Syntheses, Raman spectroscopy and crystal structures of alkali hexafluoridorhenates(IV) revisited

Louis-Jean, James; Mariappan Balasekaran, Samundeeswari; Smith, Dean; Salamat, Ashkan; Pham, Chien Thang; Poineau, Frederic

doi:10.1107/S2056989018005297

Syntheses, Raman spectroscopy and crystal structures of alkali hexafluoridorhenates(IV) revisited

Journal Article · Fri Apr 06 00:00:00 EDT 2018 · Acta Crystallographica. Section E, Crystallographic Communications

DOI:https://doi.org/10.1107/S2056989018005297· OSTI ID:1455235

Louis-Jean, James ^[1]; ^[2]; ^[3]; Salamat, Ashkan ^[3]; Pham, Chien Thang ^[4]; Poineau, Frederic ^[2]

Univ. of Nevada, Las Vegas, NV (United States). Dept. of Chemistry; UC Berkeley
Univ. of Nevada, Las Vegas, NV (United States). Dept. of Chemistry
Univ. of Nevada, Las Vegas, NV (United States). Dept. of Physics and Astronomy and High Pressure Science and Engineering Center (HiPSEC)
Hanoi Univ. of Science (Vietnam). Dept. of Chemistry

The A₂[ReF₆] (A = K, Rb and Cs) salts are isotypic and crystallize in the trigonal space group type P$$\bar{3}$$m1, adopting the K₂[GeF₆] structure type. Common to all A₂[ReF₆] structures are slightly distorted octahedral [ReF₆]^2- anions with an average Re—F bond length of 1.951 (8) Å. In these salts, symmetry lowering on the local [ReF₆]^2- anions from O_h (free anion) to D_3d (solid-state structure) occur. The distortions of the [ReF₆]^2- anions, as observed in their Raman spectra, are correlated to the size of the counter-cations.

Research Organization:: Univ. of Nevada, Las Vegas, NV (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA). Nuclear Science and Security Consortium (NSSC)

Grant/Contract Number:: NA0003180

OSTI ID:: 1455235

Journal Information:: Acta Crystallographica. Section E, Crystallographic Communications, Journal Name: Acta Crystallographica. Section E, Crystallographic Communications Journal Issue: 5 Vol. 74; ISSN ACSECI; ISSN 2056-9890

Publisher:: International Union of CrystallographyCopyright Statement

Country of Publication:: United States

Language:: English

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X-ray absorption fine structure spectroscopic study of (NH4)2ReF6 Poineau, Frederic; Louis-Jean, James; Jang, Harry SN Applied Sciences, Vol. 1, Issue 11 https://doi.org/10.1007/s42452-019-1464-6	journal	October 2019

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Raman spectroscopy
crystal structure
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rhenium

CSD 1834614: Experimental Crystal Structure Determination: Non-CSD Structure Louis-Jean, J.; Balasekaran, S. Mariappan; Smith, D. https://doi.org/10.25505/fiz.icsd.cc1zl23r The current record is supplemented by this dataset	dataset	April 2018
CSD 1834615: Experimental Crystal Structure Determination: Non-CSD Structure Louis-Jean, J.; Balasekaran, S. Mariappan; Smith, D. https://doi.org/10.25505/fiz.icsd.cc1zl24s The current record is supplemented by this dataset	dataset	April 2018
CSD 1834616: Experimental Crystal Structure Determination: Non-CSD Structure Louis-Jean, J.; Balasekaran, S. Mariappan; Smith, D. https://doi.org/10.25505/fiz.icsd.cc1zl25t The current record is supplemented by this dataset	dataset	April 2018

Syntheses, Raman spectroscopy and crystal structures of alkali hexafluoridorhenates(IV) revisited

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References (13)

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