In Operando Analysis of Diffusion in Porous Metal‐Organic Framework Catalysts

Gao, Wen‐Yang; Cardenal, Ashley D.; Wang, Chen‐Hao; Powers, David C.

doi:10.1002/chem.201804490

Title: In Operando Analysis of Diffusion in Porous Metal‐Organic Framework Catalysts

Journal Article · Fri Dec 21 00:00:00 EST 2018 · Chemistry - A European Journal

DOI:https://doi.org/10.1002/chem.201804490· OSTI ID:1493375

Gao, Wen‐Yang ^[1]; Cardenal, Ashley D. ^[1]; Wang, Chen‐Hao ^[1];

^[1]

Department of Chemistry Texas A&,M University 3255 TAMU College Station TX 77843 USA

Abstract The potential to exert atomistic control over the structure of site‐isolated catalyst sites, as well as the topology and chemical environment of interstitial pore spaces, has inspired efforts to apply porous metal‐organic frameworks (MOFs) as catalysts for fine chemical synthesis. In analogy to enzyme‐catalyzed reactions, MOF catalysts have been proposed as platforms in which substrate confinement could be used to achieve chemo‐ and stereoselectivities that are orthogonal to solution‐phase catalysts. In order to leverage the tunable pore topology of MOFs to impact catalyst selectivity, catalysis must proceed at interstitial catalyst sites, rather than at solvent‐exposed interfacial sites. This Minireview addresses challenges inherent to interstitial MOF catalysis by 1) describing the diffusional processes available to sorbates in porous materials, 2) discussing critical factors that impact the diffusion rate of substrates in porous materials, and 3) presenting in operando experimental strategies to assess the relative rates of substrate diffusion and catalyst turnover in MOF catalysis. It is anticipated that the continued development of in operando tools to evaluate substrate diffusion in porous catalysts will advance the application of these materials in fine chemical synthesis.

View Accepted Manuscript (Publisher)

Cite

Export

Save

Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0018977

OSTI ID:: 1493375

Journal Information:: Chemistry - A European Journal, Journal Name: Chemistry - A European Journal Vol. 25 Journal Issue: 14; ISSN 0947-6539

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

Citation Metrics:

Cited by: 40 works

Citation information provided by
Web of Science

References (117)

