Coexistence of metamagnetism and slow relaxation of magnetization in ammonium hexafluoridorhenate

Louis-Jean, James; Balasekaran, Samundeeswari M.; Lawler, Keith V.; Sanchis-Perucho, Adrián; Martínez-Lillo, José; Smith, Dean; Forster, Paul M.; Salamat, Ashkan; Poineau, Frederic

doi:10.1039/d0ra10325j

Coexistence of metamagnetism and slow relaxation of magnetization in ammonium hexafluoridorhenate

Journal Article · Wed Feb 03 00:00:00 EST 2021 · RSC Advances

DOI:https://doi.org/10.1039/d0ra10325j· OSTI ID:1765173

^[1]; Balasekaran, Samundeeswari M. ^[1]; ^[1]; Sanchis-Perucho, Adrián ^[2]; ^[2]; ^[3]; Forster, Paul M. ^[1]; Salamat, Ashkan ^[1]; ^[1]

Univ. of Nevada, Las Vegas, NV (United States)
Univ. of Valencia (Spain)
Univ. of Nevada, Las Vegas, NV (United States); Argonne National Lab. (ANL), Argonne, IL (United States)

The (NH₄)₂[ReF₆] (1) salt was studied by X-ray diffraction, Raman spectroscopy, theoretical calculations, and magnetic measurements. 1 crystallizes in the trigonal space group P$$\overline{3}$$m1 (Re–F = 1.958(5) Å). In the Raman spectrum of 1, splitting of the observed peaks was observed and correlated to the valence frequencies of vibration of the [ReF₆]^2– anion. The study of the magnetic properties of 1, through DC and AC magnetic susceptibility measurements, reveals the coexistence of metamagnetism and slow relaxation of magnetization at low temperature, which is unusual in the molecular systems based on the paramagnetic 5d metal ions reported so far.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: Spanish Ministry of Science, Innovation and Universities; USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC)

Grant/Contract Number:: AC02-06CH11357; NA0003180

OSTI ID:: 1765173

Journal Information:: RSC Advances, Journal Name: RSC Advances Journal Issue: 11 Vol. 11; ISSN 2046-2069

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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