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NASICON-type Na3Fe2(PO4)3 as a low-cost and high-rate anode material for aqueous sodium-ion batteries

Journal Article · · Nano Energy
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  1. Oregon State Univ., Corvallis, OR (United States)
  2. Thorlabs Inc., Jessup, MD (United States)
  3. Argonne National Lab. (ANL), Argonne, IL (United States)
  4. Southern Univ. of Science and Technology, Shenzhen (China)
  5. Beijing Univ. of Chemical Technology, Beijing (China)
  6. Nanyang Technological Univ. (Singapore)
+ Show Author Affiliations
Aqueous sodium-ion batteries are attractive battery alternatives for stationary energy storage due to their inherently low cost and high safety. The development of advanced electrode materials with excellent performance and low cost is crucial for the success of aqueous Na-ion batteries. Albeit the high capacity and stable cycling of the leading anode of NaTi2(PO4)3, the high price of titanium element and the low Na-insertion potential close to the hydrogen evolution reaction may plague its application. Here we introduced a NASICON-type Na3Fe2(PO4)3 as a promising anode alternative for aqueous Na-ion batteries. Synchrotron X-ray diffraction and spectroscopy confirm its phase and atomic structure. Electrochemical characterization and X-ray photoelectron spectroscopy reveal the reversible Na+ insertion in Na3Fe2(PO4)3 due to the Fe3+/Fe2+ redox couple, which renders a specific capacity of ~60 mAh g-1 and excellent cycling of 1000 cycles at 10C rate. A Super high rate of 100C was also achieved for this anode with a capacity retention of 61% after 1000 cycles. In addition, the Na3Fe2(PO4)3 anode is paired with a Prussian white analogue of Na2Mn[Fe(CN)6] into a full cell, exhibiting promising cell performance and material sustainability. Furthermore, our work underlines the importance of fabricating aqueous batteries on the basis of the Earth-abundant, cost-effective, and non-toxic elements.
Research Organization:
Argonne National Lab. (ANL), Argonne, IL (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
National Science Foundation (NSF); USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division
Grant/Contract Number:
AC02-06CH11357
OSTI ID:
1561515
Alternate ID(s):
OSTI ID: 1547081
OSTI ID: 1579514
Journal Information:
Nano Energy, Journal Name: Nano Energy Vol. 64; ISSN 2211-2855
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English

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Figures / Tables (5)

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Related Subjects

25 ENERGY STORAGE
Anode
Aqueous electrolytes
NASICON structure
Na3Fe2(PO4)(3)
Na3Fe2(PO4)3
Sodium-ion batteries