Selective Surface and Near-Surface Modification of a Noncatenated, Catalytically Active Metal-Organic Framework Material Based on Mn(salen) Struts Shultz, Abraham M.; Farha, Omar K.; Adhikari, Debashis Inorganic Chemistry, Vol. 50, Issue 8 https://doi.org/10.1021/ic101952y	journal	April 2011
Sintering-Resistant Single-Site Nickel Catalyst Supported by Metal–Organic Framework Li, Zhanyong; Schweitzer, Neil M.; League, Aaron B. Journal of the American Chemical Society, Vol. 138, Issue 6 https://doi.org/10.1021/jacs.5b12515	journal	February 2016
Diffusion in Nanoporous Materials Kärger, Jörg; Ruthven, Douglas M.; Theodorou, Doros N. https://doi.org/10.1002/9783527651276	book	April 2012
Revisiting Anisotropic Diffusion of Carbon Dioxide in the Metal–Organic Framework Zn ₂ (dobpdc) Forse, Alexander C.; Altobelli, Stephen A.; Benders, Stefan The Journal of Physical Chemistry C, Vol. 122, Issue 27 https://doi.org/10.1021/acs.jpcc.8b02843	journal	June 2018
Molecular Encapsulation beyond the Aperture Size Limit through Dissociative Linker Exchange in Metal–Organic Framework Crystals Morabito, Joseph V.; Chou, Lien-Yang; Li, Zhehui Journal of the American Chemical Society, Vol. 136, Issue 36 https://doi.org/10.1021/ja5054779	journal	August 2014
Adsorption and Diffusion Phenomena in Crystal Size Engineered ZIF-8 MOF Tanaka, Shunsuke; Fujita, Kosuke; Miyake, Yoshikazu The Journal of Physical Chemistry C, Vol. 119, Issue 51 https://doi.org/10.1021/acs.jpcc.5b09520	journal	December 2015
Confinement Effects on the Benzene Orientational Structure Falkowska, Marta; Bowron, Daniel T.; Manyar, Haresh Angewandte Chemie, Vol. 130, Issue 17 https://doi.org/10.1002/ange.201713115	journal	March 2018
Diffusion in 4A zeolite. Study of the effect of crystal size Yucel, Hayrettin; Ruthven, Douglas M. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 76, Issue 0 https://doi.org/10.1039/f19807600060	journal	January 1980
Transport Diffusivity of CO2 in the Highly Flexible Metal-Organic Framework MIL-53(Cr) Salles, Fabrice; Jobic, Hervé; Ghoufi, Aziz Angewandte Chemie International Edition, Vol. 48, Issue 44 https://doi.org/10.1002/anie.200902998	journal	September 2009
Zeolitic Imidazolate Frameworks for Kinetic Separation of Propane and Propene Li, Kunhao; Olson, David H.; Seidel, Jonathan Journal of the American Chemical Society, Vol. 131, Issue 30 https://doi.org/10.1021/ja9039983	journal	August 2009
Tuning Pore Size in Square-Lattice Coordination Networks for Size-Selective Sieving of CO ₂ Chen, Kai-Jie; Madden, David G.; Pham, Tony Angewandte Chemie, Vol. 128, Issue 35 https://doi.org/10.1002/ange.201603934	journal	July 2016
Surface Modification of Two‐Dimensional Metal–Organic Layers Creates Biomimetic Catalytic Microenvironments for Selective Oxidation Shi, Wenjie; Cao, Lingyun; Zhang, Hua Angewandte Chemie, Vol. 129, Issue 33 https://doi.org/10.1002/ange.201703675	journal	June 2017
Exploring the nature of surface barriers on MOF Zn(tbip) by applying IR microscopy in high temporal and spatial resolution Chmelik, Christian; Hibbe, Florian; Tzoulaki, Despina Microporous and Mesoporous Materials, Vol. 129, Issue 3 https://doi.org/10.1016/j.micromeso.2009.06.006	journal	April 2010
Retikuläre Chemie metall‐organischer Polyeder Tranchemontagne, David J.; Ni, Zheng; O'Keeffe, Michael Angewandte Chemie, Vol. 120, Issue 28 https://doi.org/10.1002/ange.200705008	journal	June 2008
Self-assembly of tetravalent Goldberg polyhedra from 144 small components Fujita, Daishi; Ueda, Yoshihiro; Sato, Sota Nature, Vol. 540, Issue 7634 https://doi.org/10.1038/nature20771	journal	December 2016
Selective Dimerization of Ethylene to 1-Butene with a Porous Catalyst Metzger, Eric D.; Brozek, Carl K.; Comito, Robert J. ACS Central Science, Vol. 2, Issue 3 https://doi.org/10.1021/acscentsci.6b00012	journal	February 2016
Continuous-Flow Production of Succinic Anhydrides via Catalytic β-Lactone Carbonylation by Co(CO) ₄ ⊂Cr-MIL-101 Park, Hoyoung D.; Dincă, Mircea; Román-Leshkov, Yuriy Journal of the American Chemical Society, Vol. 140, Issue 34 https://doi.org/10.1021/jacs.8b05948	journal	July 2018
