Chemical vapor deposition-prepared sub-nanometer Zr clusters on Pd surfaces: promotion of methane dry reforming

Mayr, Lukas; Shi, Xue -Rong; Kopfle, Norbert; Milligan, Cory A.; Zemlyanov, Dmitry Y.; Knop-Gericke, Axel; Havecker, Michael; Klotzer, Bernhard; Penner, Simon

doi:10.1039/c6cp07197j

Chemical vapor deposition-prepared sub-nanometer Zr clusters on Pd surfaces: promotion of methane dry reforming

Journal Article · Mon Nov 07 23:00:00 EST 2016 · Physical Chemistry Chemical Physics. PCCP

DOI:https://doi.org/10.1039/c6cp07197j· OSTI ID:1439062

Mayr, Lukas ^[1]; Shi, Xue -Rong ^[2]; Kopfle, Norbert ^[2]; Milligan, Cory A. ^[3]; Zemlyanov, Dmitry Y. ^[3]; Knop-Gericke, Axel ^[4]; Havecker, Michael ^[4]; Klotzer, Bernhard ^[2]; Penner, Simon ^[2]

Univ. of Innsbruck, Innsbruck (Austria); Purdue Univ., West Lafayette, IN (United States); University of Innsbruck, Austria
Univ. of Innsbruck, Innsbruck (Austria)
Purdue Univ., West Lafayette, IN (United States)
Fritz-Haber-Institute of the Max-Planck-Society, Berlin (Germany)

An inverse Pd–Zr model catalyst was prepared by chemical vapor deposition (CVD) using zirconium-t-butoxide (ZTB) as an organometallic precursor.

View Accepted Manuscript (DOE)

Research Organization:: Purdue Univ., West Lafayette, IN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: FG02-03ER15408

OSTI ID:: 1439062

Journal Information:: Physical Chemistry Chemical Physics. PCCP, Journal Name: Physical Chemistry Chemical Physics. PCCP Journal Issue: 46 Vol. 18; ISSN 1463-9076; ISSN PPCPFQ

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (48)

