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Crystal Growth of Four Oxovanadium(IV) Tartrates Prepared via a Mild Two-Step Hydrothermal Method: Observation of Spin-Dimer Behavior and Second Harmonic Generation

Journal Article · · Inorganic Chemistry
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  1. Univ. of South Carolina, Columbia, SC (United States)
  2. Univ. of Houston, TX (United States)
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Here, four new oxovanadium(IV) tartrates, namely, A2[(VO)2(C4H4O6)(C4H2O6)(H2O)2]·(H2O)2, where A = Cs, 1, Rb, 2; K2[(VO)2(C4H2O6)2(H2O)2]·(H2O)2, 3; and Na2[(VO)2(C4H4O6)(C4H2O6)(H2O)7]·(H2O)2, 4, were prepared utilizing a two-step, mild hydrothermal route involving l-(+)-tartaric acid as the reducing agent. All four compounds were structurally characterized by single-crystal and powder X-ray diffraction methods and were found to crystallize in the non-centrosymmetric orthorhombic space groups P212121 for 1, 2, and 4 and C2221 for 3. The temperature dependence of the magnetic susceptibility of these compounds was measured, and 1, 2, and 4 were found to be paramagnetic down to 2 K, while 3 was found to exhibit spin-dimer behavior. Compounds 1, 2, and 3 were found to be second harmonic generation active. Furthermore, all compounds were characterized by IR and UV–vis spectroscopies.

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Heterogeneous Functional Materials Center (HeteroFoaM)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; National Science Foundation (NSF)
Grant/Contract Number:
SC0001061
OSTI ID:
1370134
Journal Information:
Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 8 Vol. 54; ISSN 0020-1669
Publisher:
American Chemical Society (ACS)Copyright Statement
Country of Publication:
United States
Language:
English

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Cited By (2)

Application of a mild hydrothermal method to the synthesis of mixed transition-metal( ii )/uranium( iv ) fluorides journal January 2017
A pair of new chiral polyoxovanadates with decent NLO properties journal January 2018

Figures / Tables (13)

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY