+ and Mn3+/Mn2+ working on the anode and cathode sides, respectively. The symmetric cell based on this bipolar electrode material exhibits a well-defined voltage plateau centered at about 1.4 V in an aqueous electrolyte with a stable cycle performance and superior rate capability. The advent of aqueous symmetric sodium-ion battery with high safety and low cost may provide a solution for large-scale stationary energy storage.},
doi = {10.1002/anie.201606508},
url = {https://www.osti.gov/biblio/1533083}, journal = {Angewandte Chemie (International Edition)},
issn = {1433-7851},
number = 41,
volume = 55,
place = {United States},
year = {Tue Sep 13 00:00:00 EDT 2016},
month = {Tue Sep 13 00:00:00 EDT 2016}
}

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Cited by: 197 works
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Works referencing / citing this record:

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