Steigerung der Wasserstoffproduktion in der Methanol-Dampfreformierung auf Kupfer durch Zink-unterstützte Wasseraktivierung Rameshan, Christoph; Stadlmayr, Werner; Penner, Simon Angewandte Chemie, Vol. 124, Issue 12 https://doi.org/10.1002/ange.201106591	journal	February 2012
Subsurface-Controlled CO ₂ Selectivity of PdZn Near-Surface Alloys in H ₂ Generation by Methanol Steam Reforming Rameshan, Christoph; Stadlmayr, Werner; Weilach, Christian Angewandte Chemie International Edition, Vol. 49, Issue 18 https://doi.org/10.1002/anie.200905815	journal	April 2010
Boosting Hydrogen Production from Methanol and Water by in situ Activation of Bimetallic Cu−Zr Species Mayr, Lukas; Klötzer, Bernhard; Schmidmair, Daniela ChemCatChem, Vol. 8, Issue 10 https://doi.org/10.1002/cctc.201600361	journal	April 2016
XPS studies of the thermal behaviour of passivated Zircaloy-4 surfaces Kaufmann, R.; Klewe-Nebenius, H.; Moers, H. Surface and Interface Analysis, Vol. 11, Issue 10 https://doi.org/10.1002/sia.740111003	journal	July 1988
Structure and Reactivity of PdOx/ZrO2Catalysts for Methane Oxidation at Low Temperatures Fujimoto, Ken-ichiro; Ribeiro, Fabio H.; Avalos-Borja, Miguel Journal of Catalysis, Vol. 179, Issue 2 https://doi.org/10.1006/jcat.1998.2178	journal	October 1998
Structure/processing relationships in the fabrication of nanoporous gold Kertis, F.; Snyder, J.; Govada, Lata JOM, Vol. 62, Issue 6 https://doi.org/10.1007/s11837-010-0087-6	journal	June 2010
Coupled calculation of vibrational frequencies and intensities Oelichmann, H. -J.; Bougeard, D.; Schrader, B. Journal of Molecular Structure, Vol. 77, Issue 3-4 https://doi.org/10.1016/0022-2860(81)80063-4	journal	December 1981
Coupled calculation of vibrational frequencies and intensities Oelichmann, H. -J.; Bougeard, D.; Schrader, B. Journal of Molecular Structure, Vol. 77, Issue 1-2 https://doi.org/10.1016/0022-2860(81)85277-5	journal	November 1981
An XPS study of hydrogen implanted zirconium Sinha, S.; Badrinarayanan, S.; Sinha, A. P. B. Journal of the Less Common Metals, Vol. 134, Issue 2 https://doi.org/10.1016/0022-5088(87)90562-5	journal	September 1987
Oxygen-induced surface phase transformation of Pd(1 1 1): sticking, adsorption and desorption kinetics Klötzer, Bernhard; Hayek, Konrad; Konvicka, Christoph Surface Science, Vol. 482-485 https://doi.org/10.1016/S0039-6028(01)00750-6	journal	June 2001
Surface and subsurface oxygen on Pd(111) Leisenberger, F. P.; Koller, G.; Sock, M. Surface Science, Vol. 445, Issue 2-3 https://doi.org/10.1016/S0039-6028(99)01084-5	journal	January 2000
ZrO 2 film growth by chemical vapor deposition using zirconium tetra- tert- butoxide Cameron, M. A.; George, S. M. Thin Solid Films, Vol. 348, Issue 1-2 https://doi.org/10.1016/S0040-6090(99)00022-X	journal	July 1999
Comparative study at low and medium reaction temperatures of syngas production by methane reforming with carbon dioxide over silica and alumina supported catalysts Ferreira-Aparicio, P.; Guerrero-Ruiz, A.; Rodrı́guez-Ramos, I. Applied Catalysis A: General, Vol. 170, Issue 1 https://doi.org/10.1016/S0926-860X(98)00048-9	journal	May 1998
Effects of zirconia phase on the synthesis of higher alcohols over zirconia and modified zirconia He, Daiping; Ding, Yunjie; Luo, Hongyuan Journal of Molecular Catalysis A: Chemical, Vol. 208, Issue 1-2 https://doi.org/10.1016/S1381-1169(03)00542-9	journal	February 2004
Nano-Au/CeO2 catalysts for CO oxidation: Influence of dopants (Fe, La and Zr) on the physicochemical properties and catalytic activity Sudarsanam, Putla; Mallesham, Baithy; Reddy, Padigapati S. Applied Catalysis B: Environmental, Vol. 144 https://doi.org/10.1016/j.apcatb.2013.08.035	journal	January 2014
Dry reforming of methane over CeO2 supported Ni, Co and Ni–Co catalysts Ay, Hale; Üner, Deniz Applied Catalysis B: Environmental, Vol. 179 https://doi.org/10.1016/j.apcatb.2015.05.013	journal	December 2015
Low temperature dry reforming of methane over Pt–Ni–Mg/ceria–zirconia catalysts Elsayed, Nada H.; Roberts, Nathan R. M.; Joseph, Babu Applied Catalysis B: Environmental, Vol. 179 https://doi.org/10.1016/j.apcatb.2015.05.021	journal	December 2015
The electronic, elastic and structural properties of Pd–Zr intermetallic Hu, Jie-Qiong; Xie, Ming; Pan, Yong Computational Materials Science, Vol. 51, Issue 1 https://doi.org/10.1016/j.commatsci.2011.07.049	journal	January 2012
Carbon incorporation during ethene oxidation on Pd(111) studied by in situ X-ray photoelectron spectroscopy at 2×10−3 mbar2×10−3 mbar Gabasch, H.; Kleimenov, E.; Teschner, D. Journal of Catalysis, Vol. 242, Issue 2 https://doi.org/10.1016/j.jcat.2006.06.022	journal	September 2006
Steering of methanol reforming selectivity by zirconia–copper interaction Mayr, Lukas; Klötzer, Bernhard; Zemlyanov, Dmitry Journal of Catalysis, Vol. 321 https://doi.org/10.1016/j.jcat.2014.10.012	journal	January 2015
Photocatalytic studies of Ho–Zr–O nano-composite with controllable composition and defects Du, Weimin; Zhao, Guoyan; Chang, Hongxun Materials Characterization, Vol. 83 https://doi.org/10.1016/j.matchar.2013.06.015	journal	September 2013
Liquid-phase Oppenauer oxidation of primary allylic and benzylic alcohols to corresponding aldehydes by solid zirconia catalysts Liu, Shu Hua; Chuah, Gaik Khuan; Jaenicke, Stephen Journal of Molecular Catalysis A: Chemical, Vol. 220, Issue 2 https://doi.org/10.1016/j.molcata.2004.06.013	journal	October 2004
Vibrational frequency analysis, FT-IR, DFT and M06-2X studies on tert-Butyl N-(thiophen-2yl)carbamate Sert, Yusuf; Singer, L. M.; Findlater, M. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 128 https://doi.org/10.1016/j.saa.2014.02.114	journal	July 2014
