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SYNCHROTRON X-RAY MICROPROBE AND COMPUTED MICROTOMOGRAPHY FOR CHARACTERIZATION OF NANOCATALYSTS.

Conference ·
OSTI ID:15015226
Gas-to-liquids (GTL) is a viable pathway for synthesis of clean fuels from natural gas. One of the attractive synthesis options is the Fischer-Tropsch (F-T) method using an iron catalyst to yield a broad range of hydrocarbons. We collected catalyst samples during three separate F-T runs that utilized nanophase (mean particle diameter (MPD): 3 nm and 20-80 nm) and micrometer-sized (32.5 ? m) Fe{sub 2}O{sub 3} that served as catalyst precursors. The collected samples were characterized with micro x-ray fluorescence and computed Microtomography at the National Synchrotron Light Source (NSLS). Results found with two different measurement techniques indicated that there was heterogeneity on a spatial scale corresponding to volumes of roughly 10{sup 3} {micro}m{sup 3}.
Research Organization:
BROOKHAVEN NATIONAL LABORATORY (US)
Sponsoring Organization:
DOE/SC (US)
DOE Contract Number:
AC02-98CH10886
OSTI ID:
15015226
Report Number(s):
BNL--72460-2004-CP; KC0303010
Country of Publication:
United States
Language:
English

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