Porous Metal-Organic Frameworks: Promising Materials for Methane Storage Li, Bin; Wen, Hui-Min; Zhou, Wei Chem, Vol. 1, Issue 4 https://doi.org/10.1016/j.chempr.2016.09.009	journal	October 2016
Oxidation of ethane to ethanol by N2O in a metal–organic framework with coordinatively unsaturated iron(II) sites Xiao, Dianne J.; Bloch, Eric D.; Mason, Jarad A. Nature Chemistry, Vol. 6, Issue 7 https://doi.org/10.1038/nchem.1956	journal	May 2014
Yolk–Shell Nanocrystal@ZIF-8 Nanostructures for Gas-Phase Heterogeneous Catalysis with Selectivity Control Kuo, Chun-Hong; Tang, Yang; Chou, Lien-Yang Journal of the American Chemical Society, Vol. 134, Issue 35 https://doi.org/10.1021/ja306869j	journal	August 2012
A Perspective on the Synthesis, Purification, and Characterization of Porous Organic Cages Briggs, Michael E.; Cooper, Andrew I. Chemistry of Materials, Vol. 29, Issue 1 https://doi.org/10.1021/acs.chemmater.6b02903	journal	September 2016
Anion Exchange Renders Hydrophobic Capsules and Cargoes Water-Soluble Percástegui, Edmundo G.; Mosquera, Jesús; Nitschke, Jonathan R. Angewandte Chemie International Edition, Vol. 56, Issue 31 https://doi.org/10.1002/anie.201705093	journal	June 2017
Probing Substrate Diffusion in Interstitial MOF Chemistry with Kinetic Isotope Effects Wang, Chen-Hao; Das, Anuvab; Gao, Wen-Yang Angewandte Chemie, Vol. 130, Issue 14 https://doi.org/10.1002/ange.201713244	journal	March 2018
The Nature of Surface Barriers on Nanoporous Solids Explored by Microimaging of Transient Guest Distributions Hibbe, Florian; Chmelik, Christian; Heinke, Lars Journal of the American Chemical Society, Vol. 133, Issue 9 https://doi.org/10.1021/ja108625z	journal	March 2011
Metal–Organic Frameworks Invert Molecular Reactivity: Lewis Acidic Phosphonium Zwitterions Catalyze the Aldol-Tishchenko Reaction Bauer, Gerald; Ongari, Daniele; Xu, Xiaoying Journal of the American Chemical Society, Vol. 139, Issue 50 https://doi.org/10.1021/jacs.7b10928	journal	December 2017
Enantiopure Water-Soluble [Fe ₄ L ₆ ] Cages: Host-Guest Chemistry and Catalytic Activity Bolliger, Jeanne L.; Belenguer, Ana M.; Nitschke, Jonathan R. Angewandte Chemie International Edition, Vol. 52, Issue 31 https://doi.org/10.1002/anie.201302136	journal	June 2013
From Microporous to Mesoporous Molecular Sieve Materials and Their Use in Catalysis Corma, Avelino Chemical Reviews, Vol. 97, Issue 6, p. 2373-2420 https://doi.org/10.1021/cr960406n	journal	October 1997
Enantiomerenreine wasserlösliche [Fe ₄ L ₆ ]-Käfigverbindungen: Wirt-Gast-Chemie und katalytische Aktivität Bolliger, Jeanne L.; Belenguer, Ana M.; Nitschke, Jonathan R. Angewandte Chemie, Vol. 125, Issue 31 https://doi.org/10.1002/ange.201302136	journal	June 2013
Transport into Metal-Organic Frameworks from Solution Is Not Purely Diffusive Han, Shuangbing; Hermans, Thomas M.; Fuller, Patrick E. Angewandte Chemie, Vol. 124, Issue 11 https://doi.org/10.1002/ange.201108492	journal	February 2012
Kinetic Separation of Propene and Propane in Metal−Organic Frameworks: Controlling Diffusion Rates in Plate-Shaped Crystals via Tuning of Pore Apertures and Crystallite Aspect Ratios Lee, Chang Yeon; Bae, Youn-Sang; Jeong, Nak Cheon Journal of the American Chemical Society, Vol. 133, Issue 14 https://doi.org/10.1021/ja200553m	journal	April 2011
Application of Interference Microscopy and IR Microscopy for Characterizing and Investigating Mass Transport in Nanoporous Materials Heinke, L.; Chmelik, C.; Kortunov, P. Chemical Engineering & Technology, Vol. 30, Issue 8 https://doi.org/10.1002/ceat.200700093	journal	August 2007
Diffusion-Controlled Luminescence Quenching in Metal−Organic Frameworks Wang, Cheng; Lin, Wenbin Journal of the American Chemical Society, Vol. 133, Issue 12 https://doi.org/10.1021/ja111197d	journal	March 2011
Evaluating metal–organic frameworks for natural gas storage Mason, Jarad A.; Veenstra, Mike; Long, Jeffrey R. Chemical Science, Vol. 5, Issue 1, p. 32-51 https://doi.org/10.1039/C3SC52633J	journal	January 2014