Growth and decay of the Pd(111)–Pd5O4 surface oxide: Pressure-dependent kinetics and structural aspects Gabasch, Harald; Unterberger, Werner; Hayek, Konrad Surface Science, Vol. 600, Issue 1 https://doi.org/10.1016/j.susc.2005.09.052	journal	January 2006
Theoretical studies on chemisorption of oxygen on β-Mo2C catalyst and its surface oxidation Shi, Xue-Rong; Wang, Sheng-Guang; Hu, Jia Surface Science, Vol. 606, Issue 15-16 https://doi.org/10.1016/j.susc.2012.03.020	journal	August 2012
Infrared Spectra of Transition Metal Alkoxides. Lynch, C. T.; Mazdiyasni, K. S.; Smith, J. S. Analytical Chemistry, Vol. 36, Issue 12 https://doi.org/10.1021/ac60218a034	journal	November 1964
Atomic Layer Deposition of FeO on Pt(111) by Ferrocene Adsorption and Oxidation Paul, Rajib; Reifenberger, Ronald G.; Fisher, Timothy S. Chemistry of Materials, Vol. 27, Issue 17 https://doi.org/10.1021/acs.chemmater.5b01778	journal	August 2015
Trimethylaluminum and Oxygen Atomic Layer Deposition on Hydroxyl-Free Cu(111) Gharachorlou, Amir; Detwiler, Michael D.; Gu, Xiang-Kui ACS Applied Materials & Interfaces, Vol. 7, Issue 30 https://doi.org/10.1021/acsami.5b03598	journal	July 2015
Palladium Nanoparticle Formation on TiO ₂ (110) by Thermal Decomposition of Palladium(II) Hexafluoroacetylacetonate Gharachorlou, Amir; Detwiler, Michael D.; Nartova, Anna V. ACS Applied Materials & Interfaces, Vol. 6, Issue 16 https://doi.org/10.1021/am504127k	journal	August 2014
Carbon Dioxide Reforming of Methane To Produce Synthesis Gas over Metal-Supported Catalysts: State of the Art Wang, Shaobin; Lu, G. Q. (Max); Millar, Graeme J. Energy & Fuels, Vol. 10, Issue 4 https://doi.org/10.1021/ef950227t	journal	January 1996
Reactions of unsaturated oxygenates on rhodium(111) as probes of multiple coordination of adsorbates Brown, N. F.; Barteau, M. A. Journal of the American Chemical Society, Vol. 114, Issue 11 https://doi.org/10.1021/ja00037a032	journal	May 1992
Growth of an Ultrathin Zirconia Film on Pt ₃ Zr Examined by High-Resolution X-ray Photoelectron Spectroscopy, Temperature-Programmed Desorption, Scanning Tunneling Microscopy, and Density Functional Theory Li, Hao; Choi, Joong-Il Jake; Mayr-Schmölzer, Wernfried The Journal of Physical Chemistry C https://doi.org/10.1021/jp5100846	journal	January 2015
Surface Chemistry of Trimethylaluminum on Pd(111) and Pt(111) Gharachorlou, Amir; Detwiler, Michael D.; Mayr, Lukas The Journal of Physical Chemistry C, Vol. 119, Issue 33 https://doi.org/10.1021/jp512915f	journal	August 2015
Advanced anodes for high-temperature fuel cells Atkinson, A.; Barnett, S.; Gorte, R. J. Nature Materials, Vol. 3, Issue 1 https://doi.org/10.1038/nmat1040	journal	January 2004
Slab model studies of water adsorption and decomposition on clean and X- (X = C, N and O) contaminated Pd(111) surfaces Cao, Yilin; Chen, Zhao-Xu Phys. Chem. Chem. Phys., Vol. 9, Issue 6 https://doi.org/10.1039/B610691A	journal	January 2007
Surface chemistry of atomic layer deposition: A case study for the trimethylaluminum/water process Puurunen, Riikka L. Journal of Applied Physics, Vol. 97, Issue 12, Article No. 121301 https://doi.org/10.1063/1.1940727	journal	June 2005
X‐ray photoelectron spectroscopic studies on yttria, zirconia, and yttria‐stabilized zirconia Majumdar, Debasis; Chatterjee, Dilip Journal of Applied Physics, Vol. 70, Issue 2 https://doi.org/10.1063/1.349611	journal	July 1991
An (ultra) high-vacuum compatible sputter source for oxide thin film growth Mayr, Lukas; Köpfle, Norbert; Auer, Andrea Review of Scientific Instruments, Vol. 84, Issue 9 https://doi.org/10.1063/1.4821148	journal	September 2013
Combined UHV/high-pressure catalysis setup for depth-resolved near-surface spectroscopic characterization and catalytic testing of model catalysts Mayr, Lukas; Rameshan, Raffael; Klötzer, Bernhard Review of Scientific Instruments, Vol. 85, Issue 5 https://doi.org/10.1063/1.4874002	journal	May 2014
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
Surface and interface structures of epitaxial ZrO 2 films on Pt ( 111 ) : Experiment and density-functional theory calculations Meinel, K.; Eichler, A.; Förster, S. Physical Review B, Vol. 74, Issue 23 https://doi.org/10.1103/PhysRevB.74.235444	journal	December 2006
Surface oxides on Pd(111): STM and density functional calculations Klikovits, J.; Napetschnig, E.; Schmid, M. Physical Review B, Vol. 76, Issue 4 https://doi.org/10.1103/PhysRevB.76.045405	journal	July 2007
Van der Waals density functionals applied to solids Klimeš, Jiří; Bowler, David R.; Michaelides, Angelos Physical Review B, Vol. 83, Issue 19 https://doi.org/10.1103/PhysRevB.83.195131	journal	May 2011
Rapid thermal chemical vapor deposition of zirconium oxide for metal-oxide-semiconductor field effect transistor application Chang, Jane P.; Lin, You-Sheng; Chu, Karen Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 19, Issue 5 https://doi.org/10.1116/1.1396639	journal	January 2001
Ultrathin zirconium oxide films as alternative gate dielectrics Chang, J. P.; Lin, Y-S.; Berger, S. Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 19, Issue 6 https://doi.org/10.1116/1.1415513	journal	January 2001
Onset of Catalytic Activity of Gold Clusters on Titania with the Appearance of Nonmetallic Properties Valden, M. Science, Vol. 281, Issue 5383 https://doi.org/10.1126/science.281.5383.1647	journal	September 1998
Theoretical Study of Oxygen Chemisorption on Pd (111), Au (111) and Pd–Au (111) Alloy Surfaces Ji, Min; Hao, Ce; Xie, Zhenping Journal of Computational and Theoretical Nanoscience, Vol. 9, Issue 3 https://doi.org/10.1166/jctn.2012.2037	journal	March 2012

