Structure of dysprosium(111) dl-tartrate dimer in aqueous solution
Journal Article
·
· Russian Journal of Coordination Chemistry
OSTI ID:150596
- Kazan State Univ., Tatarstan (Russian Federation); and others
The paramagnetic birefringence method was supplemented by numerical simulation to determine the molar paramagnetic-birefringence constant of the dysprosium dl-tartrate dimer Dy{sub 2}(d-L)(l-L){sup 2-} (I), where d-L{sup 4-} and l-L{sup 4-} are the deprotonated d- and l-tartaric acid molecules, respectively. The structure of the ligand and hydration surroundings of I was modeled by molecular mechanic calculations (the Dashevskii-Pylamovatyi model). It is shown that adequate results can be obtained only if one takes into account the coordination of I to the Na{sup +} ion.
- OSTI ID:
- 150596
- Journal Information:
- Russian Journal of Coordination Chemistry, Journal Name: Russian Journal of Coordination Chemistry Journal Issue: 10 Vol. 20; ISSN RJCCEY
- Country of Publication:
- United States
- Language:
- English
Similar Records
Structure of dimeric dysprosium (III) d-tartrate of 2:2 composition in aqueous solution
TARTRATE COMPLEXES OF THE RARE-EARTH ELEMENTS. I. THE d-, dl-, AND meso- TARTRATE COMPLEXES OF Tb AND Eu
A new perspective on vanadyl tartrate dimers. Part II. Structure and spectroscopic properties of calcium vanadyl tartrate tetrahydrate
Journal Article
·
Mon Dec 19 23:00:00 EST 1994
· Russian Journal of General Chemistry
·
OSTI ID:198131
TARTRATE COMPLEXES OF THE RARE-EARTH ELEMENTS. I. THE d-, dl-, AND meso- TARTRATE COMPLEXES OF Tb AND Eu
Journal Article
·
Tue Oct 01 00:00:00 EDT 1963
· Canadian Journal of Chemistry (Canada)
·
OSTI ID:4657298
A new perspective on vanadyl tartrate dimers. Part II. Structure and spectroscopic properties of calcium vanadyl tartrate tetrahydrate
Journal Article
·
Thu Dec 30 23:00:00 EST 1993
· Journal of Coordination Chemistry
·
OSTI ID:75724