Structure of dimeric dysprosium (III) d-tartrate of 2:2 composition in aqueous solution
Journal Article
·
· Russian Journal of General Chemistry
OSTI ID:198131
- Kazan` State Univ. (Kazakhstan); and others
The molar constant of paramagnetic birefringence of dimeric dysprosium d-tartrate Dy{sub 2}(d-L){sup 2{minus}}{sub 2} (d-L{sup 4{minus}} is a deprotonated molecule of tartaric acid) was determined experimentally and by mathematical simulation. The structures of the ligand and hydrate environment in Dy{sub 2}(d-L){sup 2{minus}}{sub 2} were simulated by the molecular mechanics method (Dashevskii-Plyamovatyi model). Results consistent with the experimental data can be obtained only when coordination of Na{sup +} is taken into account. 6 refs., 4 figs., 8 tabs.
- OSTI ID:
- 198131
- Journal Information:
- Russian Journal of General Chemistry, Journal Name: Russian Journal of General Chemistry Journal Issue: 7 Vol. 64; ISSN RJGCEK
- Country of Publication:
- United States
- Language:
- English
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