Heterogeneous Catalytic Oxidation by MFU-1: A Cobalt(II)-Containing Metal-Organic Framework Tonigold, Markus; Lu, Ying; Bredenkötter, Björn Angewandte Chemie International Edition, Vol. 48, Issue 41 https://doi.org/10.1002/anie.200901241	journal	September 2009
Adsorption and Diffusion of Carbon Dioxide on Metal−Organic Framework (MOF-5) Zhao, Zhenxia; Li, Zhong; Lin, Y. S. Industrial & Engineering Chemistry Research, Vol. 48, Issue 22 https://doi.org/10.1021/ie900665f	journal	November 2009
Modulating the Performance of an Asymmetric Organocatalyst by Tuning Its Spatial Environment in a Metal–Organic Framework Liu, Lujia; Zhou, Tian-You; Telfer, Shane G. Journal of the American Chemical Society, Vol. 139, Issue 39 https://doi.org/10.1021/jacs.7b07921	journal	September 2017
Adsorption and Diffusion of Benzene on Chromium-Based Metal Organic Framework MIL-101 Synthesized by Microwave Irradiation Zhao, Zhenxia; Li, Xuemei; Huang, Sisi Industrial & Engineering Chemistry Research, Vol. 50, Issue 4 https://doi.org/10.1021/ie101414n	journal	February 2011
Direct assessment of molecular transport in mordenite: dominance of surface resistances Zhang, Lei; Chmelik, Christian; van Laak, Adri N. C. Chemical Communications, Issue 42 https://doi.org/10.1039/b914391b	journal	January 2009
One-Step Synthesis of Hybrid Core-Shell Metal-Organic Frameworks Yang, Xinyu; Yuan, Shuai; Zou, Lanfang Angewandte Chemie, Vol. 130, Issue 15 https://doi.org/10.1002/ange.201710019	journal	March 2018
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage Eddaoudi, Mohamed; Kim, Jaheon; Rosi, Nathaniel Science, Vol. 295, Issue 5554, p. 469-472 https://doi.org/10.1126/science.1067208	journal	January 2002
Carbon Dioxide Capture in Metal–Organic Frameworks Sumida, Kenji; Rogow, David L.; Mason, Jarad A. Chemical Reviews, Vol. 112, Issue 2, p. 724-781 https://doi.org/10.1021/cr2003272	journal	September 2011
Transport in nanoporösen Materialien, einschließlich MOFs: über die Anwendbarkeit der Fickschen Gesetze Titze, Tobias; Lauerer, Alexander; Heinke, Lars Angewandte Chemie, Vol. 127, Issue 48 https://doi.org/10.1002/ange.201506954	journal	October 2015
Metal organic framework-mediated synthesis of highly active and stable Fischer-Tropsch catalysts Santos, Vera P.; Wezendonk, Tim A.; Jaén, Juan José Delgado Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7451	journal	March 2015
Industrial Catalysis Wijngaarden, R. J.; Kronberg, A.; Westerterp, K. R. https://doi.org/10.1002/9783527611966	book	July 1998
Permeable Self-Assembled Molecular Containers for Catalyst Isolation Enabling Two-Step Cascade Reactions Ueda, Yoshihiro; Ito, Hiroaki; Fujita, Daishi Journal of the American Chemical Society, Vol. 139, Issue 17 https://doi.org/10.1021/jacs.7b02745	journal	April 2017
Multiscale Approach to the Structural Study of Water Confined in MCM41 Mancinelli, R.; Imberti, S.; Soper, A. K. The Journal of Physical Chemistry B, Vol. 113, Issue 50 https://doi.org/10.1021/jp9062109	journal	December 2009
Metal–Organic Frameworks for Separations Li, Jian-Rong; Sculley, Julian; Zhou, Hong-Cai Chemical Reviews, Vol. 112, Issue 2, p. 869-932 https://doi.org/10.1021/cr200190s	journal	September 2011
Diffusion in 5A zeolite. Study of the effect of crystal size Yucel, Hayrettin; Ruthven, Douglas M. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 76, Issue 0 https://doi.org/10.1039/f19807600071	journal	January 1980
Intracrystalline diffusion in Metal Organic Framework during heterogeneous catalysis: Influence of particle size on the activity of MIL-100 (Fe) for oxidation reactions Dhakshinamoorthy, Amarajothi; Alvaro, Mercedes; Hwang, Young Kyu Dalton Transactions, Vol. 40, Issue 40 https://doi.org/10.1039/c1dt10826c	journal	January 2011
A Homochiral Metal–Organic Framework as an Effective Asymmetric Catalyst for Cyanohydrin Synthesis Mo, Ke; Yang, Yuhua; Cui, Yong Journal of the American Chemical Society, Vol. 136, Issue 5 https://doi.org/10.1021/ja411887c	journal	January 2014
Describing the Diffusion of Guest Molecules Inside Porous Structures Krishna, Rajamani The Journal of Physical Chemistry C, Vol. 113, Issue 46 https://doi.org/10.1021/jp906879d	journal	September 2009
