Structural and spectral studies of hydrated hexaamminecobalt(III)–hexafluororhenate(IV)

Louis-Jean, James; Forster, Paul M.; Balasekaran, Samundeeswari Mariappan; Pham, Chien Thang; Poineau, Frederic

doi:10.1016/j.jfluchem.2021.109903

Structural and spectral studies of hydrated hexaamminecobalt(III)–hexafluororhenate(IV)

Journal Article · Mon Oct 11 00:00:00 EDT 2021 · Journal of Fluorine Chemistry

DOI:https://doi.org/10.1016/j.jfluchem.2021.109903· OSTI ID:1826175

^[1]; Forster, Paul M. ^[2]; Balasekaran, Samundeeswari Mariappan ^[2]; Pham, Chien Thang ^[3]; Poineau, Frederic ^[2]

Univ. of Nevada, Las Vegas, NV (United States); University of Nevada Las Vegas
Univ. of Nevada, Las Vegas, NV (United States)
Vietnam National Univ., Hanoi (Vietnam)

The crystal structure of the [Co(NH₃)₆]₂[ReF₆]₃·3H₂O (I) salt is reported. The salt crystallizes in the trigonal space group P31m with the following unit cell dimensions: a = 15.8714(4) Å, b = 15.8714(4) Å, and c = 9.8657(4) Å. Here, the structure of (I) consists of [Co(NH₃)₆]³⁺ cations, [ReF₆]^2– anions, and co-crystallized water molecules which are linked by hydrogen bonding. In (I), independent [ReF₆]^2– anions and [Co(NH₃)₆]³⁺ cations octahedron are slightly distorted. Characteristic vibration bands of the [Co(NH₃)₆]³⁺ cation, [ReF₆]^2– anion as well as the co-crystallized H₂O molecules are observed in the infrared spectra of (I). UV-Visible analyses in water showed that the absorption of the [Co(NH₃)₆]³⁺ cation predominate the spectra of (I).

View Accepted Manuscript (DOE)

Research Organization:: Univ. of California, Berkeley, CA (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA), Office of Defense Nuclear Nonproliferation

Grant/Contract Number:: NA0003180

OSTI ID:: 1826175

Journal Information:: Journal of Fluorine Chemistry, Journal Name: Journal of Fluorine Chemistry Vol. 252; ISSN 0022-1139

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Structural and spectral studies of hydrated hexaamminecobalt(III)–hexafluororhenate(IV)

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