Chemical vapor deposition-prepared sub-nanometer Zr clusters on Pd surfaces: promotion of methane dry reforming

Mayr, Lukas; Shi, Xue -Rong; Kopfle, Norbert; Milligan, Cory A.; Zemlyanov, Dmitry Y.; Knop-Gericke, Axel; Havecker, Michael; Klotzer, Bernhard; Penner, Simon

doi:10.1039/c6cp07197j

Title: Chemical vapor deposition-prepared sub-nanometer Zr clusters on Pd surfaces: promotion of methane dry reforming

Journal Article · Tue Nov 08 00:00:00 EST 2016 · Physical Chemistry Chemical Physics. PCCP

DOI:https://doi.org/10.1039/c6cp07197j· OSTI ID:1439062

Mayr, Lukas ^[1]; Shi, Xue -Rong ^[2]; Kopfle, Norbert ^[2]; Milligan, Cory A. ^[3]; Zemlyanov, Dmitry Y. ^[3]; Knop-Gericke, Axel ^[4]; Havecker, Michael ^[4]; Klotzer, Bernhard ^[2]; Penner, Simon ^[2]

Univ. of Innsbruck, Innsbruck (Austria); Purdue Univ., West Lafayette, IN (United States)
Univ. of Innsbruck, Innsbruck (Austria)
Purdue Univ., West Lafayette, IN (United States)
Fritz-Haber-Institute of the Max-Planck-Society, Berlin (Germany)

An inverse Pd–Zr model catalyst was prepared by chemical vapor deposition (CVD) using zirconium-t-butoxide (ZTB) as an organometallic precursor.

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Research Organization:: Purdue Univ., West Lafayette, IN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division

Grant/Contract Number:: FG02-03ER15408

OSTI ID:: 1439062

Journal Information:: Physical Chemistry Chemical Physics. PCCP, Vol. 18, Issue 46; ISSN 1463-9076

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 13 works

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Zirconium-Assisted Activation of Palladium To Boost Syngas Production by Methane Dry Reforming Köpfle, Norbert; Götsch, Thomas; Grünbacher, Matthias Angewandte Chemie International Edition, Vol. 57, Issue 44 https://doi.org/10.1002/anie.201807463	journal	September 2018
A Comparative Discussion of the Catalytic Activity and CO2-Selectivity of Cu-Zr and Pd-Zr (Intermetallic) Compounds in Methanol Steam Reforming Köpfle, Norbert; Mayr, Lukas; Schmidmair, Daniela Catalysts, Vol. 7, Issue 12 https://doi.org/10.3390/catal7020053	journal	February 2017
Zirconium-assistierte Aktivierung von Palladium zur Steigerung der Produktion von Synthesegas in der Trockenreformierung von Methan Köpfle, Norbert; Götsch, Thomas; Grünbacher, Matthias Angewandte Chemie, Vol. 130, Issue 44 https://doi.org/10.1002/ange.201807463	journal	September 2018
Metal Clusters Dispersed on Oxide Supports: Preparation Methods and Metal-Support Interactions Guo, Yu; Zhang, Ya-Wen Topics in Catalysis, Vol. 61, Issue 9-11 https://doi.org/10.1007/s11244-018-0957-7	journal	May 2018

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