Temperature-dependent selective oxidation processes for Ni-5Cr and Ni-4Al

Kruska, Karen; Schreiber, Daniel K.; Olszta, Matthew J.; Riley, Brian J.; Bruemmer, Stephen M.

doi:10.1016/j.corsci.2018.04.037

Temperature-dependent selective oxidation processes for Ni-5Cr and Ni-4Al

Journal Article · Sun Jul 01 04:00:00 EDT 2018 · Corrosion Science

DOI:https://doi.org/10.1016/j.corsci.2018.04.037· OSTI ID:1485424

Kruska, Karen; Schreiber, Daniel K.; Olszta, Matthew J.; Riley, Brian J.; Bruemmer, Stephen M.

The selective oxidation of Ni-5Cr and Ni-4Al alloys is evaluated during high (800°C) and low (420°C) temperature exposures with the oxygen partial pressure moderated by a Ni/NiO powder buffer. Internal oxidation of Cr and Al is observed throughout the matrix and at grain boundaries at 800°C accompanied by the ejection of Ni onto the surface for both. At 420°C, matrix internal oxidation was eliminated and only Ni-4Al exhibited intergranular (IG) oxidation. Surprisingly, a protective surface oxide rapidly formed for Ni-5Cr blocking IG oxidation. This is contradictory to results in 330–360°C hydrogenated water environments where both alloys show IG oxidation.

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1485424

Report Number(s):: PNNL-SA-129585

Journal Information:: Corrosion Science, Journal Name: Corrosion Science Journal Issue: C Vol. 139; ISSN 0010-938X

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

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