Single‐Atom Catalysts Supported by Crystalline Porous Materials: Views from the Inside

Zhang, Tianjun; Chen, Ziyi; Walsh, Andrew G.; Li, Yi; Zhang, Peng

doi:10.1002/adma.202002910

Single‐Atom Catalysts Supported by Crystalline Porous Materials: Views from the Inside

Journal Article · Sun Jul 12 00:00:00 EDT 2020 · Advanced Materials

DOI:https://doi.org/10.1002/adma.202002910· OSTI ID:1638291

Zhang, Tianjun ^[1]; Chen, Ziyi ^[2]; Walsh, Andrew G. ^[2]; ^[3]; ^[2]

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry College of Chemistry Jilin University 2699 Qianjin Street Changchun 130012 P. R. China
Department of Chemistry Dalhousie University Halifax Nova Scotia B3H 4R2 Canada
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry College of Chemistry Jilin University 2699 Qianjin Street Changchun 130012 P. R. China, International Center of Future Science Jilin University 2699 Qianjin Street Changchun 130012 P. R. China

Abstract

Single‐atom catalysts (SACs) have recently emerged as an exciting system in heterogeneous catalysis showing outstanding performance in many catalytic reactions. Single‐atom catalytic sites alone are not stable and thus require stabilization from substrates. Crystalline porous materials such as zeolites and metal‐organic frameworks (MOFs) are excellent substrates for SACs, offering high stability with the potential to further enhance their performance due to synergistic effects. This review features recent work on the structure, electronic, and catalytic properties of zeolite and MOF‐protected SACs, offering atomic‐scale views from the “inside” thanks to the subatomic resolution of synchrotron X‐ray absorption spectroscopy (XAS). The extended X‐ray absorption fine structure and associated methods will be shown to be powerful tools in identifying the single‐atom site and can provide details into the coordination environment and bonding disorder of SACs. The X‐ray absorption near‐edge structure will be demonstrated as a valuable method in probing the electronic properties of SACs by analyzing the white line intensity, absorption edge shift, and pre‐/postedge features. Emphasis is also placed on in situ/operando XAS using state‐of‐the‐art equipment, which can unveil the changes in structure and properties of SACs during the dynamic catalytic processes in a highly sensitive and time‐resolved manner.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1638291

Alternate ID(s):: OSTI ID: 1712479
OSTI ID: 1763150

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 44 Vol. 32; ISSN 0935-9648

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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