Temperature-dependent selective oxidation processes for Ni-5Cr and Ni-4Al

Kruska, Karen; Schreiber, Daniel K.; Olszta, Matthew J.; Riley, Brian J.; Bruemmer, Stephen M.

doi:10.1016/j.corsci.2018.04.037

Temperature-dependent selective oxidation processes for Ni-5Cr and Ni-4Al

Journal Article · Wed May 09 00:00:00 EDT 2018 · Corrosion Science

DOI:https://doi.org/10.1016/j.corsci.2018.04.037· OSTI ID:1437016

Kruska, Karen ^[1]; Schreiber, Daniel K. ^[1]; Olszta, Matthew J. ^[1]; Riley, Brian J. ^[1]; Bruemmer, Stephen M. ^[1]

Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Energy and Environment Directorate

The selective oxidation of Ni-5Cr and Ni-4 Al alloys is evaluated during high (800 °C) and low (420 °C) temperature exposures with the oxygen partial pressure moderated by a Ni/NiO powder buffer. Internal oxidation of Cr and Al is observed throughout the matrix and at grain boundaries at 800 °C accompanied by the ejection of Ni onto the surface for both. At 420 °C, matrix internal oxidation was eliminated and only Ni-4 Al exhibited intergranular (IG) oxidation. Surprisingly, a protective surface oxide rapidly formed for Ni-5Cr blocking IG oxidation. Finally, this is contradictory to results in 330–360 °C hydrogenated water environments where both alloys show IG oxidation.

View Accepted Manuscript (DOE)

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); USDOE Office of Science (SC), Biological and Environmental Research (BER) (SC-23)

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1437016

Alternate ID(s):: OSTI ID: 1582845
OSTI ID: 22840753
OSTI ID: 1485423
OSTI ID: 1485424

Report Number(s):: PNNL-SA--129585; PII: S0010938X17318577

Journal Information:: Corrosion Science, Journal Name: Corrosion Science Vol. 139; ISSN 0010-938X

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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