Structure of dysprosium(111) dl-tartrate dimer in aqueous solution
Journal Article
·
· Russian Journal of Coordination Chemistry
OSTI ID:150596
- Kazan State Univ., Tatarstan (Russian Federation); and others
The paramagnetic birefringence method was supplemented by numerical simulation to determine the molar paramagnetic-birefringence constant of the dysprosium dl-tartrate dimer Dy{sub 2}(d-L)(l-L){sup 2-} (I), where d-L{sup 4-} and l-L{sup 4-} are the deprotonated d- and l-tartaric acid molecules, respectively. The structure of the ligand and hydration surroundings of I was modeled by molecular mechanic calculations (the Dashevskii-Pylamovatyi model). It is shown that adequate results can be obtained only if one takes into account the coordination of I to the Na{sup +} ion.
- OSTI ID:
- 150596
- Journal Information:
- Russian Journal of Coordination Chemistry, Vol. 20, Issue 10; Other Information: PBD: Oct 1994; TN: Translated from Koordinatsionnaya Khimiya; 20: No. 10, 794-798(1994)
- Country of Publication:
- United States
- Language:
- English
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