Leveraging Exchange Kinetics for the Synthesis of Atomically Precise Porous Catalysts

Ezazi, Andrew A.; Gao, Wen‐Yang; Powers, David C.

doi:10.1002/cctc.202002034

Leveraging Exchange Kinetics for the Synthesis of Atomically Precise Porous Catalysts

Journal Article · Wed Jan 20 00:00:00 EST 2021 · ChemCatChem

DOI:https://doi.org/10.1002/cctc.202002034· OSTI ID:1780843

Ezazi, Andrew A. ^[1]; Gao, Wen‐Yang ^[2]; ^[3]

Texas A & M Univ., College Station, TX (United States); Texas A&M University
Texas A & M Univ., College Station, TX (United States); New Mexico Institute of Mining and Technology, Socorro, NM (United States)
Texas A & M Univ., College Station, TX (United States)

Metal-organic frameworks (MOFs) have attracted significant attention as porous catalyst platforms due to the synthetic modularity of these materials and the diversity of lattice-confined catalytic active sites that are readily embedded within periodic crystalline frameworks. MOFs offer platforms to heterogenize molecular catalysts, stabilize novel coordination motifs, and leverage confinement effects in catalysis. Crystallinity allows diffraction-based methods to be employed in the characterization of these catalysts. Access to crystalline MOFs typically requires reversible construction of the metal-ligand (M-L) bonds that connect the SBUs, which provides a mechanism to anneal defects during crystallization. While the required M-L bond reversibility is often promoted by synthesis at elevated temperature, access to crystalline materials based on either transition metals with characteristic slow exchange kinetics or highly basic donor ligands remains a synthetic challenge. Here in this paper, we highlight synthetic strategies that leverage M-L exchange kinetics to access MOFs based on kinetically inert ions and extensions of these strategies to the assembly of atomically precise multimetallic materials.

View Accepted Manuscript (DOE)

Research Organization:: Texas A & M Univ., College Station, TX (United States); Texas A & M University, College Station, TX (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES); Welch Foundation

Grant/Contract Number:: SC0018977

OSTI ID:: 1780843

Alternate ID(s):: OSTI ID: 1804541
OSTI ID: 2433855

Journal Information:: ChemCatChem, Journal Name: ChemCatChem Journal Issue: 9 Vol. 13; ISSN 1867-3880

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
MOF catalysis
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kinetic control
metallopolymerization

Leveraging Exchange Kinetics for the Synthesis of Atomically Precise Porous Catalysts

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