Self-diffusion of propane and propylene in 5A and 13X zeolite crystals studied by the tracer ZLC method Brandani, Stefano; Hufton, Jeffrey; Ruthven, Douglas Zeolites, Vol. 15, Issue 7 https://doi.org/10.1016/0144-2449(95)00042-5	journal	October 1995
Zeolite-based catalysts for chemicals synthesis Davis, M. E. Microporous and Mesoporous Materials, Vol. 21, Issue 4-6 https://doi.org/10.1016/S1387-1811(98)00007-9	journal	May 1998
cis-Decalin oxidation as a stereochemical probe of in-MOF versus on-MOF catalysis Cardenal, Ashley D.; Jeong Park, Hye; Chalker, Cody J. Chemical Communications, Vol. 53, Issue 53 https://doi.org/10.1039/C7CC02570J	journal	January 2017
Reticular Chemistry of Metal–Organic Polyhedra Tranchemontagne, David J.; Ni, Zheng; O'Keeffe, Michael Angewandte Chemie International Edition, Vol. 47, Issue 28, p. 5136-5147 https://doi.org/10.1002/anie.200705008	journal	June 2008
One-Step Synthesis of Hybrid Core-Shell Metal-Organic Frameworks Yang, Xinyu; Yuan, Shuai; Zou, Lanfang Angewandte Chemie International Edition, Vol. 57, Issue 15 https://doi.org/10.1002/anie.201710019	journal	March 2018
Heterogene Oxidationskatalyse durch MFU-1, eine Cobalt(II)-haltige Metall-organische Gerüststruktur Tonigold, Markus; Lu, Ying; Bredenkötter, Björn Angewandte Chemie, Vol. 121, Issue 41 https://doi.org/10.1002/ange.200901241	journal	September 2009
Gas Storage and Diffusion through Nanocages and Windows in Porous Metal–Organic Framework Cu ₂ (2,3,5,6-tetramethylbenzene-1,4-diisophthalate)(H ₂ O) ₂ Li, Liangjun; Bell, Jon G.; Tang, Sifu Chemistry of Materials, Vol. 26, Issue 16 https://doi.org/10.1021/cm403697m	journal	August 2014
Ligand-Based Phase Control in Porous Molecular Assemblies Barreda, Omar; Bannwart, Gianluca; Yap, Glenn P. A. ACS Applied Materials & Interfaces, Vol. 10, Issue 14 https://doi.org/10.1021/acsami.8b02015	journal	March 2018
Probing Substrate Diffusion in Interstitial MOF Chemistry with Kinetic Isotope Effects Wang, Chen-Hao; Das, Anuvab; Gao, Wen-Yang Angewandte Chemie International Edition, Vol. 57, Issue 14 https://doi.org/10.1002/anie.201713244	journal	March 2018
Methane Oxidation to Methanol Catalyzed by Cu-Oxo Clusters Stabilized in NU-1000 Metal–Organic Framework Ikuno, Takaaki; Zheng, Jian; Vjunov, Aleksei Journal of the American Chemical Society, Vol. 139, Issue 30 https://doi.org/10.1021/jacs.7b02936	journal	July 2017
Transport into Metal-Organic Frameworks from Solution Is Not Purely Diffusive Han, Shuangbing; Hermans, Thomas M.; Fuller, Patrick E. Angewandte Chemie International Edition, Vol. 51, Issue 11 https://doi.org/10.1002/anie.201108492	journal	February 2012
Porous organic cages: soluble, modular and molecular pores Hasell, Tom; Cooper, Andrew I. Nature Reviews Materials, Vol. 1, Issue 9 https://doi.org/10.1038/natrevmats.2016.53	journal	July 2016
Spin Diffusion Measurements: Spin Echoes in the Presence of a Time‐Dependent Field Gradient Stejskal, E. O.; Tanner, J. E. The Journal of Chemical Physics, Vol. 42, Issue 1 https://doi.org/10.1063/1.1695690	journal	January 1965
Adsorption Equilibrium and Kinetics of CO ₂ on Chromium Terephthalate MIL-101 Zhang, Zhijuan; Huang, Sisi; Xian, Shikai Energy & Fuels, Vol. 25, Issue 2 https://doi.org/10.1021/ef101548g	journal	February 2011
Multifunctional metal–organic framework catalysts: synergistic catalysis and tandem reactions Huang, Yuan-Biao; Liang, Jun; Wang, Xu-Sheng Chemical Society Reviews, Vol. 46, Issue 1 https://doi.org/10.1039/C6CS00250A	journal	January 2017
Cavity-induced enantioselectivity reversal in a chiral metal–organic framework Brønsted acid catalyst Zheng, Min; Liu, Yan; Wang, Cheng Chemical Science, Vol. 3, Issue 8 https://doi.org/10.1039/c2sc20379k	journal	January 2012
Anion Exchange Renders Hydrophobic Capsules and Cargoes Water-Soluble Percástegui, Edmundo G.; Mosquera, Jesús; Nitschke, Jonathan R. Angewandte Chemie, Vol. 129, Issue 31 https://doi.org/10.1002/ange.201705093	journal	June 2017