Cited By (4)

Zirconium-Assisted Activation of Palladium To Boost Syngas Production by Methane Dry Reforming Köpfle, Norbert; Götsch, Thomas; Grünbacher, Matthias Angewandte Chemie International Edition, Vol. 57, Issue 44 https://doi.org/10.1002/anie.201807463	journal	September 2018
Zirconium-assistierte Aktivierung von Palladium zur Steigerung der Produktion von Synthesegas in der Trockenreformierung von Methan Köpfle, Norbert; Götsch, Thomas; Grünbacher, Matthias Angewandte Chemie, Vol. 130, Issue 44 https://doi.org/10.1002/ange.201807463	journal	September 2018
Metal Clusters Dispersed on Oxide Supports: Preparation Methods and Metal-Support Interactions Guo, Yu; Zhang, Ya-Wen Topics in Catalysis, Vol. 61, Issue 9-11 https://doi.org/10.1007/s11244-018-0957-7	journal	May 2018
A Comparative Discussion of the Catalytic Activity and CO2-Selectivity of Cu-Zr and Pd-Zr (Intermetallic) Compounds in Methanol Steam Reforming Köpfle, Norbert; Mayr, Lukas; Schmidmair, Daniela Catalysts, Vol. 7, Issue 12 https://doi.org/10.3390/catal7020053	journal	February 2017

Similar Records

Low-temperature chemical vapor deposition of high-purity copper from an organometallic source

Journal Article · · Chemistry of Materials; (USA) · OSTI ID:6730434

Kinetic studies of the chemical vapor deposition of platinum

Journal Article · · Chemistry of Materials; (USA) · OSTI ID:5566472

CHEMICALLY VAPOR DEPOSITED YTTRIA-STABILIZED ZIRCONIA (YSZ) FOR THERMAL AND ENVIRONMENTAL BARRIER COATING

Conference · Tue Apr 22 00:00:00 EDT 2003 · OSTI ID:835696

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Chemical vapor deposition-prepared sub-nanometer Zr clusters on Pd surfaces: promotion of methane dry reforming

Citation Formats

References (48)

Cited By (4)

Similar Records

Related Subjects