Metal–Organic Frameworks (MOFs) Zhou, Hong-Cai “Joe”; Kitagawa, Susumu Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C4CS90059F	journal	January 2014
Simultaneous Measurement of Self- and Transport Diffusivities in Zeolites Jobic, H.; Kärger, J.; Bée, M. Physical Review Letters, Vol. 82, Issue 21 https://doi.org/10.1103/PhysRevLett.82.4260	journal	May 1999
Diffusion of Xylene Isomers in the MIL-47(V) MOF Material: A Synergic Combination of Computational and Experimental Tools Rives, S.; Jobic, H.; Kolokolov, D. I. The Journal of Physical Chemistry C, Vol. 117, Issue 12 https://doi.org/10.1021/jp400507w	journal	March 2013
Supramolecular Catalysis in Metal–Ligand Cluster Hosts Brown, Casey J.; Toste, F. Dean; Bergman, Robert G. Chemical Reviews, Vol. 115, Issue 9 https://doi.org/10.1021/cr4001226	journal	April 2015
Enzymelike Catalysis of the Nazarov Cyclization by Supramolecular Encapsulation Hastings, Courtney J.; Pluth, Michael D.; Bergman, Robert G. Journal of the American Chemical Society, Vol. 132, Issue 20 https://doi.org/10.1021/ja102633e	journal	May 2010
Catalytic test reactions for the evaluation of hierarchical zeolites Hartmann, Martin; Machoke, Albert Gonche; Schwieger, Wilhelm Chemical Society Reviews, Vol. 45, Issue 12 https://doi.org/10.1039/C5CS00935A	journal	January 2016
Confinement Effects on the Benzene Orientational Structure Falkowska, Marta; Bowron, Daniel T.; Manyar, Haresh Angewandte Chemie International Edition, Vol. 57, Issue 17 https://doi.org/10.1002/anie.201713115	journal	March 2018
Tracer-exchange experiments with positron emission profiling: diffusion in zeolites Schumacher, R. R.; Anderson, B. G.; Noordhoek, N. J. Microporous and Mesoporous Materials, Vol. 35-36 https://doi.org/10.1016/S1387-1811(99)00230-9	journal	April 2000
Nanoporous Glass as a Model System for a Consistency Check of the Different Techniques of Diffusion Measurement Chmelik, Christian; Enke, Dirk; Galvosas, Petrik ChemPhysChem, Vol. 12, Issue 6 https://doi.org/10.1002/cphc.201100072	journal	March 2011
Transport Diffusivity of CO2 in the Highly Flexible Metal-Organic Framework MIL-53(Cr) Salles, Fabrice; Jobic, Hervé; Ghoufi, Aziz Angewandte Chemie, Vol. 121, Issue 44 https://doi.org/10.1002/ange.200902998	journal	September 2009
Fluid catalytic cracking: recent developments on the grand old lady of zeolite catalysis Vogt, E. T. C.; Weckhuysen, B. M. Chemical Society Reviews, Vol. 44, Issue 20 https://doi.org/10.1039/C5CS00376H	journal	January 2015
Assessing Guest Diffusivities in Porous Hosts from Transient Concentration Profiles Heinke, Lars; Tzoulaki, Despina; Chmelik, Christian Physical Review Letters, Vol. 102, Issue 6 https://doi.org/10.1103/PhysRevLett.102.065901	journal	February 2009
Surface Modification of Two-Dimensional Metal-Organic Layers Creates Biomimetic Catalytic Microenvironments for Selective Oxidation Shi, Wenjie; Cao, Lingyun; Zhang, Hua Angewandte Chemie International Edition, Vol. 56, Issue 33 https://doi.org/10.1002/anie.201703675	journal	June 2017
Transport in Nanoporous Materials Including MOFs: The Applicability of Fick’s Laws Titze, Tobias; Lauerer, Alexander; Heinke, Lars Angewandte Chemie International Edition, Vol. 54, Issue 48 https://doi.org/10.1002/anie.201506954	journal	October 2015
Tuning Pore Size in Square-Lattice Coordination Networks for Size-Selective Sieving of CO ₂ Chen, Kai-Jie; Madden, David G.; Pham, Tony Angewandte Chemie International Edition, Vol. 55, Issue 35 https://doi.org/10.1002/anie.201603934	journal	July 2016
The surface barrier phenomenon at the loading of metal-organic frameworks Heinke, Lars; Gu, Zhigang; Wöll, Christof Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5562	journal	July 2014
Single-Site Heterogeneous Catalysts for Olefin Polymerization Enabled by Cation Exchange in a Metal-Organic Framework Comito, Robert J.; Fritzsching, Keith J.; Sundell, Benjamin J. Journal of the American Chemical Society, Vol. 138, Issue 32 https://doi.org/10.1021/jacs.6b05200	journal	August 2016
Diffusion in porous crystalline materials Krishna, Rajamani Chemical Society Reviews, Vol. 41, Issue 8 https://doi.org/10.1039/c2cs15284c	journal	January 2012
Diffusion of CO ₂ in Large Crystals of Cu-BTC MOF Tovar, Trenton M.; Zhao, Junjie; Nunn, William T. Journal of the American Chemical Society, Vol. 138, Issue 36 https://doi.org/10.1021/jacs.6b05930	journal	September 2016
Surface functionalization of metal–organic polyhedron for homogeneous cyclopropanation catalysis Lu, Weigang; Yuan, Daqiang; Yakovenko, Andrey Chemical Communications, Vol. 47, Issue 17 https://doi.org/10.1039/c1cc00030f	journal	January 2011
Intracrystalline Diffusivities and Surface Permeabilities Deduced from Transient Concentration Profiles: Methanol in MOF Manganese Formate Kortunov, Pavel V.; Heinke, Lars; Arnold, Mirko Journal of the American Chemical Society, Vol. 129, Issue 25 https://doi.org/10.1021/ja071265h	journal	June 2007
Diffusion in nanoporous materials: fundamental principles, insights and challenges Kärger, Jörg; Ruthven, Douglas M. New Journal of Chemistry, Vol. 40, Issue 5 https://doi.org/10.1039/C5NJ02836A	journal	January 2016
Cp* Iridium Precatalysts for Selective C–H Oxidation via Direct Oxygen Insertion: A Joint Experimental/Computational Study Zhou, Meng; Balcells, David; Parent, Alexander R. ACS Catalysis, Vol. 2, Issue 2 https://doi.org/10.1021/cs2005899	journal	January 2012
Applications of metal–organic frameworks in heterogeneous supramolecular catalysis Liu, Jiewei; Chen, Lianfen; Cui, Hao Chemical Society Reviews, Vol. 43, Issue 16, p. 6011-6061 https://doi.org/10.1039/C4CS00094C	journal	January 2014
Transport Phenomena in Nanoporous Materials Kärger, Jörg ChemPhysChem, Vol. 16, Issue 1 https://doi.org/10.1002/cphc.201402340	journal	August 2014
CO ₂ /H ₂ O Adsorption Equilibrium and Rates on Metal−Organic Frameworks: HKUST-1 and Ni/DOBDC Liu, Jian; Wang, Yu; Benin, Annabelle I. Langmuir, Vol. 26, Issue 17 https://doi.org/10.1021/la102359q	journal	September 2010
Diffusion of Carbon Dioxide and Nitrogen in the Small-Pore Titanium Bis(phosphonate) Metal-Organic Framework MIL-91 (Ti): A Combination of Quasielastic Neutron Scattering Measurements and Molecular Dynamics Simulations Pillai, Renjith Sasimohanan; Jobic, Hervé; Koza, Michael Marek ChemPhysChem, Vol. 18, Issue 19 https://doi.org/10.1002/cphc.201700459	journal	July 2017
Metal–Organic Frameworks for Heterogeneous Basic Catalysis Zhu, Li; Liu, Xiao-Qin; Jiang, Hai-Long Chemical Reviews, Vol. 117, Issue 12 https://doi.org/10.1021/acs.chemrev.7b00091	journal	May 2017
Chromatography in a Single Metal−Organic Framework (MOF) Crystal Han, Shuangbing; Wei, Yanhu; Valente, Cory Journal of the American Chemical Society, Vol. 132, Issue 46 https://doi.org/10.1021/ja1074322	journal	November 2010
Beyond Equilibrium: Metal–Organic Frameworks for Molecular Sieving and Kinetic Gas Separation Wang, Yuxiang; Zhao, Dan Crystal Growth & Design, Vol. 17, Issue 5 https://doi.org/10.1021/acs.cgd.7b00287	journal	April 2017
A metal–organic framework material that functions as an enantioselective catalyst for olefin epoxidation Cho, So-Hye; Ma, Baoqing; Nguyen, SonBinh T. Chem. Commun., Vol. 0, Issue 24, p. 2563-2565 https://doi.org/10.1039/B600408C	journal	January 2006
Pore Environment Effects on Catalytic Cyclohexane Oxidation in Expanded Fe ₂ (dobdc) Analogues Xiao, Dianne J.; Oktawiec, Julia; Milner, Phillip J. Journal of the American Chemical Society, Vol. 138, Issue 43 https://doi.org/10.1021/jacs.6b08417	journal	October 2016
Turnover Rates in Heterogeneous Catalysis Boudart, M. Chemical Reviews, Vol. 95, Issue 3 https://doi.org/10.1021/cr00035a009	journal	May 1995
MOFs vs. zeolites: carbonyl activation with M( iv ) catalytic sites Cirujano, Francisco G. Catalysis Science & Technology, Vol. 7, Issue 23 https://doi.org/10.1039/C7CY01811H	journal	January 2017
Transport properties of hierarchical micro–mesoporous materials Schneider, Daniel; Mehlhorn, Dirk; Zeigermann, Philipp Chemical Society Reviews, Vol. 45, Issue 12 https://doi.org/10.1039/C5CS00715A	journal	January 2016
Confinement of molecular liquids: Consequences on thermodynamic, static and dynamical properties of benzene and toluene Alba-Simionesco, C.; Dosseh, G.; Dumont, E. The European Physical Journal E, Vol. 12, Issue 1, p. 19-28 https://doi.org/10.1140/epje/i2003-10055-1	journal	September 2003
Multivariate Metal–Organic Frameworks as Multifunctional Heterogeneous Asymmetric Catalysts for Sequential Reactions Xia, Qingchun; Li, Zijian; Tan, Chunxia Journal of the American Chemical Society, Vol. 139, Issue 24 https://doi.org/10.1021/jacs.7b03113	journal	June 2017
Grand Challenges and Future Opportunities for Metal–Organic Frameworks Hendon, Christopher H.; Rieth, Adam J.; Korzyński, Maciej D. ACS Central Science, Vol. 3, Issue 6 https://doi.org/10.1021/acscentsci.7b00197	journal	June 2017
A new method for the study of diffusion and counter-diffusion in zeolites Karge, Hellmut G.; Nießen, Wilhelm Catalysis Today, Vol. 8, Issue 4 https://doi.org/10.1016/0920-5861(91)87023-G	journal	March 1991
Microphase Separation of Binary Liquids Confined in Cylindrical Pores Abdel Hamid, A. Razzak; Mhanna, Ramona; Lefort, Ronan The Journal of Physical Chemistry C, Vol. 120, Issue 17 https://doi.org/10.1021/acs.jpcc.6b01446	journal	April 2016
Correlating Surface Permeability with Intracrystalline Diffusivity in Nanoporous Solids Heinke, Lars; Kärger, Jörg Physical Review Letters, Vol. 106, Issue 7 https://doi.org/10.1103/PhysRevLett.106.074501	journal	February 2011
Metal–Organic Frameworks of Vanadium as Catalysts for Conversion of Methane to Acetic Acid Phan, Anh; Czaja, Alexander U.; Gándara, Felipe Inorganic Chemistry, Vol. 50, Issue 16, p. 7388-7390 https://doi.org/10.1021/ic201396m	journal	August 2011
A novel method to measure diffusion coefficients in porous metal–organic frameworks Zybaylo, Olexandra; Shekhah, Osama; Wang, Hui Physical Chemistry Chemical Physics, Vol. 12, Issue 28 https://doi.org/10.1039/b927601g	journal	January 2010
Unexpected Diffusion Anisotropy of Carbon Dioxide in the Metal–Organic Framework Zn ₂ (dobpdc) Forse, Alexander C.; Gonzalez, Miguel I.; Siegelman, Rebecca L. Journal of the American Chemical Society, Vol. 140, Issue 5 https://doi.org/10.1021/jacs.7b09453	journal	January 2018
Isoreticular Chiral Metal−Organic Frameworks for Asymmetric Alkene Epoxidation: Tuning Catalytic Activity by Controlling Framework Catenation and Varying Open Channel Sizes Song, Feijie; Wang, Cheng; Falkowski, Joseph M. Journal of the American Chemical Society, Vol. 132, Issue 43 https://doi.org/10.1021/ja1069773	journal	November 2010
Selective Gas Adsorption in Highly Porous Chromium(II)-Based Metal–Organic Polyhedra Lorzing, Gregory R.; Trump, Benjamin A.; Brown, Craig M. Chemistry of Materials, Vol. 29, Issue 20 https://doi.org/10.1021/acs.chemmater.7b03361	journal	October 2017
Towards a molecular understanding of shape selectivity Smit, Berend; Maesen, Theo L. M. Nature, Vol. 451, Issue 7179 https://doi.org/10.1038/nature06552	journal	February 2008
Diffusion in a pore of varying cross section Petersen, E. E. AIChE Journal, Vol. 4, Issue 3 https://doi.org/10.1002/aic.690040322	journal	September 1958
A new experimental technique for measurement of intracrystalline diffusivity Eic, Mladen; Ruthven, Douglas M. Zeolites, Vol. 8, Issue 1 https://doi.org/10.1016/S0144-2449(88)80028-9	journal	January 1988

Similar Records

Probing Substrate Diffusion in Interstitial MOF Chemistry with Kinetic Isotope Effects

Journal Article · Fri Feb 09 00:00:00 EST 2018 · Angewandte Chemie (International Edition) · OSTI ID:1493375

Wang, Chen-Hao; Das, Anuvab; Gao, Wen-Yang; +1 more

Single‐Atom Catalysts Supported by Crystalline Porous Materials: Views from the Inside

Journal Article · Sun Jul 12 00:00:00 EDT 2020 · Advanced Materials · OSTI ID:1493375

Zhang, Tianjun; Chen, Ziyi; Walsh, Andrew G.; +2 more

Leveraging Exchange Kinetics for the Synthesis of Atomically Precise Porous Catalysts

Journal Article · Wed Jan 20 00:00:00 EST 2021 · ChemCatChem · OSTI ID:1493375

Ezazi, Andrew A.; Gao, Wen‐Yang; Powers, David C.

Title: In Operando Analysis of Diffusion in Porous Metal‐Organic Framework Catalysts

Citation Formats

References (117)

Similar Records

Related Subjects